Citation: Runhua Chen, Qiong Wu, Jingchen Luo, Xiaolong Zu, Shan Zhu, Yongfu Sun. 缺陷态二维超薄材料用于光/电催化CO₂还原的基础与展望[J]. Acta Physico-Chimica Sinica, ;2025, 41(3): 230805. doi: 10.3866/PKU.WHXB202308052 shu

缺陷态二维超薄材料用于光/电催化CO₂还原的基础与展望

1.
Hefei National Research Center for Physical Sciences at Microscale, University of Science and Technology of China, Hefei 230026, China;
2.
Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM), Xiamen 361005, Fujian Province, China;
3.
State Grid Anhui Electric Power Research Institute, Hefei 230601, China

Received Date: 31 August 2023
Revised Date: 4 October 2023
Accepted Date: 17 October 2023

Fund Project: The project was supported by the National Key Research and Development Program of China (2019YFA0210004, 2022YFA1502904, 2021YFA1501502), the National Natural Science Foundation of China (22125503, 21975242, U2032212), the Youth Innovation Promotion Association of CAS (CX2340007003), the Anhui Provincial Natural Science Foundation (2208085QB31).

太阳能、风能等可再生能源驱动的光/电催化还原二氧化碳(CO₂)制碳基燃料是一种非常吸引人的资源再生和能源存储策略，这对中国实现碳达峰和碳中和战略具有重要意义。然而，CO₂分子极高的热力学稳定性和极强的化学惰性导致CO₂还原反应的转化效率和选择性仍然不理想，这严重限制了CO₂转化技术的实际应用。得益于超薄的厚度、高比表面积和相对均一的暴露晶面等特性，二维超薄材料具有高活性、高密度以及高均一的催化位点，能够优化关键的热力学和动力学因素，进而有效改善CO₂光/电还原性能。需要指出的是，缺陷态二维超薄材料中的富电子催化位点能够更高效地吸附和活化CO₂分子，从而有效降低反应势垒，加速CO₂还原并提高产物选择性。此外，二维超薄材料的缺陷结构也有助于催化过程中的质子传递和电子转移等行为，从而进一步提高催化剂的反应活性。本文综述了缺陷态二维超薄材料在CO₂光/电催化还原方面的最新研究进展，详细介绍了几类常见的缺陷态二维超薄材料的可控制备方法和精细结构表征。结合典型实例，系统总结了表面缺陷结构对二维超薄材料的局域原子结构和电子结构的调制作用，以及对CO₂还原性能的影响。最后，展望了缺陷态二维超薄材料在CO₂还原领域所面临的挑战与机遇，为今后的研究提供了借鉴和启示。
- Defect,
- Ultrathin two-dimensional materials,
- CO₂ reduction,
- Photo-/Electrocatalysis
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

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南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com

缺陷态二维超薄材料用于光/电催化CO₂还原的基础与展望