Citation: GONG Wei, NIU Qiong, NIU He-Lin, HU Lin, MAO Chang-Jie, SONG Ji-Ming, ZHANG Sheng-Yi, ZHENG Jun, CHEN Qian-Wang. Synthesis, Structure and Properties of a Porous Ni(Ⅱ) Coordination Polymer Constructed from 1,1'-(1,4-Butanediyl)bis(imidazole) and o-Phthalate Acid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(3): 642-648. doi: 10.3969/j.issn.1001-4861.2013.00.115 shu

Synthesis, Structure and Properties of a Porous Ni(Ⅱ) Coordination Polymer Constructed from 1,1'-(1,4-Butanediyl)bis(imidazole) and o-Phthalate Acid

1.
1. College of Chemistry & Chemical Engineering, Anhui University, Hefei 230039, China;

Received Date: 29 April 2012
Available Online: 23 October 2012
Fund Project: 国家自然科学基金(Nos.20905001, 21071002) (Nos.20905001, 21071002)安徽省自然科学基金(Nos.KJ2010A014) 和安徽大学“211”创新团队资助项目。 (Nos.KJ2010A014)

A coordination polymer [Ni(Pht)(bbim-4)]_n (Pht=o-phthalate acid anion,bbim-4=1, 1'-(1, 4-butanediyl)bis(imidazole) was synthesized by hydrothermal reaction and characterized by elemental analysis, powder X-ray diffraction, TGA and X-ray single crystal diffraction. The crystal belongs to monoclinic system, space group C2/c. Coordination polymer [Ni(Pht)(bbim-4)]_n is a three-dimensional porous coordination polymer with triangular channels. The coordination polymer shows an overall ferromagnetic behavior. Gas sorption studies suggest that the coordination polymer has selectivity in adsorption of N₂ and CO₂ gas. CCDC: 818068.
- nickel coordination polymer;1, 1'-(1,4-butanediyl)bis(imidazole);o-phthalate acid anion;hydrothermal synthesis;crystal structure;gas sorption
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沈阳化工大学材料科学与工程学院沈阳 110142