Citation: Qianwen Han, Tenglong Zhu, Qiuqiu Lü, Mahong Yu, Qin Zhong. 氢电极支撑可逆固体氧化物电池性能及电化学不对称性优化[J]. Acta Physico-Chimica Sinica, ;2025, 41(1): 230903. doi: 10.3866/PKU.WHXB202309037 shu

氢电极支撑可逆固体氧化物电池性能及电化学不对称性优化

School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China

Corresponding author: Tenglong Zhu, zhutenglong@njust.edu.cn
Received Date: 21 September 2023
Revised Date: 6 November 2023
Accepted Date: 13 November 2023

Fund Project: The project was supported by the Key R&D Program of Jiangsu Province (BE2022029).

Ni-YSZ (镍-氧化钇稳定的氧化锆)氢电极支撑固体氧化物电池(SOC)在可逆运行模式下(R-SOC)普遍存在电化学不对称性现象。本文通过实验研究发现，氢电极扩散阻抗及电解质欧姆阻抗同时是R-SOC性能及不对称性的显著影响因素。研究结果显示，采用大孔氢电极和薄膜隔离层显著提升了R-SOC性能并减小了不对称性，在750 ℃、50% H₂O和0.3 V偏压工况下，单电池的发电及电解电流密度分别达到了0.752和0.635 A·cm^-2，电流密度不对称度△j仅为0.117 A·cm^-2。研究结果对于高性能氢电极支撑SOC单电池的结构设计、制备和可逆运行具有重要的参考价值。
- Reversible solid oxide cell,
- Electrochemical asymmetry,
- Hydrogen electrode diffusion impedance,
- Ohmic impedance,
- Thin film barrier layer
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