Citation: Bowen Yang, Rui Wang, Benjian Xin, Lili Liu, Zhiqiang Niu. C-SnO₂/MWCNTs Composite with Stable Conductive Network for Lithium-based Semi-Solid Flow Batteries[J]. Acta Physico-Chimica Sinica, ;2025, 41(2): 231002. doi: 10.3866/PKU.WHXB202310024 shu

C-SnO₂/MWCNTs Composite with Stable Conductive Network for Lithium-based Semi-Solid Flow Batteries

Bowen Yang ¹ ,
Rui Wang ² ,
Benjian Xin ¹ ,
Lili Liu ^1,, ,
Zhiqiang Niu ^2,,

1.
Tianjin Key Laboratory for Photoelectric Materials and Devices, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China
2.
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Haihe Laboratory of Sustainable Chemical Transformations, College of Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: Lili Liu, lililiuhappy@163.com Zhiqiang Niu, zqniu@nankai.edu.cn
Received Date: 19 October 2023
Revised Date: 9 November 2023
Accepted Date: 9 November 2023

Fund Project: the National Key Research and Development Program of China 2019YFA0705601the National Natural Science Foundation of China 51972231

Lithium-based semi-solid flow batteries (LSSFBs) could potentially be applied in large-scale energy storage systems due to their high safety and relatively independent equipment units. However, the electrochemical performance of LSSFBs is limited by the unstable contact between conductive additives and active materials, as well as the poor conductivity of active materials. Therefore, it is necessary to develop semi-solid electrodes with high stability and specific capacity to obtain LSSFBs with satisfied energy density. Herein, carbon-coated SnO₂/multi-walled carbon nanotubes (C-SnO₂/MWCNTs) composite was designed as the anode material of LSSFBs. In such composite, SnO₂ nanoparticles are uniformly distributed on the surface of MWCNTs and coated with carbon layer, which was identified by field-emission scanning electron microscopy, transmission electron microscopy and X-ray diffraction (XRD) results. In general, the traditional SnO₂ as active material in electrodes will suffer from volume expansion and collapse of structure, which will decline the cycle life of batteries. In this composite, the nanoparticle structure endows SnO₂ with more reaction active sites. Furthermore, MWCNTs and carbon layer can construct a stable conductive network, which enhances the electron transport in SnO₂-based electrodes. Simultaneously, MWCNTs and carbon layer also achieve an integrated architecture. Thus, the electron transfer dynamics of SnO₂-based electrodes could be improved and their volume expansion is effectively suppressed during charging/discharging process, resulting in improved rate and cycling performance. The coin-type batteries based on C-SnO₂/MWCNTs can maintain a discharge capacity of 725 mAh∙g⁻¹ after 100 cycles under a current density of 0.5 A∙g⁻¹. On the contrary, the discharge capacity of the batteries based on bulk SnO₂ almost disappears after 100 cycles, which is attributed to the poor conductivity and excessive volume expansion of electrode materials. In addition, the MWCNTs will enhance the suspension stability of the semi-solid electrode. When the mass fraction of the C-SnO₂/MWCNTs in the semi-solid electrode is 8.0%, the semi-solid electrode has superior suspension and electron conductivity, as well as suitable viscosity. Furthermore, the lithium storage mechanism of the semi-solid electrode was explored by ex situ XRD and X-ray photoelectron spectroscopy. The results show that, in C-SnO₂/MWCNTs composite, SnO₂ has a dual Li⁺ ions storage mechanism involving conversion and alloying reactions. When the flow rate is controlled with 5 mL∙min⁻¹, the conduction network reaches a dynamic balance, and the semi-solid electrode exhibits low charge transfer resistance. These advantages endow the LSSFBs with superior rate and cycling performance. The semi-solid flow batteries could maintain 42.4% of their initial capacity (690.8 mAh∙g⁻¹) after cycling for 962 h at 0.2 mA∙cm⁻². This work provides a promising strategy for optimizing the semi-solid electrode of LSSFBs.
- Semi-solid flow battery,
- Nano-sized SnO₂,
- Carbon nanotube,
- Carbon coating
1. [1]
  Yao, Y. X.; Lei, J. X.; Shi, Y.; Ai, F.; Lu, Y. C. Nat. Energy 2021, 6 (6), 582. doi: 10.1038/s41560-020-00772-8 doi: 10.1038/s41560-020-00772-8
2. [2]
  Hou, S.; Chen, L.; Fan, X. L.; Fan, X. T.; Ji, X.; Wang, B. Y.; Cui, C. Y.; Chen, J.; Yang, C. Y.; Wang, W.; et al. Nat. Commun. 2022, 13 (1), 1281. doi: 10.1038/s41467-022-28880-x doi: 10.1038/s41467-022-28880-x
3. [3]
  Yang, X. B.; Zhao, L.; Sui, X. L.; Meng, L. H.; Wang, Z. B. Acta Phys. -Chim. Sin. 2019, 35 (12), 1372. doi: 10.3866/PKU.WHXB201905011
4. [4]
  Yang, B.; Wang, Z. Y.; Wang, W. W.; Lu, Y. C. Energy Mater. Adv. 2022, 2022, 9795675. doi: 10.34133/2022/9795675 doi: 10.34133/2022/9795675
5. [5]
  Lim, H. S.; Chae, S.; Yan, L. T.; Li, G. S.; Feng, R. Z.; Shin, Y.; Nie, Z. M.; Sivakumar, B. M.; Zhang, X.; Liang, Y. G.; et al. Energy Mater. Adv. 2022, 2022, 9863679. doi: 10.34133/2022/9863679 doi: 10.34133/2022/9863679
6. [6]
  Fan, X. Y.; Liu, B.; Liu, J.; Ding, J.; Han, X. P.; Deng, Y. D.; Lv, X. J.; Xie, Y.; Chen, B.; Hu, W. B.; et al. Trans. Tianjin Univ. 2020, 26 (2), 92. doi: 10.1007/s12209-019-00231-w doi: 10.1007/s12209-019-00231-w
7. [7]
  Sun, J.; Jiang, H. R.; Zhao, C.; Fan, X. Z.; Chao, C.; Zhao, T. Sci. Bull. 2021, 66 (9), 904. doi: 10.1016/j.scib.2020.12.019 doi: 10.1016/j.scib.2020.12.019
8. [8]
  Ling, J.; Kunwar, R.; Li, L. L.; Peng, S. J.; Misnon, I. I.; Ab Rahim, M. H.; Yang, C. C.; Jose, R. eScience 2022, 2 (4), 347. doi: 10.1016/j.esci.2022.07.002 doi: 10.1016/j.esci.2022.07.002
9. [9]
  Guo, Y.; Wu, S. C.; He, Y. B.; Kang, F. Y.; Chen, L. Q.; Li, H.; Yang, Q. H. eScience 2022, 2 (2), 138. doi: 10.1016/j.esci.2022.02.008 doi: 10.1016/j.esci.2022.02.008
10. [10]
  Rudola, A.; Wright, C. J.; Barker, J. Energy Mater. Adv. 2021, 2021, 9798460. doi: 10.34133/2021/9798460 doi: 10.34133/2021/9798460
11. [11]
  Tong, Y. F.; Sun, Z. P.; Wang, J. W.; Huang, W. W.; Zhang, Q. C. SmartMat 2022, 3 (4), 685. doi: 10.1002/smm2.1115 doi: 10.1002/smm2.1115
12. [12]
  Chen, T. M.; Jin, Y.; Lv, H. Y.; Yang, A. T.; Liu, M. Y.; Chen, B.; Xie, Y.; Chen, Q. Trans. Tianjin Univ. 2020, 26 (3), 208. doi: 10.1007/s12209-020-00236-w doi: 10.1007/s12209-020-00236-w
13. [13]
  Sun, H.; Yu, M. F.; Li, Q.; Zhuang, K. M.; Li, J.; Almheiri, S.; Zhang, X. C. Energy 2019, 168, 693. doi: 10.1016/j.energy.2018.11.130 doi: 10.1016/j.energy.2018.11.130
14. [14]
  Cong, G. T.; Lu, Y. C. Acta Phys. -Chim. Sin. 2022, 38 (6), 2106008. doi: 10.3866/PKU.WHXB202106008
15. [15]
  Wang, X.; Chai, J. C.; Jiang, J. B. Nano Mater. Sci. 2021, 3 (1), 17. doi: 10.1016/j.nanoms.2020.06.003 doi: 10.1016/j.nanoms.2020.06.003
16. [16]
  Ventosa, E. Curr. Opin. Chem. Eng. 2022, 37, 100834. doi: 10.1016/j.coche.2022.100834 doi: 10.1016/j.coche.2022.100834
17. [17]
  Huang, Q. Z.; Li, H.; Grätzel, M.; Wang, Q. Phys. Chem. Chem. Phys. 2013, 15 (6), 1793. doi: 10.1039/C2CP44466F doi: 10.1039/C2CP44466F
18. [18]
  Zhang, L.; Wu, X. K.; Qian, W. W.; Zhang, H. T.; Zhang, S. J. Green Energy Environ. 2021, 6 (1), 5. doi: 10.1016/j.gee.2020.09.012 doi: 10.1016/j.gee.2020.09.012
19. [19]
  Narayanan, A.; Mugele, F.; Duits, M. H. G. Langmuir 2017, 33 (7), 1629. doi: 10.1021/acs.langmuir.6b04322 doi: 10.1021/acs.langmuir.6b04322
20. [20]
  Xin, B. J.; Wang, R.; Liu, L. L.; Niu, Z. Q. Chem. J. Chin. Univ. 2023, 43 (5), 20220731. doi: 10.7503/cjcu20220731
21. [21]
  Duduta, M. H.; Ho, B.; Wood, V. C.; Limthongkul, P.; Brunini, V. E.; Carter, W. C.; Chiang, Y. M. Adv. Energy Mater. 2011, 1 (4), 511. doi: 10.1002/aenm.201100152 doi: 10.1002/aenm.201100152
22. [22]
  Li, B.; Liu, J. Natl. Sci. Rev. 2017, 4 (1), 91. doi: 10.1093/nsr/nww098 doi: 10.1093/nsr/nww098
23. [23]
  Wei, J.; Zhang, P. B.; Liu, Y. Z.; Liang, J. C.; Xia, Y. R.; Tao, A. Y.; Zhang, K. Q.; Tie, Z. X.; Jin, Z. ACS Energy Lett. 2022, 7 (2), 862. doi: 10.1021/acsenergylett.2c00032 doi: 10.1021/acsenergylett.2c00032
24. [24]
  Yazami, R. Electrochim. Acta 1999, 45 (1), 87. doi: 10.1016/S0013-4686(99)00195-4 doi: 10.1016/S0013-4686(99)00195-4
25. [25]
  Hatzell, K. B.; Fan, L.; Beidaghi, M.; Boota, M.; Pomerantseva, E.; Kumbur, E. C.; Gogotsi, Y. ACS Appl. Mater. Interfaces 2014, 6 (11), 8886. doi: 10.1021/am501650q doi: 10.1021/am501650q
26. [26]
  Zhou, X. L.; Huang, R. A.; Wu, Z. C.; Bin, Y.; Dai, Y. N. Acta Phys. -Chim. Sin. 2010, 26 (12), 3187. doi: 10.3866/PKU.WHXB20101212
27. [27]
  Wei, T. S.; Fan, F. Y.; Helal, A.; Smith, K. C.; McKinley, G. H.; Chiang, Y.-M.; Lewis, J. A. Adv. Energy Mater. 2015, 5 (15), 1500535. doi: 10.1002/aenm.201500535 doi: 10.1002/aenm.201500535
28. [28]
  Shen, X.; Zhang, X. Q.; Ding, F.; Huang, J. Q.; Xu, R.; Chen, X.; Yan, C.; Su, F. Y.; Chen, C. M.; Liu, X. J.; et al. Energy Mater. Adv. 2021, 2021, 1205324. doi: 10.34133/2021/1205324 doi: 10.34133/2021/1205324
29. [29]
  Tang, Y. J.; Yang, L. P.; Zhu, Y. M.; Zhang, F. J.; Zhang, H. T. J. Mater. Chem. A 2022, 10 (10), 5620. doi: 10.1039/D1TA10883B doi: 10.1039/D1TA10883B
30. [30]
  Wu, F. X.; Maier, J.; Yu, Y. Chem. Soc. Rev. 2020, 49 (5), 1569. doi: 10.1039/c7cs00863e doi: 10.1039/c7cs00863e
31. [31]
  Kim, H.; Hong, J.; Park, K.-Y.; Kim, H.; Kim, S.-W.; Kang, K. Chem. Rev. 2014, 114 (23), 11788. doi: 10.1021/cr500232y doi: 10.1021/cr500232y
32. [32]
  Gong, Y. J.; Yang, S. B.; Liu, Z.; Ma, L. L.; Vajtai, R.; Ajayan, P. M. Adv. Mater. 2013, 25 (29), 3979. doi: 10.1002/adma.201301051 doi: 10.1002/adma.201301051
33. [33]
  Ma, Y.; Ajayan, P. M.; Yang, S. B.; Gong, Y. J. Small 2018, 14 (38), 1801606. doi: 10.1002/smll.201801606 doi: 10.1002/smll.201801606
34. [34]
  Huang, J. Y.; Zhong, L.; Wang, C. M.; Sullivan, J. P.; Xu, W.; Zhang, L. Q.; Mao, S. X.; Hudak, N. S.; Liu, X. H.; Subramanian, A.; et al. Science 2010, 330 (6010), 1515. doi: 10.1126/science.1195628 doi: 10.1126/science.1195628
35. [35]
  Wang, L. B.; Zhao, D. D.; Li, J. L.; Wang, H. Q.; Zhang, N. Sci. Sin. Chim. 2021, 51 (9), 1124. doi: 10.1360/ssc-2021-0127
36. [36]
  Min, X.; Sun, B.; Chen, S.; Fang, M. H.; Wu, X. W.; Liu, Y. G.; Abdelkader, A.; Huang, Z. H.; Liu, T.; Xi, K.; et al. Energy Storage Mater. 2019, 16, 597. doi: 10.1016/j.ensm.2018.08.002 doi: 10.1016/j.ensm.2018.08.002
37. [37]
  Qian, C. L.; Gu, F. J.; Jin, S. L.; Wang, X. R.; Zhang, R.; Jin, M. L. J. Chin. Ceram. Soc. 2022, 50 (5), 1215. doi: 10.14062/j.issn.0454-5648.20210691
38. [38]
  Zhao, S. Q.; Sewell, C. D.; Liu, R. P.; Jia, S. R.; Wang, Z. W.; He, Y. J.; Yuan, K. J.; Jin, H. L.; Wang, S.; Liu, X. Q.; et al. Adv. Energy Mater. 2020, 10 (6), 1902657. doi: 10.1002/aenm.201902657 doi: 10.1002/aenm.201902657
39. [39]
  Peng, X. D.; Xiong, C.; Lin, Y. K.; Zhao, C.; Zhao, T. S. SmartMat 2021, 2 (4), 579. doi: 10.1002/smm2.1061 doi: 10.1002/smm2.1061
40. [40]
  Cui, S. Q.; Zhang, J. J.; Fan, S. Z.; Xing, X. T.; Deng, L. B.; Gong, Y. J. Nano Lett. 2022, 22 (23), 9559. doi: 10.1021/acs.nanolett.2c03699 doi: 10.1021/acs.nanolett.2c03699
41. [41]
  Lan, X. X.; Xiong, X. Y.; Liu, J.; Yuan, B.; Hu, R. Z.; Zhu, M. Small 2022, 18 (26), 2201110. doi: 10.1002/smll.202201110 doi: 10.1002/smll.202201110
42. [42]
  Shukla, G.; Franco, A. A. Batteries Supercaps 2019, 2 (7), 579. doi: 10.1002/batt.201800152 doi: 10.1002/batt.201800152
43. [43]
  Chen, H. N.; Zou, Q. L.; Liang, Z. J.; Liu, H.; Li, Q.; Lu, Y. C. Nat. Commun. 2015, 6 (1), 5877. doi: 10.1038/ncomms6877 doi: 10.1038/ncomms6877
44. [44]
  Pan, S. S.; Yang, L. P.; Su, P. P.; Zhang, H. T.; Zhang, S. J. Small 2022, 18 (33), 2202139. doi: 10.1002/smll.202202139 doi: 10.1002/smll.202202139
45. [45]
  Xin, B. J.; Wang, R.; Hu, Y.; Liu, L. L.; Niu, Z. Q. Sci. Sin. Chim. 2022, 52 (7), 1148. doi: 10.1360/ssc-2022-0102
46. [46]
  Cao, H. M.; Deng, S. Z.; Tie, Z. W.; Tian, J. L.; Liu, L. L.; Niu, Z. Q. Sci. China Chem. 2022, 65 (9), 1725. doi: 10.1007/s11426-022-1292-0 doi: 10.1007/s11426-022-1292-0
47. [47]
  Cheng, Y. Y.; Huang, J. F.; Qi, H.; Cao, L. Y.; Yang, J.; Xi, Q.; Luo, X. M.; Yanagisawa, K.; Li, J. Y. Small 2017, 13 (31), 1700656. doi: 10.1002/smll.201700656 doi: 10.1002/smll.201700656
48. [48]
  Zhu, C.; Xu, J.; Ding, Y. L. J. Chin. Ceram. Soc. 2022, 50 (2), 364. doi: 10.14062/j.issn.0454-5648.20210759
49. [49]
  Liu, M.; Zhang, S.; Dong, H. C.; Chen, X.; Gao, S.; Sun, Y. P.; Li, W. H.; Xu, J. Q.; Chen, L. W.; Yuan, A. B.; et al. ACS Sustain. Chem. Eng. 2019, 7 (4), 4195. doi: 10.1021/acssuschemeng.8b05869 doi: 10.1021/acssuschemeng.8b05869
50. [50]
  Song, L. X.; Yang, S. J.; Wei, W.; Qu, P.; Xu, M. T.; Liu, Y. Sci. Bull. 2015, 60 (9), 892. doi: 10.1007/s11434-015-0767-2 doi: 10.1007/s11434-015-0767-2
51. [51]
  Tang, J. Y.; Peng, X. Y.; Lin, T. E.; Huang, X.; Luo, B.; Wang, L. Z. eScience 2021, 1 (2), 203. doi: 10.1016/j.esci.2021.12.004 doi: 10.1016/j.esci.2021.12.004
52. [52]
  Deng, S. Z.; Tie, Z. W.; Yue, F.; Cao, H. M.; Yao, M. J.; Niu, Z. Q. Angew. Chem. Int. Ed. 2022, 61 (12), e202115877. doi: 10.1002/anie.202115877 doi: 10.1002/anie.202115877
53. [53]
  Pan, S. S.; Zhang, H. T.; Xing, C. X.; Yang, L. P.; Su, P. P.; Bi, J. J.; Zhang, S. J. J. Power Sources 2021, 508, 230341. doi: 10.1016/j.jpowsour.2021.230341 doi: 10.1016/j.jpowsour.2021.230341
54. [54]
  Parant, H.; Muller, G.; Le Mercier, T.; Tarascon, J. M.; Poulin, P.; Colin, A. Carbon 2017, 119, 10. doi: 10.1016/j.carbon.2017.04.014 doi: 10.1016/j.carbon.2017.04.014
55. [55]
  Chen, H. N.; Liu, Y.; Zhang, X. F.; Lan, Q.; Chu, Y.; Li, Y. L.; Wu, Q. X. J. Power Sources 2021, 485, 229319. doi: 10.1016/j.jpowsour.2020.229319 doi: 10.1016/j.jpowsour.2020.229319
56. [56]
  Ma, Y. J.; Ma, Y.; Giuli, G.; Diemant, T.; Behm, R. J.; Geiger, D.; Kaiser, U.; Ulissi, U.; Passerini, S.; Bresser, D. Sustain. Energy Fuels 2018, 2 (12), 2601. doi: 10.1039/C8SE00424B doi: 10.1039/C8SE00424B
57. [57]
  Hu, R. Z.; Chen, D. C.; Waller, G.; Ouyang, Y.; Chen, Y.; Zhao, B. T.; Rainwater, B.; Yang, C. H.; Zhu, M.; Liu, M. L. Energy Environ. Sci. 2016, 9 (2), 595. doi: 10.1039/C5EE03367E doi: 10.1039/C5EE03367E
58. [58]
  Wang, M. S.; Wang, Z. Q.; Jia, R.; Yang, Z. L.; Yang, Y.; Zhu, F. Y.; Huang, Y.; Li, X. J. Electroanal. Chem. 2018, 815, 30. doi: 10.1016/j.jelechem.2018.02.031 doi: 10.1016/j.jelechem.2018.02.031
59. [59]
  Ma, R. B.; Fu, Y. B.; Ma, X. H. Acta Phys. -Chim. Sin. 2009, 25 (3), 441. doi: 10.3866/PKU.WHXB20090308
60. [60]
  Liu, Y. X.; Liu, P.; Wu, D. Q.; Huang, Y. S.; Tang, Y. P.; Su, Y. Z.; Zhang, F.; Feng, X. L. Chem. Eur. J. 2015, 21 (14), 5617. doi: 10.1002/chem.201406029 doi: 10.1002/chem.201406029
61. [61]
  Xie, F. R.; Zhao, S. Q.; Bo, X. X.; Li, G. H.; Fei, J. M.; Ahmed, E.-A. M. A.; Zhang, Q. C.; Jin, H. L.; Wang, S.; Lin, Z. Q. J. Mater. Chem. A 2023, 11 (1), 53. doi: 10.1039/D2TA07435D doi: 10.1039/D2TA07435D
62. [62]
  Choo, K. Y.; Yoo, C. Y.; Han, M. H.; Kim, D. K. J. Electroanal. Chem. 2017, 806, 50. doi: 10.1016/j.jelechem.2017.10.040 doi: 10.1016/j.jelechem.2017.10.040
63. [63]
  Richards, J. J.; Hipp, J. B.; Riley, J. K.; Wagner, N. J.; Butler, P. D. Langmuir 2017, 33 (43), 12260. doi: 10.1021/acs.langmuir.7b02538 doi: 10.1021/acs.langmuir.7b02538
64. [64]
  Du, L. Y.; Bi, S. S.; Hu, Y.; Wang, R.; Zhu, J. C.; Zhang, M. H.; Niu, Z. Q. Carbon Energy 2022, 4 (4), 517. doi: 10.1002/cey2.181 doi: 10.1002/cey2.181
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  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-0. doi: 10.3866/PKU.WHXB202407020
15. [15]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
16. [16]
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17. [17]
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18. [18]
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19. [19]
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20. [20]
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

C-SnO2/MWCNTs Composite with Stable Conductive Network for Lithium-based Semi-Solid Flow Batteries

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通讯作者: 陈斌, bchen63@163.com

C-SnO₂/MWCNTs Composite with Stable Conductive Network for Lithium-based Semi-Solid Flow Batteries