Citation: ZHANG Dong-Teng, ZHU Ying-Ying, LUO Guang-Ming, CAI Hu. Synthesis and Characterization of Tert-butylimido Tetra-chloro Tantalum(Ⅴ) Anion Complex [IPrH]⁺[^tBuN=TaCl₄(py)]^-[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(5): 953-957. doi: 10.3969/j.issn.1001-4861.2013.00.162 shu

Synthesis and Characterization of Tert-butylimido Tetra-chloro Tantalum(Ⅴ) Anion Complex [IPrH]⁺[^tBuN=TaCl₄(py)]^-

1.
Department of Chemistry, Nanchang University, Nanchang 330031, China

Received Date: 18 April 2012
Available Online: 24 February 2013
Fund Project: 国家自然科学基金(No.20861007) (No.20861007)江西省教育厅基金(No.GJJ08026)资助项目。 (No.GJJ08026)

[IPrH]⁺[^tBuN=TaCl₄(py)]^- (1) (IPr=1,3-bis(2,6-diisoproylphenyl)imidazol-2-ylidene) was obtained unexpe-ctedly by the reaction of ^tBuN=TaCl₃(py)₂ and IPr. Complex 1 was structurally characterized by NMR, IR, fluores-cence spectra, elemental analysis and single-crystal X-ray diffraction. The crystal structure of 1 shows that the Ta(Ⅴ) center is octahedrally coordinated by four chlorides and two nitrogen atoms from imido and pyridyl ligands, respectively. CCDC: 873803.
- imido complex;N-heterocyclic-carbene;Ta complex;luminescence
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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Characterization of Tert-butylimido Tetra-chloro Tantalum(Ⅴ) Anion Complex [IPrH]+[tBuN=TaCl4(py)]-

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Characterization of Tert-butylimido Tetra-chloro Tantalum(Ⅴ) Anion Complex [IPrH]⁺[^tBuN=TaCl₄(py)]^-