Citation: LIU Hong-Bo, HUANG Zhi-Yong, GUO Bing-Zhi, JIAO Qing-Ze. Catalytic Thermal Decomposition of Ammonium Perchlorate by Cu/Co/Fe Mixed Oxides Derived from Layered Double Hydroxides[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(5): 1077-1083. doi: 10.3969/j.issn.1001-4861.2013.00.132 shu

Catalytic Thermal Decomposition of Ammonium Perchlorate by Cu/Co/Fe Mixed Oxides Derived from Layered Double Hydroxides

1.
1. School of Chemical Engineering and Materials Science, Beijing Institute of Technology Zhuhai, Zhuhai, Guangdong 519088, China;

Received Date: 8 October 2012
Available Online: 19 December 2012
Fund Project: 北京理工大学珠海学院青年教师科研发展基金(No.2011B06)资助项目。 (No.2011B06)

Cu/Co/Fe mixed oxides (Cu/Co/Fe-MOs) were prepared by calcining the precursors of Cu/Co/Fe layered double hydroxides (Cu/Co/Fe-LDHs), and were used as new catalysts for the thermal decomposition of ammonium perchlorate (AP). The catalytic activity was investigated using differential thermal analysis (DTA) and thermal gravimetric analyzer coupled with an online mass spectrometer (TG-MS). The results reveal that Cu/Co/Fe-MOs exhibit CuFe₂O₄ and (CoFe₂)O₄ phase with high specific surface area of 70～110 m²·g^-1. The Cu/Co/Fe-MOs have homogenous particles with crystallite size of 20～30 nm. The thermal decomposition temperature of AP can be lowered by 139 ℃ with 4wt% of Cu/Co/Fe-MOs calcined at 400 ℃. The improvement in thermal decomposition of AP by Cu/Co/Fe-MOs catalysts is achieved via the superoxide ion (O₂^-) adsorbed on the surface of Cu/Co/Fe-MOs.
- Cu/Co/Fe mixed oxides;ammonium perchlorate;thermal decomposition;layered doubled hydroxides
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沈阳化工大学材料科学与工程学院沈阳 110142