Citation: Shanghua Li, Malin Li, Xiwen Chi, Xin Yin, Zhaodi Luo, Jihong Yu. 基于高离子迁移动力学的取向ZnQ分子筛保护层实现高稳定水系锌金属负极的构筑[J]. Acta Physico-Chimica Sinica, ;2025, 41(1): 230900. doi: 10.3866/PKU.WHXB202309003 shu

基于高离子迁移动力学的取向ZnQ分子筛保护层实现高稳定水系锌金属负极的构筑

Shanghua Li ^1,2 ,
Malin Li ^1,, ,
Xiwen Chi ^1,2 ,
Xin Yin ¹ ,
Zhaodi Luo ¹ ,
Jihong Yu ^1,2,,

1.
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China;
2.
International Center of Future Science, Jilin University, Changchun 130012, China

Corresponding author: Malin Li, Jihong Yu,
Received Date: 1 September 2023
Revised Date: 25 September 2023
Accepted Date: 9 October 2023

Fund Project: The project was supported by the National Natural Science Foundation of China (22288101, 21920102005, 21835002, 22109050), and the 111 Project (B17020).

水系锌离子电池以其安全可靠、成本低、容量大、环境友好等优点被认为是最有前途的储能体系之一。然而，锌金属负极在水系电解液中通常面临严重的副反应和枝晶生长问题。在锌负极表面构建具有高离子迁移动力学的保护层是构筑高稳定、长寿命锌负极的有效策略。本文中，我们在锌负极表面制备了ZnQ分子筛(BPH拓扑)取向保护层，实现了高离子迁移动力学的稳定锌负极(ZnQ@Zn)的构筑。具有三维有序孔道的ZnQ分子筛在锌箔表面定向排列，为锌离子提供了良好的传导通路，分子筛孔道中的水分子有助于调控锌离子的配位环境，从而提高锌离子的迁移动力学。因此，ZnQ@Zn对称电池在1 mA·cm^-2的电流密度下展现出27 mV的超低过电势以及超过1100 h的循环寿命。此外，ZnQ@Zn//NaV₃O₈·1.5H₂O全电池在8 A·g^-1的电流密度下循环1800次后，容量保持率高达96%，展现出优异的循环性能。本研究为构筑高迁移动力学锌负极保护层提供了新思路，并拓展了分子筛材料在储能领域中的应用。
- Aqueous zinc ion battery,
- Zn metal anode,
- Protective layer,
- ZnQ zeolite,
- Ion migration kinetics
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