Citation: Wenxiu Yang, Jinfeng Zhang, Quanlong Xu, Yun Yang, Lijie Zhang. Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production[J]. Acta Physico-Chimica Sinica, ;2024, 40(10): 231201. doi: 10.3866/PKU.WHXB202312014 shu

Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production

1.
Wenzhou Key Lab of Advanced Energy Storage and Conversion, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325027, Zhejiang Province, China
2.
Anhui Province Key Laboratory of Pollutant Sensitive Materials and Environmental Remediation, College of Physics and Electronic Information, Huaibei Normal University, Huaibei 235000, Anhui Province, China

Corresponding author: Quanlong Xu, xuql@wzu.edu.cn Lijie Zhang, ljzhang@wzu.edu.cn
Received Date: 12 December 2023
Revised Date: 12 January 2024
Accepted Date: 12 January 2024
Available Online: 18 January 2024
Fund Project: the National Natural Science Foundation of China 52073263the National Natural Science Foundation of China 52171145the National Natural Science Foundation of China 21905209

Covalent organic frameworks (COFs) represent a kind of novel crystalline porous organic substances with extended π-conjugation framework and tunable structures, which display great promise in photocatalysis. However, unadorned COFs suffer from sluggish reaction kinetics, and a cocatalyst is essentially needed to reduce the activation barrier toward specific surface reaction and accelerate reaction kinetics. In this work, bimetallic alloys serving as co-catalysts were decorated on COFs to enhance the photocatalytic hydrogen evolution performance. By precisely-tuning the ratio of AuCu alloy, the resultant Au₁Cu₅/COF-TpPa displays the highest photocatalytic hydrogen generation rate (8.24 mmol∙g⁻¹∙h⁻¹), even surpassing the Pt modified COF-TpPa (6.51 mmol∙h⁻¹∙g⁻¹). According to the systematic characterizations and theoretical calculation, Au₁Cu₅/COF-TpPa exhibits the significantly enhanced charge carrier separation efficiency and reduced H* formation energy barrier, thus possessing high photocatalytic performance. This work affords a valuable approach to advancing COF-based photocatalysts by employing bimetallic alloy cocatalysts.
- Photocatalysis,
- H₂ generation,
- Covalent organic framework,
- Bimetallic cocatalyst
1. [1]
  Wang, S.; Yang, Y.; Liang, X.; Ren, Y.; Ma, H.; Zhu, Z.; Wang, J.; Zeng, S.; Song, S.; Wang, X.; et al. Adv. Funct. Mater. 2023, 33, 2300386. doi: 10.1002/adfm.202300386 doi: 10.1002/adfm.202300386
2. [2]
  Fan, H.; Gu, J.; Meng, H.; Knebel, A.; Caro, J. Angew. Chem. Int. Ed. 2018, 57, 4083. doi: 10.1002/anie.201712816 doi: 10.1002/anie.201712816
3. [3]
  Altundal, O. F.; Altintas, C.; Keskin, S. J. Mater. Chem. A 2020, 8, 14609. doi: 10.1039/d0ta04574h doi: 10.1039/d0ta04574h
4. [4]
  Evans, A. M.; Bradshaw, N. P.; Litchfield, B.; Strauss, M. J.; Seckman, B.; Ryder, M. R.; Castano, I.; Gilmore, C.; Gianneschi, N. C.; Mulzer, C. R.; et al. Adv. Mater. 2020, 32, 2004205. doi: 10.1002/adma.202004205 doi: 10.1002/adma.202004205
5. [5]
  Liu, Y.; Tan, H.; Sun, J.; Wei, Y.; Liu, M.; Hong, J.; Shang, S.; Wang, X.; Li, L.; Gu, Y.; et al. Adv. Funct. Mater. 2023, 33, 202302874. doi: 10.1002/adfm.202302874 doi: 10.1002/adfm.202302874
6. [6]
  Wang, W.; Zhao, W.; Xu, H.; Liu, S.; Huang, W.; Zhao, Q. Coord. Chem. Rev. 2021, 429, 213616. doi: 10.1016/j.ccr.2020.213616 doi: 10.1016/j.ccr.2020.213616
7. [7]
  Yang, Y.; Liu, J.; Gu, M.; Cheng, B.; Wang, L.; Yu, J. App. Catal. B 2023, 333, 122780. doi: 10.1016/j.apcatb.2023.122780 doi: 10.1016/j.apcatb.2023.122780
8. [8]
  Chen, H.; Jena, H. S.; Feng, X.; Leus, K.; Van Der Voort, P. Angew. Chem. Int. Ed. 2022, 61, e202204938. doi: 10.1002/anie.202204938 doi: 10.1002/anie.202204938
9. [9]
  Wang, H.; Wang, H.; Wang, Z.; Tang, L.; Zeng, G.; Xu, P.; Chen, M.; Xiong, T.; Zhou, C.; Li, X.; et al. Chem. Soc. Rev. 2020, 49, 4135. doi: 10.1039/d0cs00278j doi: 10.1039/d0cs00278j
10. [10]
  Ye, L.; Xia, Z.; Xu, Q.; Yang, Y.; Xu, X.; Jin, H.; Wang, S. Chem. Commun. 2023, 59, 9872. doi: 10.1039/D3CC02914J doi: 10.1039/D3CC02914J
11. [11]
  Yin, C.; Liu, M.; Zhang, Z.; Wei, M.; Shi, X.; Zhang, Y.; Wang, J.; Wang, Y. J. Am. Chem. Soc. 2023, 145, 11431. doi: 10.1021/jacs.3c03198 doi: 10.1021/jacs.3c03198
12. [12]
  Emmerling, S. T.; Schuldt, R.; Bette, S.; Yao, L.; Dinnebier, R. E.; Kästner, J.; Lotsch, B. V. J. Am. Chem. Soc. 2021, 143, 15711. doi: 10.1021/jacs.1c06518 doi: 10.1021/jacs.1c06518
13. [13]
  Liang, Z.; Shen, R.; Zhang, P.; Li, Y.; Li, N.; Li, X. Chin. J. Catal. 2022, 43, 2581. doi: 10.1016/S1872-2067(22)64130-5 doi: 10.1016/S1872-2067(22)64130-5
14. [14]
  Prakash, K.; Mishra, B.; Díaz, D. D.; Nagaraja, C. M.; Pachfule, P. J. Mater. Chem. A 2023, 11, 14489. doi: 10.1039/D3TA02189K doi: 10.1039/D3TA02189K
15. [15]
  Yuan, Y.; Bang, K. T.; Wang, R.; Kim, Y. Adv. Mater. 2023, 35, 2210952. doi: 10.1002/adma.202210952 doi: 10.1002/adma.202210952
16. [16]
  Song, Y.; Sun, Q.; Aguila, B.; Ma, S. Adv. Sci. 2019, 6, 1970011. doi: 10.1002/advs.201970011 doi: 10.1002/advs.201970011
17. [17]
  Sun, L.; Li, L.; Yang, J.; Fan, J.; Xu, Q. Chin. J. Catal. 2022, 43, 350. doi: 10.1016/s1872-2067(21)63869-x doi: 10.1016/s1872-2067(21)63869-x
18. [18]
  Sun, L.; Li, L.; Fan, J.; Xu, Q.; Ma, D. J. Mater. Sci. Technol. 2022, 123, 41. doi: 10.1016/j.jmst.2021.12.065 doi: 10.1016/j.jmst.2021.12.065
19. [19]
  Zhang, J.; Le, Y.; Zhang, Y. J. Mater. Sci. Technol. 2023, 142, 121. doi: 10.1016/j.jmst.2022.11.001 doi: 10.1016/j.jmst.2022.11.001
20. [20]
  Sun, F.; Tang, Q.; Jiang, D. ACS Catal. 2022, 12, 8404. doi: 10.1021/acscatal.2c02081 doi: 10.1021/acscatal.2c02081
21. [21]
  Luo, C.; Long, Q.; Cheng, B.; Zhu, B.; Wang, L. Acta Phys.-Chim. Sin. 2023, 39, 2212026. doi: 10.3866/PKU.WHXB202212026 doi: 10.3866/PKU.WHXB202212026
22. [22]
  Zhang, J.; Yang, G.; He, B.; Cheng, B.; Li, Y.; Liang, G.; Wang, L. Chin. J. Catal. 2022, 43, 2530. doi: 10.1016/S1872-2067(22)64108-1 doi: 10.1016/S1872-2067(22)64108-1
23. [23]
  Xiang, X.; Zhang, L.; Luo, C.; Zhang, J.; Cheng, B.; Liang, G.; Zhang, Z.; Yu, J. App. Catal. B 2024, 340, 123196. doi: 10.1016/j.apcatb.2023.123196 doi: 10.1016/j.apcatb.2023.123196
24. [24]
  Wu, X.; Chen, G.; Wang, J.; Li, J.; Wang, G. Acta Phys.-Chim. Sin. 2023, 39, 2212016. doi: 10.3866/PKU.WHXB202212016 doi: 10.3866/PKU.WHXB202212016
25. [25]
  Huang, Y.; Mei, F.; Zhang, J.; Dai, K.; Dawson, G. Acta Phys.-Chim. Sin. 2022, 38, 2108028. doi: 10.3866/PKU.WHXB202108028 doi: 10.3866/PKU.WHXB202108028
26. [26]
  Kuang, P.; Ni, Z.; Zhu, B.; Lin, Y.; Yu, J. Adv. Mater. 2023, 35, 2303030. doi: 10.1002/adma.202303030 doi: 10.1002/adma.202303030
27. [27]
  Zhang, Y.; Zhang, Z. J. Mater. Sci. Technol. 2024, 171, 147. doi: 10.1016/j.jmst.2023.06.048 doi: 10.1016/j.jmst.2023.06.048
28. [28]
  Zhang, X.; Liu, K.; Fu, J.; Li, H.; Pan, H.; Hu, J.; Liu, M. Front. Phys. 2021, 16, 63500. doi: 10.1007/s11467-021-1079-4 doi: 10.1007/s11467-021-1079-4
29. [29]
  Wageh, S.; Al-Ghamdi, A. A.; Xu, Q. Acta Phys.-Chim. Sin. 2022, 38, 2202001. doi: 10.3866/PKU.WHXB202202001 doi: 10.3866/PKU.WHXB202202001
30. [30]
  Liu, L.; Corma, A. Chem. Rev. 2023, 123, 4855. doi: 10.1021/acs.chemrev.2c00733 doi: 10.1021/acs.chemrev.2c00733
31. [31]
  Lee, S.; Jeong, S.; Kim, W. D.; Lee, S.; Lee, K.; Bae, W. K.; Moon, J. H.; Lee, S.; Lee, D. C. Nanoscale 2016, 8, 10043. doi: 10.1039/C6NR02124G doi: 10.1039/C6NR02124G
32. [32]
  Xu, Q.; Xia, Z.; Zhang, J.; Wei, Z.; Guo, Q.; Jin, H.; Tang, H.; Li, S.; Pan, X.; Su, Z.; et al. Carbon Energy 2023, 5, e205. doi: 10.1002/cey2.205 doi: 10.1002/cey2.205
33. [33]
  Yao, Q.; Yu, Z.; Li, L.; Huang, X. Chem. Rev. 2023, 123, 9676. doi: 10.1021/acs.chemrev.3c00252 doi: 10.1021/acs.chemrev.3c00252
34. [34]
  Gao, D.; Deng, P.; Zhang, J.; Zhang, L.; Wang, X.; Yu, H.; Yu, J. Angew. Chem. Int. Ed. 2023, 62, e202304559. doi: 10.1002/anie.202304559 doi: 10.1002/anie.202304559
35. [35]
  Akinaga, Y.; Kawawaki, T.; Kameko, H.; Yamazaki, Y.; Yamazaki, K.; Nakayasu, Y.; Kato, K.; Tanaka, Y.; Hanindriyo, A. T.; Takagi, M.; et al. Adv. Funct. Mater. 2023, 33, 202303321. doi: 10.1002/adfm.202303321 doi: 10.1002/adfm.202303321
36. [36]
  Xia, Y.; Zhu, B.; Li, L.; Ho, W.; Wu, J.; Chen, H.; Yu, J. Small 2023, 19, 2301928. doi: 10.1002/smll.202301928 doi: 10.1002/smll.202301928
37. [37]
  Shen, R.; Hao, L.; Ng, Y. H.; Zhang, P.; Arramel, A.; Li, Y.; Li, X. Chin. J. Catal. 2022, 43, 2453. doi: 10.1016/S1872-2067(22)64104-4 doi: 10.1016/S1872-2067(22)64104-4
38. [38]
  He, B.; Xiao, P.; Wan, S.; Zhang, J.; Chen, T.; Zhang, L.; Yu, J. Angew. Chem. Int. Ed. 2023, 62, e202313172. doi: 10.1002/anie.202313172 doi: 10.1002/anie.202313172
39. [39]
  Fu, J.; Wang, S.; Wang, Z.; Liu, K.; Li, H.; Liu, H.; Hu, J.; Xu, X.; Li, H.; Liu, M. Front. Phys. 2020, 15, 33201. doi: 10.1007/s11467-019-0950-z doi: 10.1007/s11467-019-0950-z
40. [40]
  Zhang, H.; Zhang, P.; Qiu, M.; Dong, J.; Zhang, Y.; Lou, X. Adv. Mater. 2019, 31, 1804883. doi: 10.1002/adma.201804883 doi: 10.1002/adma.201804883
41. [41]
  Yan, B.; He, Y.; Yang, G. Small 2022, 18, 2107840. doi: 10.1002/smll.202107840 doi: 10.1002/smll.202107840
42. [42]
  Peng, Y.; Cheng, B.; Zhang, L.; Liu, J.; Yu, J. Sensor Actuat. B-Chem. 2023, 385, 133700. doi: 10.1016/j.snb.2023.133700 doi: 10.1016/j.snb.2023.133700
43. [43]
  Zhou, Z.; Bie, C.; Li, P.; Tan, B.; Shen, Y. Chin. J. Catal. 2022, 43, 2699. doi: 10.1016/S1872-2067(22)64118-4 doi: 10.1016/S1872-2067(22)64118-4
44. [44]
  Fukuzumi, S.; Lee, Y.; Nam, W. Coord. Chem. Rev. 2018, 355, 54. doi: 10.1016/j.ccr.2017.07.014 doi: 10.1016/j.ccr.2017.07.014
45. [45]
  Deng, J.; Lei, W.; Fu, J.; Jin, H.; Xu, Q.; Wang, S. Sol. RRL 2022, 6, 2200279. doi: 10.1002/solr.202200279 doi: 10.1002/solr.202200279
46. [46]
  Deng, J.; Xu, D.; Zhang, J.; Xu, Q.; Yang, Y.; Wei, Z.; Su, Z. J. Mater. Sci. Technol. 2024, 180, 150. doi: 10.1016/j.jmst.2023.04.053 doi: 10.1016/j.jmst.2023.04.053
47. [47]
  Sun, G.; Zhang, J.; Cheng, B.; Yu, H.; Yu, J.; Xu, J. Chem. Eng. J. 2023, 476, 146818. doi: 10.1016/j.cej.2023.146818 doi: 10.1016/j.cej.2023.146818
48. [48]
  Bie, C.; Zhu, B.; Wang, L.; Yu, H.; Jiang, C.; Chen, T.; Yu, J. Angew. Chem. Int. Ed. 2022, 61, e202212045. doi: 10.1002/anie.202212045 doi: 10.1002/anie.202212045
49. [49]
  Sun, T.; Li, C.; Bao, Y.; Fan, J.; Liu, E. Acta Phys.-Chim. Sin. 2023, 39, 2212009. doi: 10.3866/PKU.WHXB202212009 doi: 10.3866/PKU.WHXB202212009
50. [50]
  Xiang, X.; Zhu, B.; Zhang, J.; Jiang, C.; Chen, T.; Yu, H.; Yu, J.; Wang, L. App. Catal. B 2023, 324, 122301. doi: 10.1016/j.apcatb.2022.122301 doi: 10.1016/j.apcatb.2022.122301
51. [51]
  Kandambeth, S.; Mallick, A.; Lukose, B.; Mane, M. V.; Heine, T.; Banerjee, R. J. Am. Chem. Soc. 2012, 134, 19524. doi: 10.1021/ja308278w doi: 10.1021/ja308278w
52. [52]
  Cao, Q.; Zhang, L.; Zhou, C.; He, J.; Marcomini, A.; Lu, J. App. Catal. B. 2021, 294, 120238. doi: 10.1016/j.apcatb.2021.120238 doi: 10.1016/j.apcatb.2021.120238
53. [53]
  Dong, P.; Wang, Y.; Zhang, A.; Cheng, T.; Xi, X.; Zhang, J. ACS Catal. 2021, 11, 13266. doi: 10.1021/acscatal.1c03441 doi: 10.1021/acscatal.1c03441
54. [54]
  Weng, W.; Guo, J. Nat Commun. 2022, 13, 5768. doi: 10.1038/s41467-022-33501-8 doi: 10.1038/s41467-022-33501-8
55. [55]
  Martin, D. J.; Qiu, K.; Shevlin, S. A.; Handoko, A. D.; Chen, X.; Guo, Z.; Tang, J. Angew. Chem. Int. Ed. 2014, 53, 9240. doi: 10.1002/anie.201403375 doi: 10.1002/anie.201403375
56. [56]
  Zhang, Y.; Zeng, P.; Yu, Y.; Zhang, W. Chem. Eng. J. 2020, 381, 2301928. doi: 10.1016/j.cej.2019.122635 doi: 10.1016/j.cej.2019.122635
57. [57]
  Liu, Q.; Xu, Y.; Wang, A.; Feng, J. Int. J. Hydrog. Energy 2016, 41, 2547. doi: 10.1016/j.ijhydene.2015.11.143 doi: 10.1016/j.ijhydene.2015.11.143
58. [58]
  Zhan, W.; Wang, J.; Wang, H.; Zhang, J.; Liu, X.; Zhang, P.; Chi, M.; Guo, Y.; Guo, Y.; Lu, G.; et al. J. Am. Chem. Soc. 2017, 139, 8846. doi: 10.1021/jacs.7b01784 doi: 10.1021/jacs.7b01784
59. [59]
  Zhang, S.; Li, M.; Zhao, J.; Wang, H.; Zhu, X.; Han, J.; Liu, X. App. Catal. B 2019, 252, 24. doi: 10.1016/j.apcatb.2019.04.013 doi: 10.1016/j.apcatb.2019.04.013
60. [60]
  Zhang, P.; Zeng, G.; Song, T.; Huang, S.; Wang, T.; Zeng, H. App. Catal. B 2019, 242, 389. doi: 10.1016/j.apcatb.2018.10.020 doi: 10.1016/j.apcatb.2018.10.020
61. [61]
  Fang, J.; Wei, H.; Chen, Y.; Dai, B.; Ni, Y.; Kou, J.; Lu, C.; Xu, Z. Small 2023, 19, 2207467. doi: 10.1002/smll.202207467 doi: 10.1002/smll.202207467
62. [62]
  Li, S.; Zhao, Z.; Liu, M.; Liu, X.; Huang, W.; Sun, S.; Jiang, Y.; Liu, Y.; Zhang, J.; Zhang, Z. Nano Energy 2022, 95, 107031. doi: 10.1016/j.nanoen.2022.107031 doi: 10.1016/j.nanoen.2022.107031
63. [63]
  Huang, Y.; Dai, K.; Zhang, J.; Dawson, G. Chin. J. Catal. 2022, 43, 2539. doi: 10.1016/S1872-2067(21)64024-X doi: 10.1016/S1872-2067(21)64024-X
64. [64]
  Chen, S.; Hau Ng, Y.; Liao, J.; Gao, Q.; Yang, S.; Peng, F.; Zhong, X.; Fang, Y.; Zhang, S. J. Energy Chem. 2021, 52, 92. doi: 10.1016/j.jechem.2020.04.040 doi: 10.1016/j.jechem.2020.04.040
65. [65]
  Xu, M.; Zhao, X.; Jiang, H.; Chen, S.; Huo, P. J. Environ. Chem. Eng. 2021, 9, 106469. doi: 10.1016/j.jece.2021.106469 doi: 10.1016/j.jece.2021.106469
66. [66]
  Xu, W.; Huang, B.; Li, G.; Yang, F.; Lin, W.; Gu, J.; Deng, H.; Gu, Z.; Jin, H. ACS Catal. 2023, 13, 5723. doi: 10.1021/acscatal.3c00284 doi: 10.1021/acscatal.3c00284
1. [1]
  Lewang Yuan , Yaoyao Peng , Zong-Jie Guan , Yu Fang . Insights into the development of 2D covalent organic frameworks as photocatalysts in organic synthesis. Acta Physico-Chimica Sinica, 2025, 41(8): 100086-0. doi: 10.1016/j.actphy.2025.100086
2. [2]
  Linfeng Xiao , Wanlu Ren , Shishi Shen , Mengshan Chen , Runhua Liao , Yingtang Zhou , Xibao Li . Enhancing Photocatalytic Hydrogen Evolution through Electronic Structure and Wettability Adjustment of ZnIn₂S₄/Bi₂O₃ S-Scheme Heterojunction. Acta Physico-Chimica Sinica, 2024, 40(8): 2308036-0. doi: 10.3866/PKU.WHXB202308036
3. [3]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 2402016-0. doi: 10.3866/PKU.WHXB202402016
4. [4]
  Jianan Hong , Chenyu Xu , Yan Liu , Changqi Li , Menglin Wang , Yanwei Zhang . Decoding the interfacial competition between hydrogen evolution and CO₂ reduction via edge-active-site modulation in photothermal catalysis. Acta Physico-Chimica Sinica, 2025, 41(9): 100099-0. doi: 10.1016/j.actphy.2025.100099
5. [5]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . Double S-Scheme ZnS/ZnO/CdS Heterostructure Photocatalyst for Efficient Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-0. doi: 10.3866/PKU.WHXB202406020
6. [6]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d-Band Center Regulated O₂ Adsorption on Transition Metal Single Atoms Loaded COF: A DFT Study. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-0. doi: 10.3866/PKU.WHXB202407013
7. [7]
  Jingping Li , Suding Yan , Jiaxi Wu , Qiang Cheng , Kai Wang . Improving hydrogen peroxide photosynthesis over inorganic/organic S-scheme photocatalyst with LiFePO₄. Acta Physico-Chimica Sinica, 2025, 41(9): 100104-0. doi: 10.1016/j.actphy.2025.100104
8. [8]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
9. [9]
  Yifan ZHAO , Qiyun MAO , Meijing GUO , Guoying ZHANG , Tongliang HU . Z-scheme bismuth-based multi-site heterojunction: Synthesis and hydrogen production from photocatalytic hydrogen production. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1318-1330. doi: 10.11862/CJIC.20250001
10. [10]
  Haitao Wang , Lianglang Yu , Jizhou Jiang , Arramel , Jing Zou . S-Doping of the N-Sites of g-C₃N₄ to Enhance Photocatalytic H₂ Evolution Activity. Acta Physico-Chimica Sinica, 2024, 40(5): 2305047-0. doi: 10.3866/PKU.WHXB202305047
11. [11]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Construction of ZnCoP/CdLa₂S₄ Schottky Heterojunctions for Enhancing Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-0. doi: 10.3866/PKU.WHXB202404030
12. [12]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-0. doi: 10.1016/j.actphy.2025.100067
13. [13]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . Architecting Inorganic/Organic S-Scheme Heterojunction of Bi₄Ti₃O₁₂ Coupling with g-C₃N₄ for Photocatalytic H₂O₂ Production from Pure Water. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-0. doi: 10.3866/PKU.WHXB202403009
14. [14]
  Yu Wang , Haiyang Shi , Zihan Chen , Feng Chen , Ping Wang , Xuefei Wang . 具有富电子Pt^δ−壳层的空心AgPt@Pt核壳催化剂：提升光催化H₂O₂生成选择性与活性. Acta Physico-Chimica Sinica, 2025, 41(7): 100081-0. doi: 10.1016/j.actphy.2025.100081
15. [15]
  Jingzhuo Tian , Chaohong Guan , Haobin Hu , Enzhou Liu , Dongyuan Yang . Waste plastics promoted photocatalytic H₂ evolution over S-scheme NiCr₂O₄/twinned-Cd_0.5Zn_0.5S homo-heterojunction. Acta Physico-Chimica Sinica, 2025, 41(6): 100068-0. doi: 10.1016/j.actphy.2025.100068
16. [16]
  Jiajie Cai , Chang Cheng , Bowen Liu , Jianjun Zhang , Chuanjia Jiang , Bei Cheng . CdS/DBTSO-BDTO S-scheme photocatalyst for H₂ production and its charge transfer dynamics. Acta Physico-Chimica Sinica, 2025, 41(8): 100084-0. doi: 10.1016/j.actphy.2025.100084
17. [17]
  Jiawei Hu , Kai Xia , Ao Yang , Zhihao Zhang , Wen Xiao , Chao Liu , Qinfang Zhang . Interfacial Engineering of Ultrathin 2D/2D NiPS₃/C₃N₅ Heterojunctions for Boosting Photocatalytic H₂ Evolution. Acta Physico-Chimica Sinica, 2024, 40(5): 2305043-0. doi: 10.3866/PKU.WHXB202305043
18. [18]
  Chenye An , Sikandaier Abiduweili , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . Hierarchical S-scheme Heterojunction of Red Phosphorus Nanoparticles Embedded Flower-like CeO₂ Triggering Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-0. doi: 10.3866/PKU.WHXB202405019
19. [19]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Construction of Electron Bridge and Activation of MoS₂ Inert Basal Planes by Ni Doping for Enhancing Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-0. doi: 10.3866/PKU.WHXB202406024
20. [20]
  Yueshuai Xu , Wei Liu , Xudong Chen , Zhikun Zheng . 水相中制备共价有机框架单晶的实验教学设计. University Chemistry, 2025, 40(6): 256-265. doi: 10.12461/PKU.DXHX202408045

Get Citation

PDF

XML

Metrics

PDF Downloads(9)
Abstract views(770)
HTML views(75)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142