Citation: Jiandong Liu, Zhijia Zhang, Kamenskii Mikhail, Volkov Filipp, Eliseeva Svetlana, Jianmin Ma. Research Progress on Cathode Electrolyte Interphase in High-Voltage Lithium Batteries[J]. Acta Physico-Chimica Sinica, ;2025, 41(2): 230804. doi: 10.3866/PKU.WHXB202308048 shu

Research Progress on Cathode Electrolyte Interphase in High-Voltage Lithium Batteries

1.
School of Chemistry, Tiangong University, Tianjin 300387, China
2.
School of Physics and Electronics, Hunan University, Changsha 410022, China
3.
School of Material Science and Engineering, Tiangong University, Tianjin 300387, China
4.
Institute of Chemistry, Saint Petersburg State University, Saint Petersburg 199034, Russia

Corresponding author: Jianmin Ma,
Received Date: 30 August 2023
Revised Date: 6 October 2023
Accepted Date: 30 October 2023

Fund Project: the National Natural Science Foundation of China U21A20311

Achieving high energy density batteries is currently a key focus in the field of energy storage. Lithium batteries, due to their high energy density, have garnered significant attention in research. Increasing the upper limit of the battery's cut-off voltage can boost the energy density of lithium batteries. However, high-voltage conditions can lead to irreversible phase transitions and side reactions in cathode materials, which can degrade battery performance and even result in safety risks, including explosions. The electrolyte can also decompose, causing capacity loss and releasing flammable gases when subjected to high voltage, which can lead to battery swelling and potential combustion and explosions. Designing an ideal cathode electrolyte interphase (CEI) on the cathode's surface to regulate the electrode-electrolyte interface reaction can effectively enhance the cycling stability of the battery, reduce irreversible phase transitions in the cathode, and improve the oxidation stability of the electrolyte. The ideal CEI should possess high ion conductivity, high thermal stability, and should minimize interface side reactions to ensure optimal battery performance. Understanding the formation and development of CEI is crucial for enhancing battery performance under high voltage. Apart from creating artificial CEI, modifying electrolytes has gained significant attention. By altering the electrolyte recipe, an ideal CEI can be achieved. Electrolyte engineering is considered an effective strategy for attaining an ideal CEI and enhancing the stability of high nickel positive electrodes. This approach is simple, cost-effective, and holds great promise for achieving higher energy density in lithium batteries. To provide a better understanding of CEI in lithium ion batteries (LIBs), this article reviews the latest advancements in CEI, including the formation mechanism of CEI, the key factors influencing CEI, methods for modifying CEI, and techniques for characterizing CEI. Additionally, it summarizes the current status of artificial CEI development and in situ CEI generation through electrolyte design. The aim is to offer fundamental guidance for future research and the design of high-voltage battery CEI. Finally, the article outlines the opportunities and challenges in electrolyte engineering for modified CEI, pointing towards the future direction of constructing an ideal CEI.
- High-voltage cathode,
- Cathode electrolyte interphase,
- Electrolyte engineering,
- Electrolyte additive,
- Lithium battery
1. [1]
  Goodenough J. B., Park K. -S. J. Am. Chem. Soc, 2013, 135, 1167 doi: 10.1021/ja3091438 doi: 10.1021/ja3091438
2. [2]
  Jia H., Xu W. Trends Chem, 2022, 4, 627 doi: 10.1016/j.trechm.2022.04.010 doi: 10.1016/j.trechm.2022.04.010
3. [3]
  Wu Y., Liu X., Wang L., Feng X., Ren D., Li Y., Rui X., Wang Y., Han X. Xu G. -L., et al. Energy Storage Mater, 2021, 37, 77 doi: 10.1016/j.ensm.2021.02.001 doi: 10.1016/j.ensm.2021.02.001
4. [4]
  Pham H. Q., Chung G. J., Han J., Hwang E. -H., Kwon Y. -G., Song S. -W. J. Chem. Phys, 2020, 152, 094709 doi: 10.1063/1.5144280 doi: 10.1063/1.5144280
5. [5]
  Zhang J. Wang P. -F., Bai P., Wan H., Liu S., Hou S., Pu X., Xia J., Zhang W., Wang Z., et al. Adv. Mater, 2022, 34, 2108353 doi: 10.1002/adma.202108353 doi: 10.1002/adma.202108353
6. [6]
  Li W., Song B., Manthiram A. Chem. Soc. Rev, 2017, 46, 3006 doi: 10.1039/C6CS00875E doi: 10.1039/C6CS00875E
7. [7]
  Kong D., Hu J., Chen Z., Song K., Li C., Weng M., Li M., Wang R., Liu T., Liu J., et al. Adv. Energy Mater, 2019, 9, 1901756 doi: 10.1002/aenm.201901756 doi: 10.1002/aenm.201901756
8. [8]
  Ren X., Chen S., Lee H., Mei D., Engelhard M. H., Burton S. D., Zhao W., Zheng J., Li Q. Ding M. S., et al. Chem, 2018, 4, 1877 doi: 10.1016/j.chempr.2018.05.002 doi: 10.1016/j.chempr.2018.05.002
9. [9]
  Song S. H., Cho M., Park I., Yoo J. -G., Ko K. -T., Hong J., Kim J. Jung S. -K., Avdeev M., Ji S., et al. Adv. Energy Mater, 2020, 10, 2000521 doi: 10.1002/aenm.202000521 doi: 10.1002/aenm.202000521
10. [10]
  Piao Z., Gao R., Liu Y., Zhou G., Cheng H. -M. Adv. Mater., 2023, 35, 2206009 doi: 10.1002/adma.202206009 doi: 10.1002/adma.202206009
11. [11]
  Qin Y., Cheng H., Zhou J., Liu M., Ding X., Li Y., Huang Y., Chen Z., Shen C., Wang D., et al. Energy Storage Mater, 2023, 57, 411 doi: 10.1016/j.ensm.2023.02.022 doi: 10.1016/j.ensm.2023.02.022
12. [12]
  Sun H. H., Kim U. -H., Park J. -H., Park S. -W., Seo D. -H., Heller A., Mullins C. B., Yoon C. S., Sun Y. -K. Nat. Commun, 2021, 12, 6552 doi: 10.1038/s41467-021-26815-6 doi: 10.1038/s41467-021-26815-6
13. [13]
  Zhou K., Xie Q., Li B., Manthiram A. Energy Storage Mater, 2021, 34, 229 doi: 10.1016/j.ensm.2020.09.015 doi: 10.1016/j.ensm.2020.09.015
14. [14]
  Li J., Li W., Wang S., Jarvis K., Yang J., Manthiram A. Chem. Mater, 2018, 30, 3101 doi: 10.1021/acs.chemmater.8b01077 doi: 10.1021/acs.chemmater.8b01077
15. [15]
  Xie Q., Li W., Dolocan A., Manthiram A. Chem. Mater, 2019, 31, 8886 doi: 10.1021/acs.chemmater.9b02916 doi: 10.1021/acs.chemmater.9b02916
16. [16]
  Nisar U., Muralidharan N., Essehli R., Amin R., Belharouak I. Energy Storage Mater, 2021, 38, 309 doi: 10.1016/j.ensm.2021.03.015 doi: 10.1016/j.ensm.2021.03.015
17. [17]
  Woo S. U., Yoon C. S., Amine K., Belharouak I., Sun Y. K. J. Electrochem. Soc, 2007, 154, A1005 doi: 10.1149/1.2776160 doi: 10.1149/1.2776160
18. [18]
  Ahmed B., Xia C., Alshareef H. N. Nano Today, 2016, 11, 250 doi: 10.1016/j.nantod.2016.04.004 doi: 10.1016/j.nantod.2016.04.004
19. [19]
  Li W., Liu X., Celio H., Smith P., Dolocan A., Chi M., Manthiram A. Adv. Energy Mater, 2018, 8, 1703154 doi: 10.1002/aenm.201703154 doi: 10.1002/aenm.201703154
20. [20]
  You Y., Celio H., Li J., Dolocan A., Manthiram A. Angew. Chem. Int. Ed, 2018, 57, 6480 doi: 10.1002/anie.201801533 doi: 10.1002/anie.201801533
21. [21]
  Gao S., Zhan X., Cheng Y. -T. J. Power Sources, 2019, 410-411, 45. doi: 10.1016/j.jpowsour.2018.10.094 doi: 10.1016/j.jpowsour.2018.10.094
22. [22]
  Shu Y., Xie Y., Yan W., Meng S., Sun D., Jin Y., Xiang L. Ceramics Int, 2020, 46, 14840 doi: 10.1016/j.ceramint.2020.03.009 doi: 10.1016/j.ceramint
23. [23]
  Mou J., Deng Y., He L., Zheng Q., Jiang N., Lin D. Electrochim. Acta, 2018, 260, 101 doi: 10.1016/j.electacta.2017.11.059 doi: 10.1016/j.electacta
24. [24]
  Cao G., Jin Z., Zhu J., Li Y., Xu B., Xiong Y., Yang J. J. Alloys Compd, 2020, 832, 153788 doi: 10.1016/j.jallcom.2020.153788 doi: 10.1016/j.jallcom
25. [25]
  Zhang Z., Yang J., Huang W., Wang H., Zhou W., Li Y., Li Y., Xu J., Huang W., Chiu W., et al. Matter, 2021, 4, 302 doi: 10.1016/j.matt.2020.10.021 doi: 10.1016/j.matt.2020.10.021
26. [26]
  Chen D., Mahmoud M. A., Wang J. -H., Waller G. H., Zhao B., Qu C., El-Sayed M. A., Liu M. Nano Lett, 2019, 19, 2037 doi: 10.1021/acs.nanolett.9b00179 doi: 10.1021/acs.nanolett.9b00179
27. [27]
  Wang S., Dai A., Cao Y., Yang H., Khalil A., Lu J., Li H., Ai X. J. Mater. Chem. A, 2021, 9, 11623 doi: 10.1039/D1TA02563E doi: 10.1039/D1TA02563E
28. [28]
  Thomas M. G. S. R., Bruce P. G., Goodenough J. B. J. Electrochem. Soc, 1985, 132, 1521 doi: 10.1149/1.2114158 doi: 10.1149/1.2114158
29. [29]
  Kanamura K., Toriyama S., Shiraishi S., Ohashi M., Takehara Z. -I. J. Electroanal. Chem, 1996, 419, 77 doi: 10.1016/S0022-0728(96)04862-0 doi: 10.1016/S0022-0728(96)04862-0
30. [30]
  Zhou Q., Ma J., Dong S., Li X., Cui G. Adv. Mater, 2019, 31, 1902029 doi: 10.1002/adma.201902029 doi: 10.1002/adma.201902029
31. [31]
  Aikens D. A. J. Chem. Edu, 1983, 60, A25 doi: 10.1021/ed060pA25.1 doi: 10.1021/ed060pA25.1
32. [32]
  Fang S., Jackson D., Dreibelbis M. L., Kuech T. F., Hamers R. J. J. Power Sources, 2018, 373, 184 doi: 10.1016/j.jpowsour.2017.09.050 doi: 10.1016/j.jpowsour.2017.09.050
33. [33]
  Zhang J. -N., Li Q., Wang Y., Zheng J., Yu X., Li H. Energy Storage Mater, 2018, 14, 1 doi: 10.1016/j.ensm.2018.02.016 doi: 10.1016/j.ensm.2018.02.016
34. [34]
  Zhang Z., Qin C., Wang K., Han X., Li J., Sui M., Yan P. J. Energy Chem, 2023, 81, 192 doi: 10.1016/j.jechem.2023.01.046 doi: 10.1016/j.jechem.2023.01.046
35. [35]
  Zhou Y. -N., Ma J., Hu E., Yu X., Gu L., Nam K. -W., Chen L., Wang Z., Yang X. -Q. Nat. Commun, 2014, 5, 5381 doi: 10.1038/ncomms6381 doi: 10.1038/ncomms6381
36. [36]
  Chen M., Wang W., Shi Z., Liu Z., Shen C. Appl. Surf. Sci, 2022, 600, 154119 doi: 10.1016/j.apsusc.2022.154119 doi: 10.1016/j.apsusc.2022.154119
37. [37]
  Tallman K. R., Wheeler G. P., Kern C. J., Stavitski E., Tong X., Takeuchi K. J., Marschilok A. C., Bock D. C., Takeuchi E. S. J. Phys. Chem. C, 2021, 125, 58 doi: 10.1021/acs.jpcc.0c08095 doi: 10.1021/acs.jpcc.0c08095
38. [38]
  Yang Y., Wang H., Zhu C., Ma J. Angew. Chem. Int. Ed, 2023, 62, e202300057 doi: 10.1002/anie.202300057 doi: 10.1002/anie.202300057
39. [39]
  Liu J., Wu M., Li X., Wu D., Wang H., Huang J., Ma J. Adv. Energy Mater, 2023, 13, 2300084 doi: 10.1002/aenm.202300084 doi: 10.1002/aenm.202300084
40. [40]
  Frisch M. J., Trucks G. W., Schlegel H. B., Scuseria G. E., Robb M. A., Cheeseman J. R., Scalmani G., Barone V. Petersson G. A., Nakatsuji H., et al. Gaussian 16 Rev. B.01, Wallingford, CT, 2016.
41. [41]
  Neese F. WIREs Comput. Mol. Sci, 2018, 8, e1327 doi: 10.1002/wcms.1327 doi: 10.1002/wcms.1327
42. [42]
  Perdew J. P., Burke K., Ernzerhof M. Phys. Rev. Lett, 1996, 77, 3865 doi: 10.1103/PhysRevLett.77.3865 doi: 10.1103/PhysRevLett.77.3865
43. [43]
  Hutter J., Iannuzzi M., Schiffmann F., VandeVondele J. WIREs Comput. Mol. Sci, 2014, 4, 15 doi: 10.1002/wcms.1159 doi: 10.1002/wcms.1159
44. [44]
  Fan X., Chen L., Borodin O., Ji X., Chen J., Hou S., Deng T., Zheng J., Yang C. Liou S. -C., et al. Nat. Nanotechnol, 2018, 13, 715 doi: 10.1038/s41565-018-0183-2 doi: 10.1038/s41565-018-0183-2
45. [45]
  Li X., Liu J., He J., Wang H., Qi S., Wu D., Huang J., Li F., Hu W., Ma J. Adv. Funct. Mater, 2021, 31, 2104395 doi: 10.1002/adfm.202104395 doi: 10.1002/adfm.202104395
46. [46]
  Kim S. C., Oyakhire S. T., Athanitis C., Wang J., Zhang Z., Zhang W., Boyle D. T. Kim M. S., Yu Z., Gao X., et al. Proc. Natl. Acad. Sci, 2023, 120, e2214357120 doi: 10.1073/pnas.2214357120 doi: 10.1073/pnas.2214357120
47. [47]
  Zhao L., Chen G., Weng Y., Yan T., Shi L., An Z., Zhang D. Chem. Eng. J, 2020, 401, 126138 doi: 10.1016/j.cej.2020.126138 doi: 10.1016/j.cej.2020.126138
48. [48]
  Qiao Y., Zhou Z., Chen Z., Du S., Cheng Q., Zhai H., Fritz N. J., Du Q., Yang Y. Nano Energy, 2018, 45, 68 doi: 10.1016/j.nanoen.2017.12.036 doi: 10.1016/j.nanoen.2017.12.036
49. [49]
  Wu Z., Li R., Zhang S., lv L., Deng T., Zhang H., Zhang R., Liu J., Ding S., Fan L., et al. Chem, 2023, 9, 650 doi: 10.1016/j.chempr.2022.10.027 doi: 10.1016/j.chempr.2022.10.027
50. [50]
  Li X., Zhang K., Mitlin D., Paek E., Wang M., Jiang F., Huang Y., Yang Z., Gong Y., Gu L., et al. Small, 2018, 14, 1802570 doi: 10.1002/smll.201802570 doi: 10.1002/smll.201802570
51. [51]
  Bai Y., Jiang K., Sun S., Wu Q., Lu X., Wan N. Electrochim. Acta, 2014, 134, 347 doi: 10.1016/j.electacta.2014.04.155 doi: 10.1016/j.electacta.2014.04.155
52. [52]
  Yao L., Liang F., Jin J., Chowdari B. V. R., Yang J., Wen Z. Chem. Eng. J, 2020, 389, 124403 doi: 10.1016/j.cej.2020.124403 doi: 10.1016/j.cej.2020.124403
53. [53]
  Gao X. -W., Deng Y. -F., Wexler D., Chen G. -H., Chou S. -L., Liu H. -K., Shi Z. -C., Wang J. -Z. J. Mater. Chem. A, 2015, 3, 404 doi: 10.1039/C4TA04018J doi: 10.1039/C4TA04018J
54. [54]
  Ding J. -F., Xu R., Yao N., Chen X., Xiao Y., Yao Y. -X., Yan C., Xie J., Huang J. -Q. Angew. Chem. Int. Ed, 2021, 60, 11442 doi: 10.1002/anie.202101627 doi: 10.1002/anie.202101627
55. [55]
  Wang Z., Zhu C., Liu J., Hu X., Yang Y., Qi S., Wang H., Wu D., Huang J., He P., et al. Adv. Funct. Mater, 2023, 33, 2212150 doi: 10.1002/adfm.202212150 doi: 10.1002/adfm.202212150
56. [56]
  Huang J., Liu J., He J., Wu M., Qi S., Wang H., Li F., Ma J. Angew. Chem. Int. Ed, 2021, 60, 20717 doi: 10.1002/anie.202107957 doi: 10.1002/anie.202107957
57. [57]
  Jiang G., Liu J., Wang Z., Ma J. Adv. Funct. Mater, 2023, 2300629. doi: 10.1002/adfm.202300629 doi: 10.1002/adfm.202300629
58. [58]
  Rath P. C., Wang Y. -W., Patra J., Umesh B., Yeh T. -J., Okada S., Li J., Chang J. -K. Chem. Eng. J, 2021, 415, 128904 doi: 10.1016/j.cej.2021.128904 doi: 10.1016/j.cej.2021.128904
59. [59]
  Zheng X., Liao Y., Zhang Z., Zhu J., Ren F., He H., Xiang Y., Zheng Y., Yang Y. J. Energy Chem, 2020, 42, 62 doi: 10.1016/j.jechem.2019.05.023 doi: 10.1016/j.jechem.2019.05.023
60. [60]
  Etacheri V., Haik O., Goffer Y., Roberts G. A., Stefan I. C., Fasching R., Aurbach D. Langmuir, 2012, 28, 965 doi: 10.1021/la203712s doi: 10.1021/la203712s
61. [61]
  Xia J., Petibon R., Xiao A., Lamanna W. M., Dahn J. R. J. Electrochem. Soc, 2016, 163, A1637 doi: 10.1149/2.0831608jes doi: 10.1149/2.0831608jes
62. [62]
  Fan X., Wang C. Chem. Soc. Rev, 2021, 50, 10486 doi: 10.1039/D1CS00450F doi: 10.1039/D1CS00450F
63. [63]
  Xu N., Shi J., Liu G., Yang X., Zheng J., Zhang Z., Yang Y. J. Power Sources Adv, 2021, 7, 100043 doi: 10.1016/j.powera.2020.100043 doi: 10.1016/j.powera.2020.100043
64. [64]
  Wang T., Rao L., Jiao X., Choi J., Yap J., Kim J. -H. ACS Appl. Energy Mater, 2022, 5, 7346 doi: 10.1021/acsaem.2c00861 doi: 10.1021/acsaem.2c00861
65. [65]
  Song Y., Mao Q., Li Q., Huang Z., Wan Y., Hong B., Zhong Q. ACS Appl. Energy Mater, 2023, 6, 4271 doi: 10.1021/acsaem.3c00196 doi: 10.1021/acsaem.3c00196
66. [66]
  Wu F., Schür A. R. Kim G. -T., Dong X., Kuenzel M., Diemant T., D'Orsi G., Simonetti E., De Francesco M., Bellusci M., et al. Energy Storage Mater, 2021, 42, 826 doi: 10.1016/j.ensm.2021.08.030 doi: 10.1016/j.ensm.2021.08.030
67. [67]
  Xu M., Liu Y., Li B., Li W., Li X., Hu S. Electrochem. Commun, 2012, 18, 123 doi: 10.1016/j.elecom.2012.02.037 doi: 10.1016/j.elecom.2012.02.037
68. [68]
  Pham T. D., Faheem A. B., Kim J., Kwak K., Lee K. -K. Electrochim. Acta, 2023, 142496. doi: 10.1016/j.electacta.2023.142496 doi: 10.1016/j.electacta.2023.142496
69. [69]
  Winter E., Briccola M., Schmidt T. J., Trabesinger S. Appl. Res, 2022, e202200096. doi: 10.1002/appl.202200096 doi: 10.1002/appl.202200096
70. [70]
  Ma Q., Zhang X., Wang A., Xia Y., Liu X., Luo J. Adv. Funct. Mater, 2020, 30, 2002824 doi: 10.1002/adfm.202002824 doi: 10.1002/adfm.202002824
71. [71]
  Yang Y. -P., Jiang J. -C., Huang A. -C., Tang Y., Liu Y. -C., Xie L. -J., Zhang C. -Z., Wu Z. -H., Xing Z. -X., Yu F. Process Saf. Environ. Prot, 2022, 160, 80 doi: 10.1016/j.psep.2022.02.018 doi: 10.1016/j.psep.2022.02.018
72. [72]
  Zhang C. -M., Li F., Zhu X. -Q., Yu J. -G. Molecules, 2022, 27, 3107; doi: 103390/molecules27103107 doi: 10.3390/molecules.27103107
73. [73]
  Li Y., Li W., Shimizu R., Cheng D., Nguyen H., Paulsen J., Kumakura S., Zhang M., Meng Y. S. Adv. Energy Mater, 2022, 12, 2103033 doi: 10.1002/aenm.202103033 doi: 10.1002/aenm.202103033
74. [74]
  Martinez A. C., Rigaud S., Grugeon S., Tran-Van P., Armand M., Cailleu D., Pilard S., Laruelle S. Electrochim. Acta, 2022, 426, 140765 doi: 10.1016/j.electacta.2022.140765 doi: 10.1016/j.electacta.2022.140765
75. [75]
  Fu A., Lin J., Zhang Z., Xu C., Zou Y., Liu C., Yan P., Wu D. -Y., Yang Y., Zheng J. ACS Energy Lett, 2022, 7, 1364 doi: 10.1021/acsenergylett.2c00316 doi: 10.1021/acsenergylett.2c00316
76. [76]
  Xu M., Zhou L., Dong Y., Chen Y., Garsuch A., Lucht B. L. J. Electrochem. Soc, 2013, 160, A2005 doi: 10.1149/2.053311jes doi: 10.1149/2.053311jes
77. [77]
  Xu M., Zhou L., Dong Y., Chen Y., Demeaux J., MacIntosh A. D., Garsuch A., Lucht B. L. Energy Environ. Sci, 2016, 9, 1308 doi: 10.1039/C5EE03360H doi: 10.1039/C5EE03360H
78. [78]
  Yang X., Lin M., Zheng G., Wu J., Wang X., Ren F., Zhang W., Liao Y., Zhao W., Zhang Z., et al. Adv. Funct. Mater, 2020, 30, 2004664 doi: 10.1002/adfm.202004664 doi: 10.1002/adfm.202004664
79. [79]
  Liu F., Zhang Z., Yu Z., Fan X., Yi M., Bai M., Song Y., Mao Q., Hong B., Zhang Z., et al. Chem. Eng. J, 2022, 434, 134745 doi: 10.1016/j.cej.2022.134745 doi: 10.1016/j.cej.2022.134745
80. [80]
  Zhang Q. -K., Zhang X. -Q., Wan J., Yao N., Song T. -L., Xie J., Hou L. -P., Zhou M. -Y., Chen X. Li B. -Q., et al. Nat. Energy, 2023, 8, 725 doi: 10.1038/s41560-023-01275-y doi: 10.1038/s41560-023-01275-y
1. [1]
  Da Wang , Xiaobin Yin , Jianfang Wu , Yaqiao Luo , Siqi Shi . All-Solid-State Lithium Cathode/Electrolyte Interfacial Resistance: From Space-Charge Layer Model to Characterization and Simulation. Acta Physico-Chimica Sinica, 2024, 40(7): 2307029-0. doi: 10.3866/PKU.WHXB202307029
2. [2]
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3. [3]
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4. [4]
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5. [5]
  Jiahe LIU , Gan TANG , Kai CHEN , Mingda ZHANG . Effect of low-temperature electrolyte additives on low-temperature performance of lithium cobaltate batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 719-728. doi: 10.11862/CJIC.20250023
6. [6]
  Zhaoxuan ZHU , Lixin WANG , Xiaoning TANG , Long LI , Yan SHI , Jiaojing SHAO . Application of poly(vinyl alcohol) conductive hydrogel electrolytes in zinc ion batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 893-902. doi: 10.11862/CJIC.20240368
7. [7]
  Ke Qiu , Fengmei Wang , Mochou Liao , Kerun Zhu , Jiawei Chen , Wei Zhang , Yongyao Xia , Xiaoli Dong , Fei Wang . A Fumed SiO₂-based Composite Hydrogel Polymer Electrolyte for Near-Neutral Zinc-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(3): 2304036-0. doi: 10.3866/PKU.WHXB202304036
8. [8]
  Zhi Dou , Huiyu Duan , Yixi Lin , Yinghui Xia , Mingbo Zheng , Zhenming Xu . High-Throughput Screening Lithium Alloy Phases and Investigation of Ion Transport for Solid Electrolyte Interphase Layer. Acta Physico-Chimica Sinica, 2024, 40(3): 2305039-0. doi: 10.3866/PKU.WHXB202305039
9. [9]
  Hanmei Lü , Xin Chen , Qifu Sun , Ning Zhao , Xiangxin Guo . Uniform Garnet Nanoparticle Dispersion in Composite Polymer Electrolytes. Acta Physico-Chimica Sinica, 2024, 40(3): 2305016-0. doi: 10.3866/PKU.WHXB202305016
10. [10]
  Changsheng An , Tao Liu . Decoding SEI chemistry at the lithium-metal potential. Acta Physico-Chimica Sinica, 2025, 41(9): 100101-0. doi: 10.1016/j.actphy.2025.100101
11. [11]
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12. [12]
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16. [16]
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17. [17]
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19. [19]
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沈阳化工大学材料科学与工程学院沈阳 110142