Citation: Zhuo Wang, Xue Bai, Kexin Zhang, Hongzhi Wang, Jiabao Dong, Yuan Gao, Bin Zhao. MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除[J]. Acta Physico-Chimica Sinica, ;2025, 41(3): 240500. doi: 10.3866/PKU.WHXB202405002 shu

MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除

School of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai 200093, China

Received Date: 1 May 2024
Revised Date: 24 May 2024
Accepted Date: 31 May 2024

Fund Project: The project was supported by the National Natural Science Foundation of China (22209114), the Chenguang Program of Shanghai Education Development Foundation and Shanghai Municipal Education Commission (21CGA56), the Natural Science Foundation of Shanghai (21ZR1445700), the Shanghai Sailing Program (21YF1430800).

电极材料在电容去离子技术中起到决定性作用，影响着盐离子的去除和电荷储存能力。本文通过碳化MOF-5和三聚氰胺的混合物，成功制备了氮掺杂的分级多孔碳，其中三聚氰胺起着氮源和造孔剂的双重作用。通过优化碳化温度，得到的MOF-5衍生纳米多孔碳(NPC-800)，其不但保持着MOF-5原始的立方体形貌、还具有大的比表面积、高氮含量和良好的润湿性。NPC-800电极在0.2 A·g^-1电流密度下具有91.8 mAh·g^-1的高比容量。在5 A·g^-1的电流密度下循环50000次，容量保持率为100%，展现出超长的循环稳定性。在500 mg·L^-1的NaCl溶液，施加恒压1.2 V，NPC-800电极具有高的脱盐容量24.17 mg·g^-1，快的脱盐速度2.8 mg·g^-1·min^-1和较稳定的再生循环能力。因此，以金属有机框架为模板合成氮掺杂的碳材料，能够有效增强钠离子的电化学储存和去除能力，有望成为电容去离子电极材料的最佳选择。
- Metal-organic framework,
- Electrochemical property,
- Sodium ion storage,
- Capacitive deionization,
- Energy storage mechanism
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