Citation: Qin Li, Huihui Zhang, Huajun Gu, Yuanyuan Cui, Ruihua Gao, Wei-Lin Dai. In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution[J]. Acta Physico-Chimica Sinica, ;2025, 41(4): 240201. doi: 10.3866/PKU.WHXB202402016 shu

In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution

Qin Li ¹ ,
Huihui Zhang ¹ ,
Huajun Gu ¹ ,
Yuanyuan Cui ³ ,
Ruihua Gao ^2,, ,
Wei-Lin Dai ^1,,

1.
Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, China
2.
State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai 200433, China
3.
Shimadzu China Co LTD, Shanghai 200436, China

Corresponding author: Ruihua Gao, Wei-Lin Dai, wldai@fudan.edu.cn
Received Date: 19 February 2024
Revised Date: 3 April 2024
Accepted Date: 3 April 2024

Fund Project: the National Key Research and Development Program of China 2021YFA1501404Natural Science Foundation of Shanghai 22ZR1404200National Natural Science Foundation of China 21373054Natural Science Foundation of Shanghai Science and Technology Committee 19DZ2270100

Against the backdrop of energy scarcities and ecological concerns, the process of photocatalytic hydrogen evolution emerges as a critical method for transforming solar energy into chemical energy. Central to this technology is the crafting of photocatalysts that are not only efficient and durable but also economically viable. The key to creating photocatalysts that boast superior hydrogen production capabilities lies in enhancing the separation and transfer of photo-generated electrons and holes. This study introduces a binary heterojunction photocatalyst, featuring a combination of Cd_0.5Zn_0.5S and Ti₃C₂ MXene, synthesized via an in situ hydrothermal method. In the composite, slender Cd_0.5Zn_0.5S nanorods are uniformly coated over the surface of single layer Ti₃C₂ nanosheets, forming a Schottky heterojunction at the material interface. This structure enhances the separation efficiency of photo-generated electrons and holes, thereby improving the utilization of light. With 0.5 wt% (mass fraction) of Ti₃C₂ MXene incorporated, we observed a peak photocatalytic H₂ generation rate of 15.56 mmol∙g⁻¹∙h⁻¹, outperforming the baseline Cd_0.5Zn_0.5S by 2.56 times. Notably, the photocatalytic efficiency remained largely unchanged after five cycles. This composite achieved the highest apparent quantum efficiency (AQE) of 18.4% when exposed to 350 nm UV light. Various characterization techniques, including in situ X-ray photoelectron spectroscopy (XPS) and femtosecond transient absorption (fs-TA) spectroscopy, along with density functional theory (DFT) calculations, have further substantiated that the formation of a Schottky heterojunction at the interface is crucial for enhancing the photocatalytic hydrogen evolution performance of the composite material. This paper demonstrates the effectiveness of the novel carbon based material MXene as a co-catalyst for improving the performance of photocatalysts and offers a viable approach for the construction of MXene-containing photocatalytic hydrogen evolution catalysts.
- Cd_1-xZn_xS nanorods,
- Photocatalysis,
- Hydrogen evolution,
- Ti₃C₂ MXene nanosheet,
- Heterojunction
1. [1]
  Wang, Z.; Li, C.; Domen, K. Chem. Soc. Rev. 2019, 48(7), 2109. doi: 10.1039/C8CS00542G doi: 10.1039/C8CS00542G
2. [2]
  Chen, X.; Shen, S.; Guo, L.; Mao, S. S. Chem. Rev. 2010, 110 (11), 6503. doi: 10.1021/cr1001645 doi: 10.1021/cr1001645
3. [3]
  Fujishima, A.; Honda, K. Nature 1972, 238 (5358), 37. doi: 10.1038/238037a0 doi: 10.1038/238037a0
4. [4]
  Wang, X.; Maeda, K.; Thomas, A.; Takanabe, K.; Xin, G.; Carlsson, J. M.; Domen, K.; Antonietti, M. Nat. Mater. 2009, 8, 76. doi: 10.1038/nmat2317 doi: 10.1038/nmat2317
5. [5]
  Liu, J.; Liu, Y.; Liu, N.; Han, Y.; Zhang, X.; Huang, H.; Lifshitz, Y.; Lee, S. -T.; Zhong, J.; Kang, Z. Science 2015, 347 (6225), 970. doi: 10.1126/science.aaa3145 doi: 10.1126/science.aaa3145
6. [6]
  Song, Y.; Li, Z.; Zhu, Y.; Feng, X.; Chen, J. S.; Kaufmann, M.; Wang, C.; Lin, W. J. Am. Chem. Soc. 2019, 141 (31), 12219. doi: 10.1021/jacs.9b05964 doi: 10.1021/jacs.9b05964
7. [7]
  Kumar, D.P.; Hong, S.; Reddy, D. A.; Kim, T. K. Appl. Catal. B-Environ. 2017, 212, 7. doi: 10.1016/j.apcatb.2017.04.065 doi: 10.1016/j.apcatb.2017.04.065
8. [8]
  Zhang, Q.; Wang, X.; Zhang, J.; Li, L.; Gu, H.; Dai, W. -L. J. Colloid Interface Sci. 2021, 590, 632. doi: 10.1016/j.jcis.2021.01.083 doi: 10.1016/j.jcis.2021.01.083
9. [9]
  Zhang, L.; Ding, N.; Lou, L.; Iwasaki, K.; Wu, H.; Luo, Y.; Li, D.; Nakata, K.; Fujishima, A.; Meng, Q. Adv. Funct. Mater. 2019, 29 (3), 1806774. doi: 10.1002/adfm.201806774 doi: 10.1002/adfm.201806774
10. [10]
  Zhang, L.; Cui, Y.; Yang, F.; Zhang, Q.; Zhang, J.; Cao, M.; Dai, W. -L. J. Mater. Sci. Technol. 2020, 45, 176. doi: 10.1016/j.jmst.2019.11.020 doi: 10.1016/j.jmst.2019.11.020
11. [11]
  Wang, J.; Shen, Y.; Liu, S.; Zhang, Y. Appl. Catal. B-Environ. 2020, 270, 118885. doi: 10.1016/j.apcatb.2020.118885 doi: 10.1016/j.apcatb.2020.118885
12. [12]
  Shehzad, N.; Tahir, M.; Johari, K.; Murugesan, T.; Hussain, M. Appl. Surf. Sci. 2019, 463, 445. doi: 10.1016/j.apsusc.2018.08.250 doi: 10.1016/j.apsusc.2018.08.250
13. [13]
  Cadiau, A.; Kolobov, N.; Srinivasan, S.; Goesten, M. G.; Haspel, H.; Bavykina, A. V.; Tchalala, M. R.; Maity, P.; Goryachev, A.; Poryvaev, A. S.; et al. Angew. Chem. -Int. Ed. 2020, 59 (32), 13468. doi: 10.1002/anie.202000158 doi: 10.1002/anie.202000158
14. [14]
  Zhu, Y. -P.; Yin, J.; Abou-Hamad, E.; Liu, X.; Chen, W.; Yao, T.; Mohammed, O. F.; Alshareef, H. N. Adv. Mater. 2020, 32 (16), 1906368. doi: 10.1002/adma.v32.1610.1002/adma.201906368 doi: 10.1002/adma.v32.1610.1002/adma.201906368
15. [15]
  Zhou, P.; Zhang, Q.; Xu, Z.; Shang, Q.; Wang, L.; Chao, Y.; Li, Y.; Chen, H.; Lv, F.; Zhang, Q.; et al. Adv. Mater. 2020, 32 (7), 1904249. doi: 10.1002/adma.201904249 doi: 10.1002/adma.201904249
16. [16]
  Ruan, D.; Fujitsuka, M.; Majima, T. Appl. Catal. B-Environ. 2020, 264, 118541. doi: 10.1016/j.apcatb.2019.118541 doi: 10.1016/j.apcatb.2019.118541
17. [17]
  Tian, L.; Min, S.; Wang, F. Appl. Catal. B-Environ. 2019, 259, 118029. doi: 10.1016/j.apcatb.2019.118029 doi: 10.1016/j.apcatb.2019.118029
18. [18]
  Yue, X.; Yi, S. Wang, R.; Zhang, Z.; Qiu, S. Appl. Catal. B-Environ. 2018, 224, 17. doi: 10.1016/j.apcatb.2017.10.010 doi: 10.1016/j.apcatb.2017.10.010
19. [19]
  Luo, Z.; Zhao, X.; Zhang, H.; Jiang, Y. Appl. Catal. A-Gen. 2019, 582, 117115. doi: 10.1016/j.apcata.2019.117115 doi: 10.1016/j.apcata.2019.117115
20. [20]
  Huang, H. -B.; Fang, Z. -B.; Yu, K.; Lü, J.; Cao, R. J. Mater. Chem. A 2020, 8 (7), 3882. doi: 10.1039/C9TA13836F doi: 10.1039/C9TA13836F
21. [21]
  Li, Q.; Meng, H.; Zhou, P.; Zheng, Y.; Wang, J.; Yu, J. ; Gong, J. ACS Catal. 2013, 3 (5), 882. doi: 10.1021/cs4000975 doi: 10.1021/cs4000975
22. [22]
  Hou, Y.; Laursen, A. B.; Zhang, J.; Zhang, G.; Zhu, Y.; Wang, X.; Dahl, S.; Chorkendorff, I. Angew. Chem. -Int. Ed. 2013, 52 (13), 3621. doi: 10.1002/anie.201210294 doi: 10.1002/anie.201210294
23. [23]
  Naguib, M.; Kurtoglu, M.; Presser, V.; Lu, J.; Niu, J.; Min, H.; Hultman, L.; Gogotsi, Y.; Barsoum, M.W. Adv. Mater. 2011, 23 (37), 4248. doi: 10.1002/adma.201102306 doi: 10.1002/adma.201102306
24. [24]
  Zhang, Q.; Lai, H.; Fan, R.; Ji, P.; Fu, X.; Li, H. ACS Nano2021, 15 (3), 5249. doi: 10.1021/acsnano.0c10671 doi: 10.1021/acsnano.0c10671
25. [25]
  Zhang, Q.; Fan, R.; Cheng, W.; Ji, P.; Sheng, J.; Liao, Q.; Lai, H.; Fu, X.; Zhang, C.; Li, H. Adv. Sci. 2022, 9 (28), 2202748. doi: 10.1002/advs.202202748 doi: 10.1002/advs.202202748
26. [26]
  Zhang, Q.; Zhang, Z.; Zhao, D.; Wang, L.; Li, H.; Zhang, F.; Huo, Y.; Li, H. Appl. Catal. B-Environ. 2023, 320, 122009. doi: 10.1016/j.apcatb.2022.122009 doi: 10.1016/j.apcatb.2022.122009
27. [27]
  Tang, X.; Zhou, D., Li, P.; Guo, X.; Sun, B.; Liu, H.; Yan, K.; Gogotsi, Y.; Wang, G. Adv. Mater. 2020, 32 (4), 1906739. doi: 10.1002/adma.201906739 doi: 10.1002/adma.201906739
28. [28]
  Zhang, Q.; He, J.; Fu, X.; Xie, S.; Fan, R.; Lai, H.; Cheng, W.; Ji, P.; Sheng, J.; Liao, Q.; Zhu, W.; Li, H. Chem. Eng. J. 2022, 430, 132950. doi: 10.1016/j.cej.2021.132950 doi: 10.1016/j.cej.2021.132950
29. [29]
  Zhou, Y.; Maleski, K.; Anasori, B.; Thostenson, J.O.; Pang, Y.; Feng, Y.; Zeng, K.; Parker, C. B.; Zauscher, S.; Gogotsi, Y.; Glass, J. T.; Cao, C. ACS Nano 2020, 14 (3), 3576. doi: 10.1021/acsnano.9b10066 doi: 10.1021/acsnano.9b10066
30. [30]
  Li, Y.; Yin, Z.; Ji, G.; Liang, Z.; Xue, Y.; Guo, Y.; Tian, J.; Wang, X.; Cui, H. Appl. Catal. B-Environ. 2019, 246, 12. doi: 10.1016/j.apcatb.2019.01.051 doi: 10.1016/j.apcatb.2019.01.051
31. [31]
  Wu, Y.; Li, X.; Yang, Q.; Wang, D.; Yao, F.; Cao, J.; Chen, Z.; Huang, X.; Yang, Y.; Li, X. Chem. Eng. J. 2020, 390, 124519. doi: 10.1016/j.cej.2020.124519 doi: 10.1016/j.cej.2020.124519
32. [32]
  Cheng, L.; Chen, Q.; Li, J.; Liu, H. Appl. Catal. B-Environ. 2020, 267, 118379. doi: 10.1016/j.apcatb.2019.118379 doi: 10.1016/j.apcatb.2019.118379
33. [33]
  Shao, M.; Shao, Y.; Chai, J.; Qu, Y.; Yang, M.; Wang, Z.; Yang, M.; Ip, W. F.; Kwok, C. T.; Shi, X.; et al. J. Mater. Chem. A 2017, 5, 16748. doi: 10.1039/C7TA04122E doi: 10.1039/C7TA04122E
34. [34]
  Kwon, N. H.; Shin, S. -J.; Jin, X.; Jung, Y.; Hwang, G. -S.; Kim, H.; Hwang, S. -J. Appl. Catal. B-Environ. 2020, 277, 19191. doi: 10.1016/j.apcatb.2020.119191 doi: 10.1016/j.apcatb.2020.119191
35. [35]
  Huang, Y.; Mei, F.; Zhang, J.; Dai, K.; Dawson, G. Acta Phys. -Chim. Sin. 2022, 38 (7), 2108028. doi: 10.3866/PKU.WHXB202108028 doi: 10.3866/PKU.WHXB202108028
36. [36]
  Yang, H.; Dai, K.; Zhang, J.; Dawson, G. Chin. J. Catal. 2022, 43 (8), 2111. doi: 10.1016/S1872-2067(22)64096-8 doi: 10.1016/S1872-2067(22)64096-8
37. [37]
  Wang, Z.; Wang, J.; Zhang, J.; Dai, K. Acta Phys. -Chim. Sin. 2023, 39 (6), 2209037. doi: 10.3866/PKU.WHXB202209037 doi: 10.3866/PKU.WHXB202209037
38. [38]
  Hua, J.; Wang, Z.; Zhang, J.; Dai, K.; Shao, C.; Fan, K. J. Mater. Sci. Technol. 2023, 156, 64. doi: 10.1016/j.jmst.2023.03.003 doi: 10.1016/j.jmst.2023.03.003
39. [39]
  Zhao, Z.; Wang, Z.; Zhang, J.; Shao, C.; Dai, K.; Fan, K.; Liang, C. Adv. Funct. Mater. 2023, 33, 2214470. doi: 10.1002/adfm.202214470 doi: 10.1002/adfm.202214470
40. [40]
  Zhang, H.; Wang, Z.; Zhang, J.; Dai, K. Chin. J. Catal. 2023, 49, 42. doi: 10.1016/S1872-2067(23)64444-4 doi: 10.1016/S1872-2067(23)64444-4
41. [41]
  Li, Y. -H.; Zhang, F.; Chen, Y.; Li, J. -Y.; Xu, Y. -J. Green. Chem. 2020, 22, 163. doi: 10.1039/c9gc03332g doi: 10.1039/c9gc03332g
42. [42]
  Li, Z.; Huang, W.; Liu, J.; Lv, K.; Li, Q. ACS Catal. 2021, 11 (14), 8510. doi: 10.1021/acscatal.1c02018 doi: 10.1021/acscatal.1c02018
43. [43]
  Gu, H.; Zhang, H.; Wang, X.; Li, Q.; Chang, S.; Huang, Y.; Gao, L.; Cui, Y.; Liu, R.; Dai, W. -L. Appl. Catal. B-Environ. 2023, 328, 122537. doi: 10.1016/j.apcatb.2023.122537 doi: 10.1016/j.apcatb.2023.122537
44. [44]
  Sun, B.; Qiu, P.; Liang, Z.; Xue, Y.; Zhang, X.; Yang, L.; Cui, H.; Tian, J. Chem. Eng. J. 2021, 406, 127177. doi: 10.1016/j.cej.2020.127177 doi: 10.1016/j.cej.2020.127177
45. [45]
  Xiao, R.; Zhao, C.; Zou, Z.; Chen, Z.; Tian, L.; Xu, H.; Tang, H.; Liu, Q.; Lin, Z.; Yang, X. Appl. Catal. B-Environ. 2020, 268, 118382. doi: 10.1016/j.apcatb.2019.118382 doi: 10.1016/j.apcatb.2019.118382
46. [46]
  Saini, B.; Laishram, H. K. D.; Krishnapriya, R.; Singhal, R.; Sharma, R. K. ACS Appl. Nano Mater. 2022, 5 (7), 9319. doi: 10.1021/acsanm.2c01639 doi: 10.1021/acsanm.2c01639
47. [47]
  Zhu, S. -C.; Li, S.; Tang, B.; Liang, H.; Liu, B. -J.; Xiao, G.; Xiao, F. -X. J. Catal. 2021, 404, 56. doi: 10.1016/j.jcat.2021.09.001 doi: 10.1016/j.jcat.2021.09.001
48. [48]
  Zhu, S. -C.; Wang, Z. -C.; Tang, B.; Liang, H.; Liu, B. -J.; Li, S.; Chen, Z.; Cheng, N. C.; Xiao, F. -X. J. Mater. Chem. A 2022, 10, 11926. doi: 10.1039/D2TA02755K doi: 10.1039/D2TA02755K
49. [49]
  He, F.; Zhu, B.; Cheng, B.; Yu, J.; Ho, W.; Macyk, W. Appl. Catal. B- Environ. 2020, 272, 119006. doi: 10.1016/j.apcatb.2020.119006 doi: 10.1016/j.apcatb.2020.119006
50. [50]
  Huang, W.; Li, Z.; Wu, C.; Zhang, H.; Sun, J.; Li, Q. J. Mater. Sci. Technol. 2022, 120, 89. doi: 10.1016/j.jmst.2021.12.028 doi: 10.1016/j.jmst.2021.12.028
51. [51]
  Huang, W. -X.; Li, Z. -P.; Li, D. -D.; Hu, Z. -H.; Wu, C.; Lv, K. -L.; Li, Q. Rare Met. 2022, 41, 3268. doi: 10.1007/s12598-022-02058-2 doi: 10.1007/s12598-022-02058-2
52. [52]
  Li, H.; Sun, B.; Gao, T.; Li, H.; Ren, Y.; Zhou, G. Chin. J. Catal. 2022, 43 (2), 461. doi: 10.1016/S1872-2067(21)63915-3 doi: 10.1016/S1872-2067(21)63915-3
53. [53]
  Guan, C.; Yue, X.; Fan, J.; Xiang, Q. Chin. J. Catal. 2022, 43 (10), 2484. doi: 10.1016/S1872-2067(22)64102-0 doi: 10.1016/S1872-2067(22)64102-0
54. [54]
  You, Z.; Liao, Y.; Li, X.; Fan, J.; Xiang, Q. Nanoscale 2021, 13, 9463. doi: 10.1039/D1NR02224E doi: 10.1039/D1NR02224E
55. [55]
  Su, T.; Men, C.; Chen, L.; Chu, B.; Luo, X.; Ji, H.; Chen, J.; Qin, Z. Adv. Sci. 2022, 9, 2103715. doi: 10.1002/advs.202103715 doi: 10.1002/advs.202103715
56. [56]
  Yu, J.; Zhang, J.; Jaroniec, M. Green Chem. 2010, 12, 1611. doi: 10.1039/c0gc00236d doi: 10.1039/c0gc00236d
57. [57]
  Sun, Q. -M.; Xu, J. -J.; Tao, F. -F.; Ye, W.; Zhou, C.; He, J. -H.; Lu, J. -M. Angew. Chem. -Int. Ed. 2022, 61, e202200872. doi: 10.1002/anie.202200872 doi: 10.1002/anie.202200872
58. [58]
  Zhu, J.; Wageh, S.; Al-Ghamdi, A. A. Chin. J. Catal. 2023, 49, 5. doi: 10.1016/S1872-2067(23)64438-9 doi: 10.1016/S1872-2067(23)64438-9
59. [59]
  Cheng, C.; Zhang, J.; Zhu, B.; Liang, G.; Zhang, L.; Yu, J. Angew. Chem. -Int. Ed. 2023, 62, e202218688. doi: 10.1002/anie.202218688 doi: 10.1002/anie.202218688
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2. [2]
  Jiawei Hu , Kai Xia , Ao Yang , Zhihao Zhang , Wen Xiao , Chao Liu , Qinfang Zhang . Interfacial Engineering of Ultrathin 2D/2D NiPS₃/C₃N₅ Heterojunctions for Boosting Photocatalytic H₂ Evolution. Acta Physico-Chimica Sinica, 2024, 40(5): 2305043-0. doi: 10.3866/PKU.WHXB202305043
3. [3]
  Yingqi BAI , Hua ZHAO , Huipeng LI , Xinran REN , Jun LI . Perovskite LaCoO₃/g-C₃N₄ heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 480-490. doi: 10.11862/CJIC.20240259
4. [4]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-0. doi: 10.3866/PKU.WHXB202312014
5. [5]
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6. [6]
  Chenye An , Sikandaier Abiduweili , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . Hierarchical S-scheme Heterojunction of Red Phosphorus Nanoparticles Embedded Flower-like CeO₂ Triggering Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-0. doi: 10.3866/PKU.WHXB202405019
7. [7]
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8. [8]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . Architecting Inorganic/Organic S-Scheme Heterojunction of Bi₄Ti₃O₁₂ Coupling with g-C₃N₄ for Photocatalytic H₂O₂ Production from Pure Water. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-0. doi: 10.3866/PKU.WHXB202403009
9. [9]
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10. [10]
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13. [13]
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14. [14]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(Ⅵ) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-0. doi: 10.3866/PKU.WHXB202309020
15. [15]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . Molten Intermediate Transportation-Oriented Synthesis of Amino-Rich g-C₃N₄ Nanosheets for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-0. doi: 10.3866/PKU.WHXB202406021
16. [16]
  Kun Rong , Cuilian Wen , Jiansen Wen , Xiong Li , Qiugang Liao , Siqing Yan , Chao Xu , Xiaoliang Zhang , Baisheng Sa , Zhimei Sun . Hierarchical MoS₂/Ti₃C₂T_x heterostructure with excellent photothermal conversion performance for solar-driven vapor generation. Acta Physico-Chimica Sinica, 2025, 41(6): 100053-0. doi: 10.1016/j.actphy.2025.100053
17. [17]
  Jiajie Cai , Chang Cheng , Bowen Liu , Jianjun Zhang , Chuanjia Jiang , Bei Cheng . CdS/DBTSO-BDTO S-scheme photocatalyst for H₂ production and its charge transfer dynamics. Acta Physico-Chimica Sinica, 2025, 41(8): 100084-0. doi: 10.1016/j.actphy.2025.100084
18. [18]
  Haitao Wang , Lianglang Yu , Jizhou Jiang , Arramel , Jing Zou . S-Doping of the N-Sites of g-C₃N₄ to Enhance Photocatalytic H₂ Evolution Activity. Acta Physico-Chimica Sinica, 2024, 40(5): 2305047-0. doi: 10.3866/PKU.WHXB202305047
19. [19]
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20. [20]
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

In situ Growth of Cd0.5Zn0.5S Nanorods on Ti3C2 MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution

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通讯作者: 陈斌, bchen63@163.com

In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution