Citation: FU Wei-Wei, KUANG Dai-Zhi, ZHANG Fu-Xing, LIU Yang, LI Wei, KUANG Yun-Fei. Synthesis, Crystal Structure and Properties of the Nickel(Ⅱ) 4'-(p-methoxylphenyl)-2, 2':6',2″-terpyridine Complex[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(3): 654-658. doi: 10.3969/j.issn.1001-4861.2013.00.099 shu

Synthesis, Crystal Structure and Properties of the Nickel(Ⅱ) 4'-(p-methoxylphenyl)-2, 2':6',2″-terpyridine Complex

1.
Department of Chemistry and Materials Science, Hengyang Normal University, Key Laboratory of Functional Organometallic Materials of Gerneral Institutes of Higher Education In Hunan Province, Hengyang, Hunan 421008, China

Received Date: 1 April 2012
Available Online: 10 October 2012
Fund Project: 衡阳市科技计划项目(No.2011KJ21) (No.2011KJ21)衡阳师范学院科研启动基金(No.09B02) (No.09B02)

The title complex has been synthesized with 4'-(p-methoxylphenyl)-2,2':6',2″-terpyridine (meophtpy) and zinc sulfate heptahydrate (NiSO₄·7H₂O), sodium perchlorate (NaClO₄) with solvothermal method and characterized by IR, UV and X-ray diffraction. It crystallizes in monoclinic space group P2₁/c. The crystal structure shows that the nickel atom is coordinated with six nitrogen atoms from two terpyridine molecules, forming six-coordinated octahedral coordination geometry. There are three abosrpsion peaks 235.5, 278.5 and 342 nm which are the typical absorption spectrum of terpyridine complexes. The fluerescence are peaked at 396 nm. Following a cyclic voltammetry measurement a typical reduction peak of Ni²⁺ at -0.82 V was found. CCDC: 899537.
- nickel(Ⅱ) complex;terpyridine;fluerescence;cyclic voltammetry
1. [1]
  [1] TANG Liang(唐亮), SHAO Yun(邵芸), WAN Hai-Qin (万海勤), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(9):1691-1696
2. [2]
  [2] ZOU Min(邹敏), LIU Shu-Wen(刘叔文), ZHOU Chun-Qiong (周春琼). Acta Chim. Sinica(Huaxue Xuebao), 2010,68(6): 481-486
3. [3]
  [3] XIAN Jing-Chun(贤景春). J. Mol. Sci. (Fenzi Kexue Xuebao), 2010,26(5):365-367
4. [4]
  [4] CHEN Xiao-Hua(陈小华), WU Qiong-Jie(吴琼洁), CHEN Shun-Yu(陈顺玉), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(9):1573-1576
5. [5]
  [5] YUAN Si-Chun(苑嗣纯), CHEN Hai-Bo(陈海波), WANG Hui-Chuan(王惠川), et al. Progress in Chemistry (Huaxue Jinzhan), 2009,21(10):2132-2152
6. [6]
  [6] PAN Yue-Xiu(潘月秀), TONG Bin(佟斌), ZHI Jun-Ge (支俊格), et al. Progress in Chemistry (Huaxue Jinzhan), 2009,21(9): 1763-1771
7. [7]
  [7] YUAN Si-Chun(苑嗣纯), WANG Hui-Chuang(王惠川), CHEN Hai-Bo(陈海波), et al. Chinese J. Org. Chem. (Youji Huaxue), 2009,25(4):589-595
8. [8]
  [8] Constable E C, Lewis J, Liptrot M C, et al. Inorg. Chim. Acta., 1990,178:47-54
9. [9]
  [9] McMurtrie J, Dance I. CrystEngComm, 2009,11:1141-1149
10. [10]
  [10] Alock N W, Barker P R, Haider J M, et al. J. Chem. Soc., Dalton Trans., 2000:1447-1461
11. [11]
  [11] Padhi S K, Sahu R, Manivannan V. Polyhedron, 2010,29: 709-714
12. [12]
  [12] Gou L, Xu L F, Hu H M, et al. Z. Anorg. Allg. Chem., 2008, 634:1215-1220
13. [13]
  [13] Beves J E, Bray D J, Clegg J K, et al. Inorg. Chim. Acta, 2008,361:2582-2590
14. [14]
  [14] McMurtrie J, Dance I. CrystEngComm, 2005,7:230-236
15. [15]
  [15] Zhou X P, Ni W X, Zhan S Z, et al. Inorg. Chem., 2007,46: 2345-2347
16. [16]
  [16] YANG Hao(杨浩), CHEN Wen-Tao(陈文涛), FENG Yu-Quan(冯玉泉), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(1):62-66
17. [17]
  [17] Yoshida J, Nishikiori S, Kuroda R. Bull. Chem. Soc. Jpn., 2009,82:1377-1385
18. [18]
  [18] WANG Xiao-Xia(王晓霞), LIU Han-Guo(刘汉国), WAN Xia(万霞), et al. Chemical Reagents (Huaxue Shiji), 2009, 25(4):589-595
19. [19]
  [19] Sheldrick G M. SHELX-97 Program for the Solution and the Refinement of Crystal Structures, University of Gottingen, Germany, 1997.
20. [20]
  [20] Calatayud M L, Sletten J, Julve M, et al. J. Mol. Struct., 2005,741:121-128
21. [21]
  [21] Padhi S K, Sahu R, Manivannan V. Polyhedron, 2008,27: 2221-2225
22. [22]
  [22] WANG Na-Na(王娜娜), GUO Li-Qin(郭莉芹), ZHANG Xiao-Hong(张晓红), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(3):445-452
1. [1]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
2. [2]
  Cen Zhou , Biqiong Hong , Yiting Chen . Application of Electrochemical Techniques in Supramolecular Chemistry. University Chemistry, 2025, 40(3): 308-317. doi: 10.12461/PKU.DXHX202406086
3. [3]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
4. [4]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
5. [5]
  Chun-Lin Sun , Yaole Jiang , Yu Chen , Rongjing Guo , Yongwen Shen , Xinping Hui , Baoxin Zhang , Xiaobo Pan . Construction, Performance Testing, and Practical Applications of a Home-Made Open Fluorescence Spectrometer. University Chemistry, 2024, 39(5): 287-295. doi: 10.3866/PKU.DXHX202311096
6. [6]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
7. [7]
  Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363
8. [8]
  Keweiyang Zhang , Zihan Fan , Liyuan Xiao , Haitao Long , Jing Jing . Unveiling Crystal Field Theory: Preparation, Characterization, and Performance Assessment of Nickel Macrocyclic Complexes. University Chemistry, 2024, 39(5): 163-171. doi: 10.3866/PKU.DXHX202310084
9. [9]
  Qiaowen CHANG , Ke ZHANG , Guangying HUANG , Nuonan LI , Weiping LIU , Fuquan BAI , Caixian YAN , Yangyang FENG , Chuan ZUO . Syntheses, structures, and photo-physical properties of iridium phosphorescent complexes with phenylpyridine derivatives bearing different substituting groups. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 235-244. doi: 10.11862/CJIC.20240311
10. [10]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
11. [11]
  Jinfeng Chu , Yicheng Wang , Ji Qi , Yulin Liu , Yan Li , Lan Jin , Lei He , Yufei Song . Comprehensive Chemical Experiment Design: Convenient Preparation and Characterization of an Oxygen-Bridged Trinuclear Iron(III) Complex. University Chemistry, 2024, 39(7): 299-306. doi: 10.3866/PKU.DXHX202310105
12. [12]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
13. [13]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
14. [14]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
15. [15]
  Mi Wen , Baoshuo Jia , Yongqi Chai , Tong Wang , Jianbo Liu , Hailong Wu . Improvement of Fluorescence Quantitative Analysis Experiment: Simultaneous Determination of Rhodamine 6G and Rhodamine 123 in Food Using Chemometrics-Assisted Three-Dimensional Fluorescence Method. University Chemistry, 2025, 40(4): 390-398. doi: 10.12461/PKU.DXHX202405147
16. [16]
  Wei Peng , Baoying Wen , Huamin Li , Yiru Wang , Jianfeng Li . Exploration and Practice on Raman Scattering Spectroscopy Experimental Teaching. University Chemistry, 2024, 39(8): 230-240. doi: 10.3866/PKU.DXHX202312062
17. [17]
  Mengyao Shi , Kangle Su , Qingming Lu , Bin Zhang , Xiaowen Xu . Determination of Potassium Content in Tobacco Stem Ash by Flame Atomic Absorption Spectroscopy. University Chemistry, 2024, 39(10): 255-260. doi: 10.12461/PKU.DXHX202404105
18. [18]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
19. [19]
  Yingying Chen , Di Xu , Congmin Wang . Exploration and Practice of the “Four-Level, Three-Linkage” General Chemistry Course System. University Chemistry, 2024, 39(8): 119-125. doi: 10.3866/PKU.DXHX202401057
20. [20]
  Zhongxin YU , Wei SONG , Yang LIU , Yuxue DING , Fanhao MENG , Shuju WANG , Lixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(352)
HTML views(29)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142