Citation: JIA Yun-Jie, LI Ming-Lei, CUI Ji-Li, LIU Liang, WANG Run-Wei, YI Jian-Jun, XU Qing-Hong. 3D-Mesoporous Zirconium Phosphonate NTAZP: Synthesis and Formaldehyde Oxidation by Its Supported Fe³⁺ Catalyst[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(3): 465-473. doi: 10.3969/j.issn.1001-4861.2013.00.078 shu

3D-Mesoporous Zirconium Phosphonate NTAZP: Synthesis and Formaldehyde Oxidation by Its Supported Fe³⁺ Catalyst

1.
1. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China;

Received Date: 12 July 2012
Available Online: 7 October 2012
Fund Project: 国家自然科学基金(No.50602004) (No.50602004)

A new mesoporous zirconium phosphonate(NTAZP) was synthesized by using nitrilotris(methylene)-triphosphonic acid (ATMP) and zirconium dichloride oxide octahydrate. The as-prepared mesoporous materials were characterized by XRD, FTIR, TG-DTA and SEM techniques. Fe³⁺-based aminotrialkylene zirconium phosphonate catalyst was obtained by using NTAZP as the support and by treating the support with an aqueous solution of Fe(NO₃)₃. The results indicate that the structure and morphology of NTAZP are not changed after loading, and ferric species are mainly anchored on NTAZP via the coordinative interactions between Fe³⁺ and N atoms inside the mesoporous channel. The supported ferric species NTAZP (NTAZP-Fe³⁺) with a good thermal stability are highly catalytic active for formaldehyde oxidation in relatively mild reaction conditions. The Fe-based catalyst can prevent Fe³⁺ from dissolving into the water, and can be recycled to avoid secondary pollution. NTAZP-Fe³⁺ is a high-efficient and green catalyst in small-molecule aldehydes oxidation.
- catalysis;catalyst;catalyst preparation;coordination load;zirconium phosphonates;mesoporous;coordination loading;oxidation
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

3D-Mesoporous Zirconium Phosphonate NTAZP: Synthesis and Formaldehyde Oxidation by Its Supported Fe3+ Catalyst

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通讯作者: 陈斌, bchen63@163.com

3D-Mesoporous Zirconium Phosphonate NTAZP: Synthesis and Formaldehyde Oxidation by Its Supported Fe³⁺ Catalyst