Citation: Runhua Chen, Qiong Wu, Jingchen Luo, Xiaolong Zu, Shan Zhu, Yongfu Sun. 缺陷态二维超薄材料用于光/电催化CO₂还原的基础与展望[J]. Acta Physico-Chimica Sinica, ;2025, 41(3): 230805. doi: 10.3866/PKU.WHXB202308052 shu

缺陷态二维超薄材料用于光/电催化CO₂还原的基础与展望

1.
Hefei National Research Center for Physical Sciences at Microscale, University of Science and Technology of China, Hefei 230026, China;
2.
Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM), Xiamen 361005, Fujian Province, China;
3.
State Grid Anhui Electric Power Research Institute, Hefei 230601, China

Received Date: 31 August 2023
Revised Date: 4 October 2023
Accepted Date: 17 October 2023

Fund Project: The project was supported by the National Key Research and Development Program of China (2019YFA0210004, 2022YFA1502904, 2021YFA1501502), the National Natural Science Foundation of China (22125503, 21975242, U2032212), the Youth Innovation Promotion Association of CAS (CX2340007003), the Anhui Provincial Natural Science Foundation (2208085QB31).

太阳能、风能等可再生能源驱动的光/电催化还原二氧化碳(CO₂)制碳基燃料是一种非常吸引人的资源再生和能源存储策略，这对中国实现碳达峰和碳中和战略具有重要意义。然而，CO₂分子极高的热力学稳定性和极强的化学惰性导致CO₂还原反应的转化效率和选择性仍然不理想，这严重限制了CO₂转化技术的实际应用。得益于超薄的厚度、高比表面积和相对均一的暴露晶面等特性，二维超薄材料具有高活性、高密度以及高均一的催化位点，能够优化关键的热力学和动力学因素，进而有效改善CO₂光/电还原性能。需要指出的是，缺陷态二维超薄材料中的富电子催化位点能够更高效地吸附和活化CO₂分子，从而有效降低反应势垒，加速CO₂还原并提高产物选择性。此外，二维超薄材料的缺陷结构也有助于催化过程中的质子传递和电子转移等行为，从而进一步提高催化剂的反应活性。本文综述了缺陷态二维超薄材料在CO₂光/电催化还原方面的最新研究进展，详细介绍了几类常见的缺陷态二维超薄材料的可控制备方法和精细结构表征。结合典型实例，系统总结了表面缺陷结构对二维超薄材料的局域原子结构和电子结构的调制作用，以及对CO₂还原性能的影响。最后，展望了缺陷态二维超薄材料在CO₂还原领域所面临的挑战与机遇，为今后的研究提供了借鉴和启示。
- Defect,
- Ultrathin two-dimensional materials,
- CO₂ reduction,
- Photo-/Electrocatalysis
1. [1]
  (1) Aresta, M.; Dibenedetto, A.; Angelini, A. Chem. Rev. 2014, 114, 1709. doi:10.1021/cr4002758
2. [2]
  (2) Gao, S.; Lin, Y.; Jiao, X.; Sun, Y.; Luo, Q.; Zhang, W.; Li, D.; Yang, J.; Xie, Y. Nature 2016, 529, 68. doi:10.1038/nature16455
3. [3]
  (3) Li, Y.; Li, F.; Laaksonen, A.; Wang, C.; Cobden, P.; Boden, P.; Liu, Y.; Zhang, X.; Ji, X. Ind. Chem. Mater. 2023, 1, 410. doi:10.1039/D2IM00055E
4. [4]
  (4) Jiang, J.; Xiong, Z.; Wang, H.; Liao, G.; Bai, S.; Zou, J.; Wu, P.; Zhang, P.; Li, X. J. Mater. Sci. Technol. 2022, 118, 15. doi:10.1016/j.jmst.2021.12.018
5. [5]
  (5) Wu, Y.; Wu, M.; Zhu, J.; Zhang, X.; Li, J.; Zheng, K.; Hu, J.; Liu, C.; Pan, Y.; Zhu, J.; et al. Sci. China Chem. 2023, 66, 1997. doi:10.1007/s11426-022-1595-9
6. [6]
7. [7]
  (7) Bai, S.; Zhang, N.; Gao, C.; Xiong, Y. Nano Energy 2018, 53, 296. doi:10.1016/j.nanoen.2018.08.058
8. [8]
  (8) Sun, Y.; Gao, S.; Lei, F.; Xie, Y. Chem. Soc. Rev. 2015, 44, 623. doi:10.1039/C4CS00236A
9. [9]
  (9) Wang, Y.; Liu, J.; Zheng, G. Adv. Mater. 2021, 33, 2005798. doi:10.1002/adma.202005798
10. [10]
  (10) Zhou, W.; Fu, H. Inorg. Chem. Front. 2018, 5, 1240. doi:10.1039/C8QI00122G
11. [11]
  (11) Jiang, J.; Li, F.; Bai, S.; Wang, Y.; Xiang, K.; Wang, H.; Zou, J.; Hsu, J.-P. Nano Res. 2023, 16, 4656. doi:10.1007/s12274-022-5112-x
12. [12]
  (12) Jiang, J.; Ou-yang, L.; Zhu, L.; Zheng, A.; Zou, J.; Yi, X.; Tang, H. Carbon 2014, 80, 213. doi:10.1016/j.carbon.2014.08.059
13. [13]
  (13) Zou, J.; Wu, S.; Liu, Y.; Sun, Y.; Cao, Y.; Hsu, J.-P.; Shen Wee, A. T.; Jiang, J. Carbon 2018, 130, 652. doi:10.1016/j.carbon.2018.01.008
14. [14]
  (14) Jiao, X.; Hu, Z.; Li, L.; Wu, Y.; Zheng, K.; Sun, Y.; Xie, Y. Sci. China Chem. 2022, 65, 428. doi:10.1007/s11426-021-1184-6
15. [15]
  (15) Li, X.; Wang, S.; Li, L.; Sun, Y.; Xie, Y. J. Am. Chem. Soc. 2020, 142, 9567. doi:10.1021/jacs.0c02973
16. [16]
  (16) Corma, A.; Garcia, H. J. Catal. 2013, 308, 168. doi:10.1016/j.jcat.2013.06.008
17. [17]
  (17) Nitopi, S.; Bertheussen, E.; Scott, S. B.; Liu, X.; Engstfeld, A. K.; Horch, S.; Seger, B.; Stephens, I. E. L.; Chan, K.; Hahn, C.; et al. Chem. Rev. 2019, 119, 7610. doi:10.1021/acs.chemrev.8b00705
18. [18]
  (18) Chang, X.; Wang, T.; Gong, J. Energy Environ. Sci. 2016, 9, 2177. doi:10.1039/C6EE00383D
19. [19]
  (19) Ménard, G.; Stephan, D. W. Angew. Chem. Int. Ed. 2011, 50, 8396. doi:10.1002/anie.201103600
20. [20]
21. [21]
  (21) Sun, Z.; Ma, T.; Tao, H.; Fan, Q.; Han, B. Chem 2017, 3, 560. doi:10.1016/j.chempr.2017.09.009
22. [22]
  (22) Zhou, Y.; Wang, Z.; Huang, L.; Zaman, S.; Lei, K.; Yue, T.; Li, Z. A.; You, B.; Xia, B. Y. Adv. Energy Mater. 2021, 11, 2003159. doi:10.1002/aenm.202003159
23. [23]
  (23) Zhao, Y.; Chen, G.; Bian, T.; Zhou, C.; Waterhouse, G. I. N.; Wu, L.-Z.; Tung, C.-H.; Smith, L. J.; O’Hare, D.; Zhang, T. Adv. Mater. 2015, 27, 7824. doi:10.1002/adma.201503730
24. [24]
  (24) Guan, M.; Xiao, C.; Zhang, J.; Fan, S.; An, R.; Cheng, Q.; Xie, J.; Zhou, M.; Ye, B.; Xie, Y. J. Am. Chem. Soc. 2013, 135, 10411. doi:10.1021/ja402956f
25. [25]
  (25) Di, J.; Zhao, X.; Lian, C.; Ji, M.; Xia, J.; Xiong, J.; Zhou, W.; Cao, X.; She, Y.; Liu, H.; et al. Nano Energy 2019, 61, 54. doi:10.1016/j.nanoen.2019.04.029
26. [26]
  (26) Jiao, X.; Chen, Z.; Li, X.; Sun, Y.; Gao, S.; Yan, W.; Wang, C.; Zhang, Q.; Lin, Y.; Luo, Y.; et al. J. Am. Chem. Soc. 2017, 139, 7586. doi:10.1021/jacs.7b02290
27. [27]
  (27) Xue, X.; Chen, R.; Chen, H.; Hu, Y.; Ding, Q.; Liu, Z.; Ma, L.; Zhu, G.; Zhang, W.; Yu, Q.; et al. Nano Lett. 2018, 18, 7372. doi:10.1021/acs.nanolett.8b03655
28. [28]
  (28) Li, P.; Wang, F.; Wei, S.; Li, X.; Zhou, Y. Phys. Chem. Chem. Phys. 2017, 19, 4405. doi:10.1039/C6CP08409E
29. [29]
  (29) Li, H.; Tsai, C.; Koh, A. L.; Cai, L.; Contryman, A. W.; Fragapane, A. H.; Zhao, J.; Han, H. S.; Manoharan, H. C.; Abild-Pedersen, F.; et al. Nat. Mater. 2016, 15, 48. doi:10.1038/nmat4465
30. [30]
  (30) Xu, L.; Jiang, Q.; Xiao, Z.; Li, X.; Huo, J.; Wang, S.; Dai, L. Angew. Chem. Int. Ed. 2016, 55, 5277. doi:10.1002/anie.201600687
31. [31]
  (31) Wu, J.; Li, X.; Shi, W.; Ling, P.; Sun, Y.; Jiao, X.; Gao, S.; Liang, L.; Xu, J.; Yan, W.; et al. Angew. Chem. Int. Ed. 2018, 57, 8719. doi:10.1002/anie.201803514
32. [32]
  (32) Chen, X.; Liu, L.; Yu, P. Y.; Mao, S. S. Science 2011, 331, 746. doi:10.1126/science.1200448
33. [33]
  (33) Zhao, Z.; Zhang, X.; Zhang, G.; Liu, Z.; Qu, D.; Miao, X.; Feng, P.; Sun, Z. Nano Res. 2015, 8, 4061. doi:10.1007/s12274-015-0917-5
34. [34]
  (34) Zou, X.; Liu, J.; Su, J.; Zuo, F.; Chen, J.; Feng, P. Chem. - Eur. J. 2013, 19, 2866. doi:10.1002/chem.201202833
35. [35]
  (35) Niu, P.; Yin, L.-C.; Yang, Y.-Q.; Liu, G.; Cheng, H.-M. Adv. Mater. 2014, 26, 8046. doi:10.1002/adma.201404057
36. [36]
  (36) Li, X.; Sun, Y.; Xu, J.; Shao, Y.; Wu, J.; Xu, X.; Pan, Y.; Ju, H.; Zhu, J.; Xie, Y. Nat. Energy 2019, 4, 690. doi:10.1038/s41560-019-0431-1
37. [37]
  (37) Lei, F.; Sun, Y.; Liu, K.; Gao, S.; Liang, L.; Pan, B.; Xie, Y. J. Am. Chem. Soc. 2014, 136, 6826. doi:10.1021/ja501866r
38. [38]
  (38) Sun, Y.; Gao, S.; Lei, F.; Liu, J.; Liang, L.; Xie, Y. Chem. Sci. 2014, 5, 3976. doi:10.1039/C4SC00565A
39. [39]
  (39) Sun, Y.; Liu, Q.; Gao, S.; Cheng, H.; Lei, F.; Sun, Z.; Jiang, Y.; Su, H.; Wei, S.; Xie, Y. Nat. Commun. 2013, 4, 2899. doi:10.1038/ncomms3899
40. [40]
  (40) Xiong, Y.; Zhao, W.; Gu, D.; Tie, Z.; Zhang, W.; Jin, Z. Nano Lett. 2023, 23, 4876. doi:10.1021/acs.nanolett.3c00524
41. [41]
  (41) Jiang, M.; Zhu, M.; Wang, M.; He, Y.; Luo, X.; Wu, C.; Zhang, L.; Jin, Z. ACS Nano 2023, 17, 3209. doi:10.1021/acsnano.2c11046
42. [42]
  (42) Čížek, J. J. Mater. Sci. Technol. 2018, 34, 577. doi:10.1016/j.jmst.2017.11.050
43. [43]
  (43) Gao, S.; Gu, B.; Jiao, X.; Sun, Y.; Zu, X.; Yang, F.; Zhu, W.; Wang, C.; Feng, Z.; Ye, B.; et al. J. Am. Chem. Soc. 2017, 139, 3438. doi:10.1021/jacs.6b11263
44. [44]
  (44) Sun, Y.; Cheng, H.; Gao, S.; Liu, Q.; Sun, Z.; Xiao, C.; Wu, C.; Wei, S.; Xie, Y. J. Am. Chem. Soc. 2012, 134, 20294. doi:10.1021/ja3102049
45. [45]
  (45) Wang, Z.; Zu, X.; Li, X.; Li, L.; Wu, Y.; Wang, S.; Ling, P.; Zhao, Y.; Sun, Y.; Xie, Y. Nano Res. 2022, 15, 6999. doi:10.1007/s12274-022-4335-1
46. [46]
  (46) Shi, X.; Dong, X. A.; He, Y.; Yan, P.; Zhang, S.; Dong, F. ACS Catal. 2022, 12, 3965. doi:10.1021/acscatal.2c00157
47. [47]
  (47) Liu, Y.; Xiao, C.; Li, Z.; Xie, Y. Adv. Energy Mater. 2016, 6, 1600436. doi:10.1002/aenm.201600436
48. [48]
  (48) Sun, X.; Zhang, X.; Xie, Y. Matter 2020, 2, 842. doi:10.1016/j.matt.2020.02.006
49. [49]
  (49) Jiang, M.; Zhu, M.; Wang, H.; Song, X.; Liang, J.; Lin, D.; Li, C.; Cui, J.; Li, F.; Zhang, X. L.; et al. Nano Lett. 2023, 23, 291. doi:10.1021/acs.nanolett.2c04335
50. [50]
  (50) Gao, S.; Sun, Z.; Liu, W.; Jiao, X.; Zu, X.; Hu, Q.; Sun, Y.; Yao, T.; Zhang, W.; Wei, S.; et al. Nat. Commun. 2017, 8, 14503. doi:10.1038/ncomms14503
51. [51]
  (51) Liang, L.; Ling, P.; Li, Y.; Li, L.; Liu, J.; Luo, Q.; Zhang, H.; Xu, Q.; Pan, Y.; Zhu, J.; et al. Sci. China Chem. 2021, 64, 953. doi:10.1007/s11426-021-9967-9
52. [52]
  (52) Wang, H.; Bi, X.; Yan, Y.; Zhao, Y.; Yang, Z.; Ning, H.; Wu, M. Adv. Funct. Mater. 2023, 33, 2214946. doi:10.1002/adfm.202214946
53. [53]
  (53) Jia, S.; Wu, L.; Xu, L.; Sun, X.; Han, B. Ind. Chem. Mater. 2023, 1, 93. doi:10.1039/D2IM00056C
54. [54]
  (54) Wang, X.; Ma, S.; Liu, B.; Wang, S.; Huang, W. Chem. Commun. 2023, 59, 10044. doi:10.1039/D3CC02843G
55. [55]
  (55) Zu, X.; Zhao, Y.; Li, X.; Chen, R.; Shao, W.; Wang, Z.; Hu, J.; Zhu, J.; Pan, Y.; Sun, Y.; et al. Angew. Chem. Int. Ed. 2021, 60, 13840. doi:10.1002/anie.202101894
56. [56]
  (56) Liu, K.; Li, X.; Liang, L.; Wu, J.; Jiao, X.; Xu, J.; Sun, Y.; Xie, Y. Nano Res. 2018, 11, 2897. doi:10.1007/s12274-017-1943-2
57. [57]
  (57) Ling, P.; Zhu, J.; Wang, Z.; Hu, J.; Zhu, J.; Yan, W.; Sun, Y.; Xie, Y. Nanoscale 2022, 14, 14023. doi:10.1039/D2NR02364D
58. [58]
  (58) Zhu, S.; Li, X.; Jiao, X.; Shao, W.; Li, L.; Zu, X.; Hu, J.; Zhu, J.; Yan, W.; Wang, C.; et al. Nano Lett. 2021, 21, 2324. doi:10.1021/acs.nanolett.1c00383
59. [59]
  (59) Zhu, J.; Shao, W.; Li, X.; Jiao, X.; Zhu, J.; Sun, Y.; Xie, Y. J. Am. Chem. Soc. 2021, 143, 18233. doi:10.1021/jacs.1c08033
60. [60]
  (60) Jiao, X.; Zheng, K.; Liang, L.; Li, X.; Sun, Y.; Xie, Y. Chem. Soc. Rev. 2020, 49, 6592. doi:10.1039/D0CS00332H
61. [61]
  (61) Chen, Z.; Concepcion, J. J.; Brennaman, M. K.; Kang, P.; Norris, M. R.; Hoertz, P. G.; Meyer, T. J. Proc. Natl. Acad. Sci. 2012, 109, 15606. doi:10.1073/pnas.1203122109
62. [62]
  (62) Liang, L.; Li, X.; Sun, Y.; Tan, Y.; Jiao, X.; Ju, H.; Qi, Z.; Zhu, J.; Xie, Y. Joule 2018, 2, 1004. doi:10.1016/j.joule.2018.02.019
63. [63]
  (63) Shi, J.; Cui, H. N.; Liang, Z.; Lu, X.; Tong, Y.; Su, C.; Liu, H. Energy Environ. Sci. 2011, 4, 466. doi:10.1039/C0EE00309C
64. [64]
  (64) Kong, M.; Li, Y.; Chen, X.; Tian, T.; Fang, P.; Zheng, F.; Zhao, X. J. Am. Chem. Soc. 2011, 133, 16414. doi:10.1021/ja207826q
65. [65]
  (65) Bi, W.; Ye, C.; Xiao, C.; Tong, W.; Zhang, X.; Shao, W.; Xie, Y. Small 2014, 10, 2820. doi:10.1002/smll.201303548
66. [66]
  (66) Hou, J.; Cao, S.; Wu, Y.; Liang, F.; Sun, Y.; Lin, Z.; Sun, L. Nano Energy 2017, 32, 359. doi:10.1016/j.nanoen.2016.12.054
67. [67]
  (67) Huygh, S.; Bogaerts, A.; Neyts, E. C. J. Phys. Chem. C 2016, 120, 21659. doi:10.1021/acs.jpcc.6b07459
68. [68]
  (68) Shao, W.; Li, X.; Zhu, J.; Zu, X.; Liang, L.; Hu, J.; Pan, Y.; Zhu, J.; Yan, W.; Sun, Y.; et al. Nano Res. 2022, 15, 1882. doi:10.1007/s12274-021-3789-x
69. [69]
  (69) Ye, F.; Zhang, S.; Cheng, Q.; Long, Y.; Liu, D.; Paul, R.; Fang, Y.; Su, Y.; Qu, L.; Dai, L.; et al. Nat. Commun. 2023, 14, 2040. doi:10.1038/s41467-023-37679-3
70. [70]
  (70) Sun, Y.; Sun, Z.; Gao, S.; Cheng, H.; Liu, Q.; Piao, J.; Yao, T.; Wu, C.; Hu, S.; Wei, S.; et al. Nat. Commun. 2012, 3, 1057. doi:10.1038/ncomms2066
71. [71]
  (71) Li, Z.; Cao, A.; Zheng, Q.; Fu, Y.; Wang, T.; Arul, K. T.; Chen, J.-L.; Yang, B.; Adli, N. M.; Lei, L.; et al. Adv. Mater. 2021, 33, 2005113. doi:10.1002/adma.202005113
72. [72]
  (72) Zhang, B.; Zhang, J.; Hua, M.; Wan, Q.; Su, Z.; Tan, X.; Liu, L.; Zhang, F.; Chen, G.; Tan, D.; et al. J. Am. Chem. Soc. 2020, 142, 13606. doi:10.1021/jacs.0c06420
73. [73]
  (73) Peng, C.; Luo, G.; Zhang, J.; Chen, M.; Wang, Z.; Sham, T.-K.; Zhang, L.; Li, Y.; Zheng, G. Nat. Commun. 2021, 12, 1580. doi:10.1038/s41467-021-21901-1
74. [74]
  (74) Li, F.; Anjarsari, Y.; Wang, J.; Azzahiidah, R.; Jiang, J.; Zou, J.; Xiang, K.; Ma, H.; Arramel. Carbon Lett. 2023, 33, 1321. doi:10.1007/s42823-022-00380-4
75. [75]
  (75) Wang, J.; Jiang, J.; Li, F.; Zou, J.; Xiang, K.; Wang, H.; Li, Y.; Li, X. Green Chem. 2023, 25, 32. doi:10.1039/D2GC03160D
76. [76]
  (76) Wang, J.; Qin, Q.; Li, F.; Anjarsari, Y.; Sun, W.; Azzahiidah, R.; Zou, J.; Xiang, K.; Ma, H.; Jiang, J.; et al. Carbon Lett. 2023, 33, 1381. doi:10.1007/s42823-022-00401-2
77. [77]
  (77) Lei, W.; Zhou, T.; Pang, X.; Xue, S.; Xu, Q. J. Mater. Sci. Technol. 2022, 114, 143. doi:10.1016/j.jmst.2021.10.029
78. [78]
  (78) Wang, W.; Duan, J.; Liu, Y.; Zhai, T. Adv. Mater. 2022, 34, 2110699. doi:10.1002/adma.202110699
79. [79]
  (79) Yang, S.; Jiang, M.; Zhang, W.; Hu, Y.; Liang, J.; Wang, Y.; Tie, Z.; Jin, Z. Adv. Funct. Mater. 2023, 33, 2301984. doi:10.1002/adfm.202301984
80. [80]
  (80) Wang, S.; Hai, X.; Ding, X.; Chang, K.; Xiang, Y.; Meng, X.; Yang, Z.; Chen, H.; Ye, J. Adv. Mater. 2017, 29, 1701774. doi:10.1002/adma.201701774
81. [81]
  (81) Luo, S.; Li, X.; Wang, M.; Zhang, X.; Gao, W.; Su, S.; Liu, G.; Luo, M. J. Mater. Chem. A 2020, 8, 5647. doi:10.1039/D0TA01154A
1. [1]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
2. [2]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
3. [3]
  Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO₂ capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213
4. [4]
  Wei HE , Jing XI , Tianpei HE , Na CHEN , Quan YUAN . Application of solar-driven inorganic semiconductor-microbe hybrids in carbon dioxide fixation and biomanufacturing. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 35-44. doi: 10.11862/CJIC.20240364
5. [5]
  Baohua LÜ , Yuzhen LI . Anisotropic photoresponse of two-dimensional layered α-In₂Se₃(2H) ferroelectric materials. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1911-1918. doi: 10.11862/CJIC.20240105
6. [6]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
7. [7]
  Huayan Liu , Yifei Chen , Mengzhao Yang , Jiajun Gu . Strategies for enhancing capacity and rate performance of two-dimensional material-based supercapacitors. Acta Physico-Chimica Sinica, 2025, 41(6): 100063-. doi: 10.1016/j.actphy.2025.100063
8. [8]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
9. [9]
  Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195
10. [10]
  Huanhuan XIE , Yingnan SONG , Lei LI . Two-dimensional single-layer BiOI nanosheets: Lattice thermal conductivity and phonon transport mechanism. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 702-708. doi: 10.11862/CJIC.20240281
11. [11]
  Haiyu Zhu , Zhuoqun Wen , Wen Xiong , Xingzhan Wei , Zhi Wang . Accurate and efficient prediction of Schottky barrier heights in 2D semimetal/silicon heterojunctions. Acta Physico-Chimica Sinica, 2025, 41(7): 100078-. doi: 10.1016/j.actphy.2025.100078
12. [12]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
13. [13]
  Meng Lin , Hanrui Chen , Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117
14. [14]
  Xueting Cao , Shuangshuang Cha , Ming Gong . 电催化反应中的界面双电层：理论、表征与应用. Acta Physico-Chimica Sinica, 2025, 41(5): 100041-. doi: 10.1016/j.actphy.2024.100041
15. [15]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
16. [16]
  Yongzhi LI , Han ZHANG , Gangding WANG , Yanwei SUI , Lei HOU , Yaoyu WANG . A two-dimensional metal-organic framework for the determination of nitrofurantoin and nitrofurazone in aqueous solution. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 245-253. doi: 10.11862/CJIC.20240307
17. [17]
  Shiyang He , Dandan Chu , Zhixin Pang , Yuhang Du , Jiayi Wang , Yuhong Chen , Yumeng Su , Jianhua Qin , Xiangrong Pan , Zhan Zhou , Jingguo Li , Lufang Ma , Chaoliang Tan . 铂单原子功能化的二维Al-TCPP金属-有机框架纳米片用于增强光动力抗菌治疗. Acta Physico-Chimica Sinica, 2025, 41(5): 100046-. doi: 10.1016/j.actphy.2025.100046
18. [18]
  Zhuoyan Lv , Yangming Ding , Leilei Kang , Lin Li , Xiao Yan Liu , Aiqin Wang , Tao Zhang . Light-Enhanced Direct Epoxidation of Propylene by Molecular Oxygen over CuO_x/TiO₂ Catalyst. Acta Physico-Chimica Sinica, 2025, 41(4): 100038-. doi: 10.3866/PKU.WHXB202408015
19. [19]
  .
  CCS Chemistry 综述推荐│绿色氧化新思路：光/电催化助力有机物高效升级
  . CCS Chemistry, 2025, 7(10.31635/ccschem.024.202405369): -.
20. [20]
  .
  南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积
  . CCS Chemistry, 2025, 7(0): -.

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(51)
HTML views(0)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

缺陷态二维超薄材料用于光/电催化CO2还原的基础与展望

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

Metrics

通讯作者: 陈斌, bchen63@163.com

缺陷态二维超薄材料用于光/电催化CO₂还原的基础与展望