Citation: Qin Li, Huihui Zhang, Huajun Gu, Yuanyuan Cui, Ruihua Gao, Wei-Lin Dai. In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution[J]. Acta Physico-Chimica Sinica, ;2025, 41(4): 100031. doi: 10.3866/PKU.WHXB202402016 shu

In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution

Qin Li ¹ ,
Huihui Zhang ¹ ,
Huajun Gu ¹ ,
Yuanyuan Cui ³ ,
Ruihua Gao ^2,, ,
Wei-Lin Dai ^1,,

1.
Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, China;
2.
State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai 200433, China;
3.
Shimadzu China Co LTD, Shanghai 200436, China

Corresponding author: Ruihua Gao, Wei-Lin Dai,
Received Date: 19 February 2024
Revised Date: 3 April 2024
Accepted Date: 3 April 2024

Fund Project: This work was financially supported by the National Key Research and Development Program of China (2021YFA1501404), Natural Science Foundation of Shanghai (22ZR1404200), National Natural Science Foundation of China (21373054), and Natural Science Foundation of Shanghai Science and Technology Committee (19DZ2270100).

Against the backdrop of energy scarcities and ecological concerns, the process of photocatalytic hydrogen evolution emerges as a critical method for transforming solar energy into chemical energy. Central to this technology is the crafting of photocatalysts that are not only efficient and durable but also economically viable. The key to creating photocatalysts that boast superior hydrogen production capabilities lies in enhancing the separation and transfer of photo-generated electrons and holes. This study introduces a binary heterojunction photocatalyst, featuring a combination of Cd_0.5Zn_0.5S and Ti₃C₂ MXene, synthesized via an in situ hydrothermal method. In the composite, slender Cd_0.5Zn_0.5S nanorods are uniformly coated over the surface of single layer Ti₃C₂ nanosheets, forming a Schottky heterojunction at the material interface. This structure enhances the separation efficiency of photo-generated electrons and holes, thereby improving the utilization of light. With 0.5 wt% (mass fraction) of Ti₃C₂ MXene incorporated, we observed a peak photocatalytic H₂ generation rate of 15.56 mmol∙g⁻¹∙h⁻¹, outperforming the baseline Cd_0.5Zn_0.5S by 2.56 times. Notably, the photocatalytic efficiency remained largely unchanged after five cycles. This composite achieved the highest apparent quantum efficiency (AQE) of 18.4% when exposed to 350 nm UV light. Various characterization techniques, including in situ X-ray photoelectron spectroscopy (XPS) and femtosecond transient absorption (fs-TA) spectroscopy, along with density functional theory (DFT) calculations, have further substantiated that the formation of a Schottky heterojunction at the interface is crucial for enhancing the photocatalytic hydrogen evolution performance of the composite material. This paper demonstrates the effectiveness of the novel carbon based material MXene as a co-catalyst for improving the performance of photocatalysts and offers a viable approach for the construction of MXene-containing photocatalytic hydrogen evolution catalysts.
- Cd₁₋_xZn_xS nanorods,
- Photocatalysis,
- Hydrogen evolution,
- Ti₃C₂ MXene nanosheet,
- Heterojunction
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In situ Growth of Cd0.5Zn0.5S Nanorods on Ti3C2 MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution

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In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution