Citation: Yangrui Xu, Yewei Ren, Xinlin Liu, Hongping Li, Ziyang Lu. NH₂-UIO-66 Based Hydrophobic Porous Liquid with High Mass Transfer and Affinity Surface for Enhancing CO₂ Photoreduction[J]. Acta Physico-Chimica Sinica, ;2024, 40(11): 240303. doi: 10.3866/PKU.WHXB202403032 shu

NH₂-UIO-66 Based Hydrophobic Porous Liquid with High Mass Transfer and Affinity Surface for Enhancing CO₂ Photoreduction

Yangrui Xu ¹ ,
Yewei Ren ¹ ,
Xinlin Liu ^2,, ,
Hongping Li ³ ,
Ziyang Lu ^{1, 4,,}

1.
Institute of Environmental Health and Ecological Security, School of Emergency Management, School of the Environment and Safety Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu Province, China
2.
School of Energy and Power Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu Province, China
3.
Institute for Energy Research, Jiangsu University, Jiangsu, Zhenjiang 212013, Jiangsu Province, China
4.
Jiangsu Collaborative Innovation Center of Technology and Material of Water Treatment, Suzhou University of Science and Technology, Suzhou 215009, Jiangsu Province, China

Corresponding author: Xinlin Liu, liuxl@ujs.edu.cn Ziyang Lu, luziyang126@126.com
Received Date: 28 March 2024
Revised Date: 2 May 2024
Accepted Date: 6 May 2024
Available Online: 13 May 2024
Fund Project: the National Natural Science Foundation of China 22278190Zhenjiang Carbon Emissions Peak/Carbon Neutrality Science and Technology Innovation Special Fund Project CQ2022009Open Project of State Key Laboratory of Structural Chemistry 20230022Qing Lan Project of Jiangsu Province 2023Jiangsu Collaborative Innovation Center of Technology and Material of Water Treatment, Project of Research on Educational Reform and Talent Development of School of Emergency Management of Jiangsu University JG-03-11the Special Scientific Research Project of School of Emergency Management of Jiangsu University KY-C-12

Increasing the CO₂ concentration on the surface of the photocatalysts helps to increase the reaction dynamic rate of the photocatalytic CO₂ reduction. However, the low solubility and poor mass transfer of CO₂ in aqueous phase seriously hinder the adsorption and conversion of CO₂ at the active site. In this work, the porous liquid photocatalyst (NH₂-UIO-66 PL) with strong hydrophobicity has been synthesized by grafting the hydrophobic liquid end long-chain (PDMS) onto the amino site of metal-organic framework (NH₂-UIO-66). It is found that the NH₂-UIO-66 PL with permanent porosity causes a large amount of CO₂ to be concentrated in the porous liquid cavity for transporting and diffusing CO₂ onto the photocatalyst surface rapidly, and then the CO₂ affinity surface with high positive potential and key intermediates for activation reduction reactions are formed with the grafting of hydrophobic PDMS, leading to stronger electron enrichment Zr active sites for enhancement of the overall CO₂ reduction ability. As a result, NH₂-UIO-66 PL achieved CO₂ photoreduction with a CO yield of 24.70 μmol∙g⁻¹∙h⁻¹ and CH₄ yield of 7.93 μmol∙g⁻¹∙h⁻¹, which is 2.3-fold and 2.7-fold compared to hydrophilic NH₂-UIO-66, respectively. This research provides a novel design of hydrophobic porous liquids to provide industrial possibilities for high CO₂ adsorption and reduction.
- Porous liquids,
- UIO-66,
- Hydrophobic surface,
- CO₂ transport channel,
- CO₂ photoreduction
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NH2-UIO-66 Based Hydrophobic Porous Liquid with High Mass Transfer and Affinity Surface for Enhancing CO2 Photoreduction

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NH₂-UIO-66 Based Hydrophobic Porous Liquid with High Mass Transfer and Affinity Surface for Enhancing CO₂ Photoreduction