Citation: Chenye An, Sikandaier Abiduweili, Xue Guo, Yukun Zhu, Hua Tang, Dongjiang Yang. Hierarchical S-scheme Heterojunction of Red Phosphorus Nanoparticles Embedded Flower-like CeO₂ Triggering Efficient Photocatalytic Hydrogen Production[J]. Acta Physico-Chimica Sinica, ;2024, 40(11): 240501. doi: 10.3866/PKU.WHXB202405019 shu

Hierarchical S-scheme Heterojunction of Red Phosphorus Nanoparticles Embedded Flower-like CeO₂ Triggering Efficient Photocatalytic Hydrogen Production

Chenye An ¹ ,
Sikandaier Abiduweili ¹ ,
Xue Guo ¹ ,
Yukun Zhu ^1,, ,
Hua Tang ^1,, ,
Dongjiang Yang ^{1, 2,,}

1.
School of Environmental Science and Engineering, Qingdao University, Qingdao 266071, Shandong Province, China
2.
Institute of Micro/Nano Materials and Devices, Ningbo University of Technology, Ningbo 315211, Zhejiang Province, China

Corresponding author: Yukun Zhu, yukunzhu@qdu.edu.cn Hua Tang, tanghua@qdu.edu.cn Dongjiang Yang, d.yang@qdu.edu.cn
Received Date: 23 May 2024
Revised Date: 21 June 2024
Accepted Date: 24 June 2024
Available Online: 28 June 2024
Fund Project: the National Natural Science Foundation of China 52102362the National Natural Science Foundation of China 22378219the National Natural Science Foundation of China 52302097Taishan Scholar Program of Shandong Province ts201712030Taishan Scholar Program of Shandong Province tsqn201909102Taishan Scholar Program of Shandong Province tstp20230665Shandong Provincial Natural Science Foundation ZR2021QB022Shandong Provincial Natural Science Foundation ZR2021ME012Shandong Provincial Natural Science Foundation ZR2022QE036Technology Support Program for Youth Innovation Team of Shandong Universities 2023KJ225

Designing heterojunctions using two semiconductors with aligned band structures is a promising strategy for solar energy-driven photocatalytic hydrogen production. Particularly, S-scheme heterojunctions exhibit significant promise for accelerating spatial separation and migration of photoexcited charge carriers while maintaining strong redox capacity. Herein, a hierarchical S-scheme composite of red phosphorus (RP) nanoparticles decorated flower-like CeO₂ (CeO₂/RP) was synthesized via the chemical vapor deposition process. Under simulated solar light irradiation, the optimized CeO₂/RP S-scheme heterojunction exhibited a highly efficient photocatalytic hydrogen production rate of 297.8 μmol·h^-1·g^-1, which is approximately 8.8 and 5.7 times greater than that of pure CeO₂ and RP, respectively. After decoration with RP, the optical absorption of CeO₂/RP is greatly expanded to the visible light region. The effective photocatalytic performance can be primarily attributed to the presence of interfacial P-O-Ce bonds providing charge transfer pathways, as well as the development of a built-in electric field between CeO₂ and RP at the intimate interface. The photogenerated electrons follow an S-scheme mechanism, the electric field drives directional charge transfer from the conduction band (CB) of CeO₂ to the valence band (VB) of RP upon exposure to light, thus enabling the retention of photoexcited electrons and holes with higher redox potential at the CB of RP and the VB of CeO₂, respectively. This work provides a novel vision in the fabrication of S-scheme photocatalytic heterojunction systems with great photocatalytic hydrogen production performance.
- Red phosphorus,
- CeO₂,
- S-scheme heterojunction,
- Hydrogen production,
- Photocatalyst
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Hierarchical S-scheme Heterojunction of Red Phosphorus Nanoparticles Embedded Flower-like CeO2 Triggering Efficient Photocatalytic Hydrogen Production

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通讯作者: 陈斌, bchen63@163.com

Hierarchical S-scheme Heterojunction of Red Phosphorus Nanoparticles Embedded Flower-like CeO₂ Triggering Efficient Photocatalytic Hydrogen Production