Citation: Ke Li, Chuang Liu, Jingping Li, Guohong Wang, Kai Wang. Architecting Inorganic/Organic S-Scheme Heterojunction of Bi₄Ti₃O₁₂ Coupling with g-C₃N₄ for Photocatalytic H₂O₂ Production from Pure Water[J]. Acta Physico-Chimica Sinica, ;2024, 40(11): 240300. doi: 10.3866/PKU.WHXB202403009 shu

Architecting Inorganic/Organic S-Scheme Heterojunction of Bi₄Ti₃O₁₂ Coupling with g-C₃N₄ for Photocatalytic H₂O₂ Production from Pure Water

Ke Li ^{1, †} ,
Chuang Liu ^{1, †} ,
Jingping Li ¹ ,
Guohong Wang ^1,, ,
Kai Wang ^{1, 2, 3,,}

1.
Hubei Key Laboratory of Pollutant Analysis and Reuse Technology, College of Chemistry and Chemical Engineering, Huangshi Key Laboratory of Prevention and Control of Soil Pollution, Hubei Normal University, Huangshi 435002, Hubei Province, China
2.
Engineering Research Center for Clean Production of Textile Printing and Dyeing, Ministry of Education, Wuhan Textile University, Wuhan 430073, China
3.
School of Chemistry, Chemical Engineering and Biotechnology, Nanyang Technological University, 62 Nanyang Drive, Singapore 637459, Singapore

Corresponding author: Guohong Wang, wanggh2003@163.com Kai Wang, wangkai@hbnu.edu.cn

^†

Received Date: 12 March 2024
Revised Date: 8 April 2024
Accepted Date: 8 April 2024
Available Online: 11 April 2024
Fund Project: the National Natural Science Foundation of China 22378104the National Natural Science Foundation of China 52104254the Open Subject of Engineering Research Center for Clean Production of Textile Printing and Dyeing, Ministry of Education 2023GCZX008

Hydrogen peroxide (H₂O₂) plays a significant role as an industrial chemical and potential energy carrier. However, common H₂O₂ photosynthesis catalysts face challenges such as limited solar spectrum absorption, severe agglomeration, and difficulty in reuse, hindering their widespread application. In this study, an inorganic/organic heterojunction photocatalyst comprising g-C₃N₄ nanosheets and Bi₄Ti₃O₁₂ nanofibers is synthesized using electrospinning assisted self-assembly methods. The Bi₄Ti₃O₁₂/g-C₃N₄ heterojunction exhibits significantly enhanced H₂O₂ yield of 1650 μmol∙g⁻¹∙h⁻¹ and efficient H₂O₂ photosynthesis directly from pure water. The improved performance is attributed to enhanced visible light absorption, charge separation efficiency, and boosting redox properties of photoinduced carriers in S-scheme heterojunctions. Additionally, the utilization of in situ X-ray photoelectron spectroscopy (ISXPS) enables the investigation of the S-scheme mechanism and dynamics of inorganic/organic Bi₄Ti₃O₁₂/g-C₃N₄ heterojunctions. This research presents a novel approach for designing inorganic/organic heterojunction photocatalysts for solar-driven H₂O₂ production.
- Heterojunction,
- Photocatalysis,
- Hydrogen peroxide production,
- S-scheme mechanism
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Architecting Inorganic/Organic S-Scheme Heterojunction of Bi4Ti3O12 Coupling with g-C3N4 for Photocatalytic H2O2 Production from Pure Water

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通讯作者: 陈斌, bchen63@163.com

Architecting Inorganic/Organic S-Scheme Heterojunction of Bi₄Ti₃O₁₂ Coupling with g-C₃N₄ for Photocatalytic H₂O₂ Production from Pure Water