Citation: Mingyang Men, Jinghua Wu, Gaozhan Liu, Jing Zhang, Nini Zhang, Xiayin Yao. 液相法制备硫化物固体电解质及其在全固态锂电池中的应用[J]. Acta Physico-Chimica Sinica, ;2025, 41(1): 230901. doi: 10.3866/PKU.WHXB202309019 shu

液相法制备硫化物固体电解质及其在全固态锂电池中的应用

Mingyang Men ^1,2 ,
Jinghua Wu ^1,2 ,
Gaozhan Liu ^1,2 ,
Jing Zhang ^1,2 ,
Nini Zhang ^1,2 ,
Xiayin Yao ^1,2,,

1.
Key Laboratory of Advanced Fuel Cells and Electrolyzers Technology of Zhejiang Province, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, Zhejiang Province, China;
2.
Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Xiayin Yao, yaoxy@nimte.ac.cn
Received Date: 12 September 2023
Revised Date: 11 October 2023
Accepted Date: 30 October 2023

Fund Project: The project was supported by the National Natural Science Foundation of China (22309194, 52372244), the Ningbo S&T Innovation 2025 Major Special Program (2021Z122, 2023Z106), the Zhejiang Provincial Key R&D Program of China (2022C01072), and the Youth Innovation Promotion Association CAS (Y2021080).

硫化物固体电解质具有接近甚至超过液态有机电解质的高室温离子电导率和较好的机械延展性，是一种极具应用潜力的固体电解质。其制备方式主要分为固相烧结法、高能球磨法和液相法三类。其中，固相烧结法和高能球磨法耗时长，能耗高，且合成的电解质颗粒尺寸较大。相比之下，液相法以有机溶剂为介质，可以合成颗粒较小的硫化物固体电解质，工艺简单省时，更适用于规模化生产。有鉴于此，本文总结了近年来液相法制备硫化物固体电解质的研究进展，基于原料在溶剂中的溶解状态，分析了悬浮型、溶液型和混合型三种反应类型的反应机理，并进一步探讨了溶剂对电解质纯度、形貌及结晶性的影响。同时，概述了液相法制备的硫化物固体电解质在全固态锂电池中的应用。最后，对硫化物固体电解质液相法合成的优势与局限性进行了全面的分析，以期为该领域的研究提供方向。
- All-solid-state battery,
- Sulfide solid electrolyte,
- Liquid phase method,
- Wet-chemical synthesis,
- Reaction mechanism
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