Citation: Zehua Zhang, Haitao Yu, Yanyu Qi. 多重共振TADF分子的设计策略[J]. Acta Physico-Chimica Sinica, ;2025, 41(1): 230904. doi: 10.3866/PKU.WHXB202309042 shu

多重共振TADF分子的设计策略

Hebei Key Laboratory of Organic Functional Molecules, College of Chemistry and Materials Science, Hebei Normal University, Shijiazhuang 050024, China

Corresponding author: Haitao Yu, Yanyu Qi,
Received Date: 27 September 2023
Revised Date: 7 November 2023
Accepted Date: 9 November 2023

Fund Project: The project was supported by the National Natural Science Foundation of China (21971054, 22002092), S&T Program of Hebei (B2022205014, 22567622H), Science Research Project of Hebei Education Department (BJK2023014), Postdoctoral Research Projects Merit-based Funding Programs of Hebei Province (B2023005008), Shijiazhuang Science and Technology Research and Development Program (211790303A), and the Science Foundation of Hebei Normal University (L2022B12, L2023T01).

自首例多重共振热激活延迟荧光(Multiple resonance thermal activation delayed fluorescence，MR-TADF)分子报道至今，其表现出的窄带发射、高发光量子效率等特性在有机电子学，尤其是有机发光二极管(Organic light-emitting diode，OLED)等领域引发了持续的研究热度，迅速成为重点研究对象，并涌现出了众多性能出色的分子和高性能器件。以MR-TADF分子为发光层的器件不断刷新人们对OLED的认知，其中一些采用了超荧光技术所制备的器件性能代表了当今某些光色领域OLED性能的最高值。随着人们对超高分辨率显示器需求的与日俱增，国际电信联盟(ITU)宣布了下一代色域标准，即BT.2020。此标准建立了最宽的显示色域标准，要求单色的原色波长为467、532和630 nm，这个色域非常宽。同时，在如此之宽的色域上实现高分辨率的显示，对器件基元色纯度的要求达到了可谓史无前例的严格。因此，它为显示技术树立了一个具有极大挑战难度的色纯度目标。鉴于以往传统荧光材料难以担当此攻关重任，故而BT.2020的出现给予了MR-TADF分子新的发展机遇，并在很大程度上使得该领域愈发火热起来。近年来，随着大量的研究与实践，MR-TADF分子家族得到了飞速的发展，然而大家讨论和归纳的重点基本都集中在领域整体的发展方面，专门针对分子设计策略所展开的讨论和总结依旧较少，不足以为刚涉足该领域的科研人员提供足够的参考。因此，本文从X-π-X原则，快反向系间窜越过程，窄带发射与高振子强度等方面，阐述了近三年来所报道的MR-TADF分子的设计思路，并对未来可能的设计方向进行了展望，例如将一些不同于传统MR-TADF分子的结构引入这一领域。最后，对今后MR-TADF领域的发展和产业化提出建议。
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沈阳化工大学材料科学与工程学院沈阳 110142