用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂

引用本文: RazaAsif Hassan, FarhanShumail, 余志贤, 吴艳. 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂[J]. 物理化学学报, 2024, 40(11): 240602. doi: 10.3866/PKU.WHXB202406020 shu

Citation: Asif Hassan Raza, Shumail Farhan, Zhixian Yu, Yan Wu. Double S-Scheme ZnS/ZnO/CdS Heterostructure Photocatalyst for Efficient Hydrogen Production[J]. Acta Physico-Chimica Sinica, 2024, 40(11): 240602. doi: 10.3866/PKU.WHXB202406020 shu

用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂

中国地质大学(武汉)材料科学与化学学院, 武汉 430078

通讯作者: 吴艳, wuyan@cug.edu.cn

基金项目:
国家自然科学基金 22378372

中国政府奖学金支持

摘要: 这项工作展示了一种新型具有高效光催化活性的双S型ZnS/ZnO/CdS三元异质结光催化剂。具有最佳CdS组成的ZnS/ZnO/CdS三元催化剂，ZnS/ZnO/CdS-14%显示最大H2析出速率为4.1 mmol·g^‒1·h^‒1。最大光催化性能分别约是相应的ZnS/CdS和ZnO/ZnS的2倍和13倍。在420 nm下，获得了19.8%的量子效率。此外，连续6次测试后，催化剂的结构和产氢活性只有微小的变化，表明了光催化剂的稳定性。根据理论计算和实验结果，三元光催化活性的显著提高归因于快速的电子转移和分离，以及相互作用的双S型半导体界面之间的紧密接触。这项工作强调了一种构建双S型光催化系统的新方法，该分解水产氢系统对光生载流子具有高效分离和快速迁移能力。

关键词:

English

Double S-Scheme ZnS/ZnO/CdS Heterostructure Photocatalyst for Efficient Hydrogen Production

Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan 430078, China

Corresponding author: Yan Wu, Email: wuyan@cug.edu.cn; Tel: +86-13517286716

Received Date: 17 June 2024
Accepted Date: 29 July 2024
Revised Date: 24 July 2024
Available Online: 15 November 2024
Fund Project:
the National Natural Science Foundation of China

Chinese Government Scholarship

Abstract: This work illustrates the novelty of double S-scheme ZnS/ZnO/CdS ternary heterojunction photocatalyst with efficient photocatalytic activity. The sample with optimal CdS content, ZnS/ZnO/CdS-14% (ZZC14%), displayed the maximum H₂ evolution rate of 4.1 mmol·g^‒1·h^‒1. The maximum photocatalytic performance was approximately 2 and 13 times higher than their corresponding counterparts, ZnS/CdS and ZnO/ZnS, respectively. A high AQE of 19.8% under 420 nm was obtained. Additionally, the slight changes in H₂ evolution activities and retentions of crystal structures after six successive cycles indicate the stability of the photocatalyst. In accordance with the theoretical calculations and experimental results, the remarkable enhancement in photocatalytic activity is attributed to fast electron transfer and separation as well as the intimate contact due to mutual interaction between S-scheme. This work highlights an innovative approach to constructing a dual S-scheme photocatalytic system with high separation and fast migration capabilities of photogenerated charge carriers for splitting water to produce hydrogen.

Key words:

1. [1]
  Bie, C.; Wang, L.; Yu, J. Chem. 2022, 8 (6), 1567. doi: 10.1016/j.chempr.2022.04.013
2. [2]
  Sun, T.; Li, C.; Bao, Y.; Fan, J.; Liu, E. Acta Phys.-Chim.Sin. 2023, 39 (6), 2212009. doi: 10.3866/PKU.WHXB202212009.
3. [3]
  Fujishima, A.; Honda, K. Nature 1972, 238(5358), 37. doi: 10.1038/238037a0
4. [4]
  Lu, C.; Du, S.; Zhao, Y.; Wang, Q.; Ren, K.; Li, C.; Dou, W. RSC Adv. 2021, 11 (45), 28211. doi: 10.1039/DIRA04823F
5. [5]
  Xiao, Y.; Li, M.; Li, H.; Wang, Z.; Wang, Y. Nano Energy 2024, 120 (1), 109164. doi: 10.1016/j.nanoen.2023.109164
6. [6]
  Jiang, J.; Wang, G.; Shao, Y.; Wang, J.; Zhou, S.; Su, Y. Chin. J. Catal. 2022, 43 (2), 329. doi: 10.1016/S1872-2067(21)63889
7. [7]
  Liang, S.; Wang, Z.; Zhou, L.; You, S.; Zhang, R.; Liu, F.; Niu, P.; Wang, X. ACS Appl. Mater. Interfaces 2024, 16 (14), 17442. doi: 10.1021/acsami.3c8575
8. [8]
  Li, J. Y.; Tan, C. L.; Qi, M. Y.; Tang, Z. R.; Xu, Y. J. Angew. Chem. Int. Edit. 2023, 62 (22), e202303054. doi: 10.1002/anie.202303054.
9. [9]
  Zhao, N.; Peng, J.; Wang, J.; Zhai, M. Acta Phys.-Chim.Sin. 2022, 38 (4), 2004046. doi: 10.3866/PKU.WHXB202004046
10. [10]
  Xiang, X.; Zhang, L.; Luo, C.; Zhang, J.; Cheng, B.; Liang, G.; Zhang, Z.; Yu, J. Appl. Catal. B-Environ. 2024, 340, 123196. doi: 10.1016/j.apcatb.2023.123196
11. [11]
  Ren, Y.; Li, Y.; Pan, G.; Wang, N.; Xing, Y.; Zhang, Z. J. Mater. Sci. Technol. 2023, 171, 162. doi: 10.1016/j.jmst.2023.06.052
12. [12]
  Tang, W.; Luo, L.; Fan, Z.; Zhang, A.; Ma, Y.; Xie, Y.; Zhao, J. Mater. Today Chem. 2024, 37, 102000. doi: 10.1016/j.mtchem.2024.102000
13. [13]
  Cheng, Y.; Kang, J.; Yan, P.; Shen, J.; Chen, Z.; Zhu, X.; Tan, Q.; Shen, L.; Wang, S.; Wang, S. Appl. Catal. B-Environ. 2024, 341, 123325. doi: 10.1016/j.apcatb.2023.123325
14. [14]
  Shin, H.; Kim, S.; Lee, J.; Jeong, H.; Joo, S. W.; Lee, C.-T.; Park, S.-M.; Kang, M. Mater. Today Adv. 2024, 21, 100469. doi: 10.1016/j.mtadv.2024.100469
15. [15]
  Yusuff, A. S.; Popoola, L. T.; Gbadamosi, A. O.; Igbafe, A. I. Mater. Today Commun. 2024, 38, 107999. doi: 10.1016/j.mtcomm.2023.107999
16. [16]
  Shundo, Y.; Nguyen, T. T.; Akrami, S.; Edalati, P.; Itagoe, Y.; Ishihara, T.; Arita, M.; Guo, Q.; Fuji, M.; Edalati, K. J. Colloid Interface Sci. 2024, 666, 22. doi: 10.1016/j.jcis.2024.04.010
17. [17]
  Revathi, M.; Saravanan, S. Inorg. Chem. Commun. 2021, 134, 109056. doi: 10.1016/j.inoche.2021.109056
18. [18]
  Wang, J.; Pan, R.; Yuan, Z.; Hao, Q.; Niu, X.; Wang, R.; Ye, J.; Yang, H. Y.; Wu, Y. Chem. Eng. J. 2024, 481, 148296. doi: 10.1016/j.cej.2023.148296
19. [19]
  Ali, R.; Qureshi, W.; Yaseen, M.; Jiang, H.; Wang, L.; Yang, J.; Liu, Q. Mater. Today Sustain. 2023, 22, 100337. doi: 10.1016/j.mtsust.2023.100337
20. [20]
  Lin, Q.; Liang, S.; Wang, J.; Zhang, R.; Liu, G.; Wang, X. ACS Sustain. Chem. Eng. 2023, 11 (7), 3093. doi: 10.1021/acssuschemeng.2c07255
21. [21]
  Jia, Y.; Wang, Z.; Qiao, X.-Q.; Huang, L.; Gan, S.; Hou, D.; Zhao, J.; Sun, C.; Li, D.-S. Chem. Eng. J. 2021, 424, 130368. doi: 10.1016/j.cej.2021.130368
22. [22]
  Zhu, Q.; Xu, Q.; Du, M.; Zeng, X.; Zhong, G.; Qiu, B.; Zhang, J. Adv. Mater. 2022, 34 (45), 2202929. doi: 10.1001/adma.202202929
23. [23]
  Dong, J.; Fang, W.; Yuan, H.; Xia, W.; Zeng, X.; Shangguan, W. ACS Appl. Energy Mater. 2022, 5 (4), 4893. doi: 10.1021/acsaem.2c00301
24. [24]
  Wu, P.; Liu, H.; Xie, Z.; Xie, L.; Liu, G.; Xu, Y.; Chen, J.; Lu, C.-Z. ACS Appl. Mater. Interfaces 2024, 16 (13), 16601. doi: 10.1021/acsami.3c15957
25. [25]
  Bao, L.; Ali, S.; Dai, C.; Zeng, Q.; Zeng, C.; Jia, Y.; Liu, X.; Wang, P.; Ren, X.; Yang, T. ACS Nano 2024, 18 (7) 5878. doi: 10.1021/acsnano.3c12773
26. [26]
  Xue, S.; Tang, H.; Shen, M.; Liang, X.; Li, X.; Xing, W.; Yang, C.; Yu, Z. Adv. Mater. 2024, 36 (16), 2311937. doi: 10.1002/adma.202311937
27. [27]
  Piña-Pérez, Y.; Samaniego-Benítez, E.; Sierra-Uribe, J. H.; González, F.; Tzompantzi, F.; Lartundo-Rojas, L.; Mantilla, Á. J. Environ. Chem. Eng. 2023, 11 (3), 109760. doi: 10.1016/j.jece.2023.109760
28. [28]
  Sun, H.; Xiao, Z.; Zhao, Z.; Zhai, S.; An, Q. Appl. Surf. Sci. 2023, 611 (Part A), 155631. doi: 10.1016/j.apsusc.2022.155631
29. [29]
  Li, Q.; Yang, S.; Huang, Y.; Liang, Y.; Hu, C.; Wang, M.; Liu, Z.; Tai, Y.; Liu, J.; Li, Y. J. Mater. Sci. Technol. 2024, in press. doi: 10.1016/j.jmst.2024.01.104
30. [30]
  Yan, J.; Wei, L. Acta Phys.-Chim.Sin. 2024, 40 (10), 2312024. doi. 10.3866/PKU.WHXB202312024 doi: 10.3866/PKU.WHXB202312024
31. [31]
  Deng, X.; Zhang, J.; Qi, K.; Liang, G.; Xu, F.; Yu, J. Nat. Commun. 2024, 15 (1), 4807. doi. 10.1038/s41467-024-49004-7 doi: 10.1038/s41467-024-49004-7
32. [32]
  Xu, F.; Meng, K.; Cheng, B.; Wang, S.; Xu, J.; Yu, J. Nat. Commun. 2020, 11 (1), 4613. doi: 10.1038/s41467-020-18350-7
33. [33]
  Fu, J.; Xu, Q.; Low, J.; Jiang, C.; Yu, J. Appl. Catal. B-Environ. 2019, 243, 556. doi: 10.1016/j.apcatb.2018.11.011
34. [34]
  Zhu, B.; Sun, J.; Zhao, Y.; Zhang, L.; Yu, J. Adv. Mater. 2024, 36 (8), 2310600. doi: 10.1002/adma.202310600
35. [35]
  Yu, W.; Bie, C. Acta Phys.-Chim.Sin. 2023, 40 (4), 2307022. doi. 10.3866/PKU.WHXB202307022 doi: 10.3866/PKU.WHXB202307022
36. [36]
  Li, Z.; Liu, W.; Chen, C.; Ma, T.; Zhang, J.; Wang, Z. Acta Phys.-Chim.Sin. 2023, 39 (6), 2208030. doi: 10.3866/PKU.WHXB202208030
37. [37]
  Zhu, J.; Wageh, S.; Al-Ghamdi, A. A. Chin. J. Catal. 2023, 49 (6), 5. doi: 10.1016/S1872-2067(23)64438-9
38. [38]
  Li, T.; Tsubaki, N.; Jin, Z. J. Mater. Sci. Technol. 2024, 169, 82. doi: 10.1016/j.jmst.2023.04.049
39. [39]
  Wu, X.; Chen, G.; Wang, J.; Li, J.; Wang, G. Acta Phys. -Chim. Sin. 2023, 39 (6), 2212016. doi: 10.3866/PKU.WHXB202212016
40. [40]
  Wang, T.; Jin, Z. J. Mater. Sci. Technol. 2023, 155, 132. doi: 10.1016/j.jmst.2023.03.002
41. [41]
  Li, Y.; Shu, S.; Huang, L.; Liu, J.; Liu, J.; Yao, J.; Liu, S.; Zhu, M.; Huang, L. J. Colloid Interf. Sci. 2023, 633, 60. doi: 10.1016/j.jcis.2022.11.058
42. [42]
  Chen, Z.; Ma, T.; Li, Z.; Zhu, W.; Li, L. J. Mater. Sci. Technol. 2024, 179, 198. doi: 10.1016/j.jmst.2023.07.029
43. [43]
  Xiao, L.; Ren, W.; Shen, S.; Chen, M.; Liao, R.; Zhou, Y. Acta Phys.-Chim.Sin. 2024, 40 (8), 2308036. doi: 10.3866/PKU.WHXB202308036
44. [44]
  Hong, S. H.; Kim, Y. K.; Hwang, S.-H.; Seo, H.-J.; Lim, S. K. Int. J. Hydrogen Energ. 2024, 57, 717. doi: 10.1016/j.ijhydene.2024.01.087
45. [45]
  Nowosielska, A. M.; Nikoloski, A. N.; Parsons, D. F. Miner. Eng. 2023, 202, 108236. doi: 10.1016/j.mineng.2023.108236
46. [46]
  Wu, F.; Zhang, X.; Wang, L.; Li, G.; Huang, J.; Song, A.; Meng, A.; Li, Z. Small 2024, 2309439. doi: 10.1002/small.202309439
47. [47]
  Jiang, Z.; Cheng, B.; Zhang, L.; Zhang, Z.; Bie, C. A. Chin. J. Catal. 2023, 52, 32. doi: 10.1016/S1872-2067(23)64502-4
48. [48]
  Liu, B.; Cai, J.; Zhang, J.; Tan, H.; Cheng, B.; Xu, J. Chin. J. Catal. 2023, 51, 204. doi: 10.1016/S1872-2067(23)64466-3
49. [49]
  Bi, L.; Liu, J.; Du, M.; Huang, B.; Song, M.; Jiang, G. Chem. Eng. J. 2023, 454, 140258. doi: 10.1016/j.cej.2022.140258
50. [50]
  Jiang, J.; Ye, K.; Zhang, W.; Ren, H.; Chen, H.; Hu, Y.; Wang, F.; Hou, J.; Diao, G.; Chen, M. J. Mater. Sci. 2022, 57 (47), 21667. doi: 10.1007/s10853-022-07980-5
51. [51]
  Wen, B.; Guo, X.; Liu, Y.; Jin, Z. ACS Appl. Nano Mater. 2024, 7 (6), 6056. doi: 10.1021/acsanm.3c05962
52. [52]
  Sun, H.; Qin, P.; Guo, J.; Jiang, Y.; Liang, Y.; Gong, X.; Ma, X.; Wu, Q.; Zhang, J.; Luo, L. Chem. Eng. J. 2023, 470, 144217. doi: 10.1016/j.cej.2023.144217
53. [53]
  Cheng, C.; Zhang, J.; Zhu, B.; Liang, G.; Zhang, L.; Yu, J. Angew. Chem. Int. Edit. 2023, 62 (8), e202218688. doi: 10.1002/anie.202218688
54. [54]
  Li, L.; Shi, H.; Yu, H.; Tan, X.; Wang, Y.; Ge, S.; Wang, A.; Cui, K.; Zhang, L.; Yu, J. Appl. Catal. B-Environ. 2021, 292, 120184. doi: 10.1016/j.apcatb.2021.120184
55. [55]
  Jiang, L.; Liu, S.; Zhang, D.; Deng, M.; Xia, Z.; Fu, Y.; Lü, C. Mater. Today Chem. 2024, 35, 101875. doi: 10.1016/j.mtchem.2023.101875
56. [56]
  Liu, S.; Wang, W.; Shi, S.; Liao, S.; Zhong, M.; Xiao, W.; Wang, S.; Wang, X.; Chen, C. Appl. Surf. Sci. 2024, 657, 159795. doi: 10.1016/j.apsusc.2024.159795
57. [57]
  Yang, X.; Yang, H.; Zhang, T.; Lou, Y.; Chen, J. Catal. Sci. Technol. 2021, 11 (17), 5849. doi: 10.1039/D1CY00951F
58. [58]
  Wang, X.; Liu, B.; Ma, S.; Zhang, Y.; Wang, L.; Zhu, G.; Huang, W.; Wang, S. Nat. Commun. 2024, 15 (1), 2600. doi: 10.1038/s41467-024-47022-z
59. [59]
  Farhan, S.; Raza, A. H.; Yang, S.; Yu, Z.; Wu, Y. J. Colloid Interface Sci. 2024, 669, 430. doi: 10.1016/j.jcis.2024.04.189.
60. [60]
  Wang, K.; Yang, Y.; Farhan, S.; Wu, Y.; Lin, W.-F. Chem. Eng. J. 2024, 490, 151408. doi: 10.1016/j.cej.2024.151408.
61. [61]
  Jakob, D. S.; Wang, H.; Xu, X. G. ACS Nano 2020, 14 (4), 4839. doi: 10.1021/acsnano.0c00767
62. [62]
  Zhou, J.; Zhang, J.; Deng, Y.; Zhao, H.; Zhang, P.; Fu, S.; Xu, X.; Li, H. Nano Energy 2022, 99, 107411. doi: 10.1016/j.nanoen.2022.107411
63. [63]
  Bie, C.; Meng, Z.; He, B.; Cheng, B.; Liu, G.; Zhu, B. J. Mater. Sci. Technol. 2024, 173, 11. doi: 10.1016/j.jmst.2023.07.019
64. [64]
  Yang, S.; Wang, K.; Wu, Z.; Wu, Y. J. Mater. Sci. Technol. 2024, 200, 253. doi: 10.1016/j.jmst.2024.02.055.
65. [65]
  Chen, Y.; Ma, M.; Hu, J.; Chen, Z.; Jiang, P.; Amirav, L.; Yang, S.; Xing, Z. Appl. Catal. B-Environ. 2023, 324, 122300. doi: 10.1016/j.apcatb.2022.122300
66. [66]
  Sun, Y.; Shen, S.; Deng, W.; Tian, G.; Xiong, D.; Zhang, H.; Yang, T.; Wang, S.; Chen, J.; Yang, W. Nano Energy 2023, 105, 108024. doi: 10.1016/j.nanoen.2022.108024
67. [67]
  Wang, N.; Pu, M.; Ma, Z.; Feng, Y.; Guo, Y.; Guo, W.; Zheng, Y.; Zhang, L.; Wang, Z.; Feng, M. Nano Energy 2021, 90, 106646. doi: 10.1016/j.nanoen.2021.106646
68. [68]
  Zhang, W.; Xu, Q.; Tang, X.; Jiang, H.; Shi, J.; Fominski, V.; Bai, Y.; Chen, P.; Zou, J. J. Colloid Interface Sci. 2023, 649, 325. doi: 10.1016/j.jcis.2023.06.080.
69. [69]
  Patel, M.; Song, J.; Kim, D.-W.; Kim, J. Appl. Mater. Today 2022, 26, 101344. doi: 10.1016/j.apmt.2021.101344
70. [70]
  Vishwakarma, M.; Kumar, M.; Hendrickx, M.; Hadermann, J.; Singh, A. P.; Batra, Y. Adv. Mater. Interfaces 2021, 8 (10), 2002124. doi: 10.1002/admi.202002124
71. [71]
  Chen, X.; Guo, R.-T.; Pan, W.-G.; Yuan, Y.; Hu, X.; Bi, Z.-x.; Wang, J. Appl. Catal. B-Environ. 2022, 318, 121839. doi: 10.1016/j.apcatb.2022.121839
72. [72]
  Ruan, X.; Meng, D.; Huang, C.; Xu, M.; Jiao, D.; Cheng, H.; Cui, Y.; Li, Z.; Ba, K.; Xie, T. Adv. Mater. 2024, 36 (9), 2309199. doi: 10.1002/adma.202309199
73. [73]
  Ruan, X.; Huang, C.; Cheng, H.; Zhang, Z.; Cui, Y.; Li, Z.; Xie, T.; Ba, K.; Zhang, H.; Zhang, L. Adv. Mater. 2023, 35 (6), 2209141. doi: 10.1002/adma.202209141

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂

通讯作者: 吴艳, wuyan@cug.edu.cn

English

Double S-Scheme ZnS/ZnO/CdS Heterostructure Photocatalyst for Efficient Hydrogen Production

Corresponding author: Yan Wu, Email: wuyan@cug.edu.cn; Tel: +86-13517286716

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂

通讯作者: 吴艳, wuyan@cug.edu.cn

English

Double S-Scheme ZnS/ZnO/CdS Heterostructure Photocatalyst for Efficient Hydrogen Production

Corresponding author: Yan Wu, Email: wuyan@cug.edu.cn; Tel: +86-13517286716

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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