Citation: HUANG De-Qian, ZHANG Hong, SHENG Liang-Quan, JIANG Xue-Yue, LIU Zhao-Di, XU Hua-Jie. Synthesis, Structure and Properties of a Samarium(Ⅲ) Complex Based on 1-Naphthaleneacetate and 5,5'-Dimethyl-2,2'-Bipyridine Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(5): 1065-1071. doi: 10.3969/j.issn.1001-4861.2013.00.158 shu

Synthesis, Structure and Properties of a Samarium(Ⅲ) Complex Based on 1-Naphthaleneacetate and 5,5'-Dimethyl-2,2'-Bipyridine Ligands

1.
School of Chemistry and Chemical Engineering, Fuyang Teachers College, Fuyang, Anhui 236037, China

Corresponding author: HUANG De-Qian,
Received Date: 5 October 2012
Available Online: 22 February 2013
Fund Project: 安徽高校省级自然科学研究项目(No.KJ2012Z310, KJ2011A210, KJ2012Z306) (No.KJ2012Z310, KJ2011A210, KJ2012Z306)阜阳师范学院博士启动基金(No.29709004)阜阳师范学院分析化学重点学科基金(No.2010xk7-02)资助项目。 (No.29709004)阜阳师范学院分析化学重点学科基金(No.2010xk7-02)

A complex Sm₂(1-npac)₆(dmpy)₂·(H₂O)₃(1), (1-npac=1-naphthaleneacetate, dmpy=5,5'-dimethyl-2,2'-bipyridine) has been hydrothermally synthesized and characterized by elemental analysis, IR, TGA, powder X-ray diffraction, UV-Vis and single-crystal X-ray diffraction. Structural determination reveals that the samarium ions are bridged by two bidentate and two terdentate carboxylato groups to give centrosymmetric dimers with Sm…Sm separation of 0.3925(2) nm, which is further extended to a 3D supramolecular structure by hydrogen bonds, C-H…π and π…π stacking interactions. Solid-state 1 emits the intensive orange luminescence of Sm³⁺ ion with fluorescence lifetime of 0.87 μs (598 nm) at room temperature. CCDC: 898378.
- samarium complex;crystal structure;1-naphthaleneacetate;5,5'-dimethyl-2,2'-bipyridine;luminescent
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沈阳化工大学材料科学与工程学院沈阳 110142