Citation: Jiaxuan Zuo, Kun Zhang, Jing Wang, Xifei Li. 锂离子电池Ni-Co-Mn基正极材料前驱体的形核调控及机制[J]. Acta Physico-Chimica Sinica, ;2025, 41(1): 240404. doi: 10.3866/PKU.WHXB202404042 shu

锂离子电池Ni-Co-Mn基正极材料前驱体的形核调控及机制

Jiaxuan Zuo ¹ ,
Kun Zhang ² ,
Jing Wang ¹ ,
Xifei Li ^1,3,4,,

1.
Institute of Advanced Electrochemical Energy, School of Materials Science and Engineering, Xi'an University of Technology, Xi'an 710048, China;
2.
GEM Co., Ltd., Shenzhen 518101, Guangdong Province, China;
3.
Guangdong Yuanneng Technologies Co., Ltd., Foshan 528223, Guangdong Province, China;
4.
Qinghai Provincial Key Laboratory of Nanomaterials and Nanotechnology, Qinghai Minzu University, Xining 810007, China

Corresponding author: Xifei Li, xfli@xaut.edu.cn
Received Date: 29 April 2024
Revised Date: 11 June 2024
Accepted Date: 13 June 2024

Fund Project: The project was supported by the Key Research and Development Program of Shaanxi (2024GH-ZDXM-02), Foshan Science and Technology Innovation Team Project (1920001004098) and University-level Principle Investigator (PI) team of Qinghai Minzu University.

三元正极材料具有较高的放电比容量、倍率性能和工作电压，成为锂离子电池正极材料代表之一。三元正极材料由前驱体经过嵌锂烧结拓扑转变而来，因此，前驱体材料直接决定了三元正极材料的电池性能。针对前驱体可控均匀沉淀需求和对共沉淀过程参数变化极度敏感特性，本综述首先阐述络合调控实现Ni、Co、Mn元素均匀共沉淀，及沉淀物过饱和度诱导溶液体系不同形核状态基本原理，其次从晶面择优生长结合溶解-再结晶模型讨论了前驱体一次颗粒和二次颗粒生长模式，最后从实际生产角度，基本涵盖共沉淀过程所有可调参数，并深入讨论了各种参数由低到高变化对共沉淀反应形核及前驱体材料理化性能的影响。本综述阐释的相关理论及规律可进一步延伸至富锂锰基前驱体、单晶用前驱体以及径向排列织构前驱体等高端产品研发。
- Hydroxide precursor,
- Co-precipitation reaction,
- Supersaturation,
- Heterogeneous nucleation,
- Homogeneous nucleation,
- Reaction parameter
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