Citation: Qianwen Han, Tenglong Zhu, Qiuqiu Lü, Mahong Yu, Qin Zhong. 氢电极支撑可逆固体氧化物电池性能及电化学不对称性优化[J]. Acta Physico-Chimica Sinica, ;2025, 41(1): 230903. doi: 10.3866/PKU.WHXB202309037 shu

氢电极支撑可逆固体氧化物电池性能及电化学不对称性优化

School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China

Corresponding author: Tenglong Zhu, zhutenglong@njust.edu.cn
Received Date: 21 September 2023
Revised Date: 6 November 2023
Accepted Date: 13 November 2023

Fund Project: The project was supported by the Key R&D Program of Jiangsu Province (BE2022029).

Ni-YSZ (镍-氧化钇稳定的氧化锆)氢电极支撑固体氧化物电池(SOC)在可逆运行模式下(R-SOC)普遍存在电化学不对称性现象。本文通过实验研究发现，氢电极扩散阻抗及电解质欧姆阻抗同时是R-SOC性能及不对称性的显著影响因素。研究结果显示，采用大孔氢电极和薄膜隔离层显著提升了R-SOC性能并减小了不对称性，在750 ℃、50% H₂O和0.3 V偏压工况下，单电池的发电及电解电流密度分别达到了0.752和0.635 A·cm^-2，电流密度不对称度△j仅为0.117 A·cm^-2。研究结果对于高性能氢电极支撑SOC单电池的结构设计、制备和可逆运行具有重要的参考价值。
- Reversible solid oxide cell,
- Electrochemical asymmetry,
- Hydrogen electrode diffusion impedance,
- Ohmic impedance,
- Thin film barrier layer
1. [1]
  (1) Staffell, I.; Scamman, D.; Abad, A. V.; Balcombe, P.; Dodds, P. E.; Ekins, P.; Shah, N.; Ward, K. R. Energ. Environ. Sci. 2019, 12, 463. doi: 10.1039/c8ee01157e
2. [2]
  (2) Wang, M. Y.; Wang, Z.; Gong, X. Z.; Guo, Z. C. Renew. Sust. Energ. Rev. 2014, 29, 573. doi: 10.1016/j.rser.2013.08.090
3. [3]
  (3) Marina, O. A.; Pederson, L. R.; Williams, M. C.; Coffey, G. W.; Meinhardt, K. D.; Nguyen, C. D.; Thomsen, E. C. J. Electrochem. Soc. 2007, 154, B452. doi: 10.1149/1.2710209
4. [4]
  (4) Njodzefon, J. C.; Klotz, D.; Kromp, A.; Weber, A.; Ivers-Tiffee, E. J. Electrochem. Soc. 2013, 160, F313. doi: 10.1149/2.018304jes
5. [5]
  (5) Cui, T. H.; Lyu, Z. W.; Han, M. F.; Sun, K. H.; Liu, Y.; Ni, M. Energy Conv. Manag. 2022, 262, 115657. doi: 10.1016/j.enconman.2022.115657
6. [6]
  (6) Ebbesen, S. D.; Sun, X. F.; Mogensen, M. B. Faraday Discuss. 2015, 182, 393. doi: 10.1039/c5fd00032g
7. [7]
  (7) Kishimoto, M.; Tanimura, Y.; Seo, H.; Iwai, H.; Yoshida, H. Int. J. Hydrog. Energy 2023, 48, 11790. doi: 10.1016/j.ijhydene.2021.07.093
8. [8]
  (8) Kusnezoff, M.; Trofimenko, N.; Müller, M.; Michaelis, A. Materials 2016, 9, 906. doi: 10.3390/ma9110906
9. [9]
  (9) Preininger, M.; Subotic, V.; Stoeckl, B.; Schauperl, R.; Reichholf, D.; Megel, S.; Kusnezoff, M.; Hochenauer, C. Int. J. Hydrog. Energy 2018, 43, 12398. doi: 10.1016/j.ijhydene.2018.04.230
10. [10]
  (10) Knibbe, R.; Hjelm, J.; Menon, M.; Pryds, N.; Sogaard, M.; Wang, H. J.; Neufeld, K. J. Am. Ceram. Soc. 2010, 93, 2877. doi: 10.1111/j.1551-2916.2010.03763.x
11. [11]
  (11) Shiono, M.; Kobayashi, K.; Nguyen, T. L.; Hosoda, K.; Kato, T.; Ota, K.; Dokiya, M. Solid State Ion. 2004, 170, 1. doi: 10.1016/j.ssi.2004.02.018
12. [12]
  (12) De Vero, J. C.; Develos-Bagarinao, K.; Matsuda, H.; Kishimoto, H.; Ishiy ama, T.; Yamaji, K.; Horita, T.; Yokokawa, H. Solid State Ion. 2018, 314, 165. doi: 10.1016/j.ssi.2017.10.023
13. [13]
  (13) Budiman, R. A.; Yamaguchi, T.; Ishiyama, T.; Develos-Bagarinao, K.; Yamaji, K.; Kishimoto, H. Mater. Lett. 2022, 309, 131419. doi: 10.1016/j.matlet.2021.131419
14. [14]
  (14) Molin, S.; Karczewski, J.; Kamecki, B.; Mrozi, A.; Wang, S. F.; Jasi, P. J. Eur. Ceram. Soc. 2020, 40, 5626. doi: 10.1016/j.jeurceramsoc.2020.06.006
15. [15]
  (15) Lyu, Q. Q.; Zhu, T. L.; Qu, H. X.; Sun, Z. H.; Sun, K. H.; Zhong, Q.; Han, M. F. J. Eur. Ceram. Soc. 2021, 41, 5931. doi: 10.1016/j.jeurceramsoc.2021.05.020
16. [16]
  (16) Yang, J.; Chen, L.; Cai, D. M.; Zhang, H.; Wang, J. X.; Guan, W. B. Int. J. Hydrog. Energy 2021, 46, 9730. doi: 10.1016/j.ijhydene.2020.12.228
17. [17]
  (17) Sun, Y.; He, S.; Saunders, M.; Chen, K.; Shao, Z.; Jiang, S. P. Int. J. Hydrog. Energy 2021, 46, 2606. doi: 10.1016/j.ijhydene.2020.10.113
18. [18]
  (18) Wang, H. Q.; Yakal-Kremski, K. J.; Yeh, T.; Rupp, G. M.; Limbeck, A.; Fleig, J.; Barnett, S. A. J. Electrochem. Soc. 2016, 163, F581. doi: 10.1149/2.0031607jes
19. [19]
20. [20]
  (20) Chen, X. Y.; Ni, W. J.; Du, X. J.; Sun, Z. H.; Zhu, T. L.; Zhong, Q.; Han, M. F. J. Mater. Sci. Technol. 2019, 35, 695. doi: 10.1016/j.jmst.2018.10.015
21. [21]
  (21) Wan, T. H.; Saccoccio, M.; Chen, C.; Ciucci, F. Electrochim. Acta 2015, 184, 483. doi: 10.1016/j.electacta.2015.09.097
22. [22]
23. [23]
  (23) Lyu, Q.; Zhu, T.; Xu, N.; Qu, H.; Zhong, Q. ACS Appl. Mater. Inter. 2023, 15, 40588. doi: 10.1021/acsami.3c08019
24. [24]
  (24) Yang, Y. R.; Tong, X. F.; Hauch, A.; Sun, X. F.; Yang, Z. B.; Peng, S. P.; Chen, M. Chem. Eng. J. 2021, 417, 129260. doi: 10.1016/j.cej.2021.129260
25. [25]
  (25) Jin, C.; Yang, C. H.; Chen, F. L. J. Membrane Sci. 2010, 363, 250. doi: 10.1016/j.memsci.2010.07.044
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