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Citation: SONG Ya-Jiao, SUN Jing, ZHU Peng, YAN Ling-Ling, LI Jian. Preparation and Properties of Rare Earth Yttrium Doped Eu(TTA)3 /PMMA Temperature Sensitive Paint[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(6): 1171-1175. doi: 10.3969/j.issn.1001-4861.2013.00.148 shu

Preparation and Properties of Rare Earth Yttrium Doped Eu(TTA)3 /PMMA Temperature Sensitive Paint

  • 1.

    School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, China

  • Received Date: 10 September 2012
    Available Online: 10 January 2013

    Fund Project: 兵器预研基金(No.BQ0302)资助项目。 (No.BQ0302)

  • In this paper, the yttrium doped Eu(TTA)3 probe molecule were prepared, which the EuCl3, YCl3 and 2-Thenoyltrifluoroacetone(TTA) were used as raw materials, and then the yttrium doped Eu(TTA)3/Polymethyl-methacrylate(PMMA) temperature-sensitive paint (TSP) was obtained when the yttrium doped Eu(TTA)3 probe molecule were doped into the PMMA. The structure of the probe molecule and the properties of the TSP were characterized by IR, absorption spectra, excitation and emission spectra. IR analysis indicate that the coordinate bond between Eu(Y) and TTA was formed, and the structure of Eu(TTA)3 was not destroyed when the yttrium was doped into Eu(TTA)3. UV absorption spectra show that the absorption band of the probe molecule is 290～376 nm. Excitation and emission spectra illustrate that the strongest emission peak is 614 nm when the TSP was excited by 340 nm, and the emission of Eu(TTA)3 will be enhanced for the doping of yttrium, and the gain function was the strongest when the ratio between Eu and Y was 0.5:0.5. The emission spectra of the TSP at different temperatures illustrate that the emission strength of the TSP was decreased with the increasing of temperature, it shows that the TSP has good temperature quenching property, Furthermore, the temperature measure sensitivity was also enhanced for the doping of yttrium.
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