调控ZnIn2S4/Bi2O3 S型异质结的电子结构和润湿性增强光催化析氢

引用本文: 肖林锋, 任婉璐, 沈诗诗, 陈梦姗, 廖润华, 周英棠, 李喜宝. 调控ZnIn₂S₄/Bi₂O₃ S型异质结的电子结构和润湿性增强光催化析氢[J]. 物理化学学报, 2024, 40(8): 230803. doi: 10.3866/PKU.WHXB202308036 shu

Citation: Linfeng Xiao, Wanlu Ren, Shishi Shen, Mengshan Chen, Runhua Liao, Yingtang Zhou, Xibao Li. Enhancing Photocatalytic Hydrogen Evolution through Electronic Structure and Wettability Adjustment of ZnIn₂S₄/Bi₂O₃ S-Scheme Heterojunction[J]. Acta Physico-Chimica Sinica, 2024, 40(8): 230803. doi: 10.3866/PKU.WHXB202308036 shu

调控ZnIn₂S₄/Bi₂O₃ S型异质结的电子结构和润湿性增强光催化析氢

肖林锋 ^{1, †,} ,
任婉璐 ^{1, †,} ,
沈诗诗 ^3, ,
陈梦姗 ^2, ,
廖润华 ^{1,
,} ,
周英棠 ^{2,
,} ,
李喜宝 ^{3,
,}

1.
景德镇陶瓷大学材料科学与工程学院, 江西景德镇 333403
2.
浙江海洋大学海洋科学与技术学院, 浙江省石油化工环境污染控制重点实验室, 国家海洋设施养殖工程技术研究中心, 浙江舟山 316022
3.
南昌航空大学材料科学与工程学院, 江西南昌 330063

通讯作者: 廖润华, 001072@jcu.edu.cn; 周英棠, zhouyingtang@zjou.edu.cn; 李喜宝, lixibao@nchu.edu.cn

基金项目:
浙江省重点研发项目 2023 C01191

国家自然科学基金项目 22262024

国家自然科学基金项目 51962023

国家自然科学基金项目 51468024

江西省重点学科学术技术带头人项目 20232BCJ22008

江西自然科学基金 20232ACB204007

江西自然科学基金 20192GYZD008-33

景德镇市科技局项目 20192GYZD008-33
^†These authors contributed equally to this work.

摘要: 通过光催化水裂解制氢来生产可再生燃料具有巨大的潜力。然而，缓慢的析氢动力学和较差的水吸附对光催化剂构成了重大挑战。在这项研究中，我们开发了一种简单的水热法，用于从金属有机框架(MOF)中合成Bi₂O₃ (BO)，并将其负载到花状ZnIn₂S₄ (ZIS)上。该方法显著增强了水吸附和表面催化反应，从而显著提高了光催化活性。以三乙醇胺(TEOA)作为牺牲剂，在BO上负载15% (质量分数) ZIS时，析氢速率达到了1610 μmol∙h⁻¹∙g⁻¹，是纯BO的6.34倍。此外，利用密度泛函理论(DFT)和从头算分子动力学(AIMD)计算，我们确定了ZIS/BO S型异质结界面上的反应，包括水吸附和催化反应的活性位点。这项工作将为开发具有特定电子性能和润湿性的高性能复合光催化材料提供有价值的见解。

关键词:

S型
/ 析氢
/ 润湿性
/ 光催化
/ 电子结构

English

Enhancing Photocatalytic Hydrogen Evolution through Electronic Structure and Wettability Adjustment of ZnIn₂S₄/Bi₂O₃ S-Scheme Heterojunction

1.
School of Materials Science and Engineering, Jingdezhen Ceramic University, Jingdezhen 333403, Jiangxi Province, China
2.
Zhejiang Key Laboratory of Petrochemical Environmental Pollution Control, National Engineering Research Center for Marine Aquaculture, Marine Science and Technology College, Zhejiang Ocean University, Zhoushan 316022, Zhejiang Province, China
3.
School of Materials Science and Engineering, Nanchang Hangkong University, Nanchang 330063, Jiangxi Province, China

Corresponding author: Email: 001072@jcu.edu.cn (R.L.); Email: zhouyingtang@zjou.edu.cn (Y.Z.); Email: lixibao@nchu.edu.cn (X.L.)

Received Date: 21 August 2023
Accepted Date: 28 September 2023
Revised Date: 28 September 2023
Available Online: 15 August 2024
Fund Project:
the Zhejiang Province Key Research and Development Project

National Natural Science Foundation of China

National Natural Science Foundation of China

National Natural Science Foundation of China

Jiangxi Academic and Technical Leader of Major Disciplines

Natural Science Foundation of Jiangxi Province

Natural Science Foundation of Jiangxi Province

Jingdezhen Science and Technology Bureau Project

Abstract: The production of renewable fuels through water splitting via photocatalytic hydrogen production holds significant promise. Nonetheless, the sluggish kinetics of hydrogen evolution and the inadequate water adsorption on photocatalysts present notable challenges. In this study, we have devised a straightforward hydrothermal method to synthesize Bi₂O₃ (BO) derived from metal-organic frameworks (MOFs), loaded with flower-like ZnIn₂S₄ (ZIS). This approach substantially enhances water adsorption and surface catalytic reactions, resulting in a remarkable enhancement of photocatalytic activity. By employing triethanolamine (TEOA) as a sacrificial agent, the hydrogen evolution rate achieved with 15% (mass fraction) ZIS loading on BO reached an impressive value of 1610 μmol∙h⁻¹∙g⁻¹, marking a 6.34-fold increase compared to that observed for bare BO. Furthermore, through density functional theory (DFT) and ab initio molecular dynamics (AIMD) calculations, we have identified the reactions occurring at the ZIS/BO S-scheme heterojunction interface, including the identification of active sites for water adsorption and catalytic reactions. This study provides valuable insights into the development of high-performance composite photocatalytic materials with tailored electronic properties and wettability.

Key words:

1. [1]
  Zhang, L.; Zhang, J.; Yu, H.; Yu, J. Adv. Mater. 2022, 34 (11), 2107668. doi: 10.1002/adma.202107668
2. [2]
  Hu, Y.; Li, X.; Wang, W.; Deng, F.; Han, L.; Gao, X.; Feng, Z.; Chen, Z.; Huang, J.; Zeng, F.; et al. Chin. J. Struct. Chem. 2022, 41 (4), 69. doi: 10.14102/j.cnki.0254-5861
3. [3]
  Yi, J.; Zhou, Z.; Xia, Y.; Zhou, G.; Zhang, G.; Li, L.; Wang, X.; Zhu, X.; Wang, X.; Pang, H. Chin. Chem. Lett. 2023, 34 (11), 108328. doi: 10.1016/j.cclet.2023.108328
4. [4]
  Zhang, P.; Li, Y.; Li, X. Chin. J. Catal. 2023, 44, 4. doi: 10.1016/S1872-2067(22)64185-8
5. [5]
  Tang, S.; Xia, Y.; Fan, J.; Cheng, B.; Yu, J.; Ho, W. Chin. J. Catal. 2021, 42 (5), 743. doi: 10.1016/S1872-2067(20)63695-6
6. [6]
  Wang, J.; Sun, M.; Liu, C.; Ye, Y.; Chen, M.; Zhao, Z.; Zhang, Y.; Wu, X.; Wang, K.; Zhou, Y. Adv. Mater. 2023, 35, 2306103. doi: 10.1002/adma.202306103
7. [7]
  Zhang, P.; Tian, Z.; Hung, C.; Liu, Y.; Jia, B.; Lan, K.; Kong, B.; Huang, F.; Mai, L.; Zhao, D. Cell Rep. Phys. Sci. 2020, 1 (7), 100081. doi: 10.1016/j.xcrp.2020.100081
8. [8]
  Li, Y.; Kidkhunthod, P.; Zhou, Y.; Wang, X.; Lee, J. Adv. Func. Mater. 2022, 32 (41), 2205985. doi: 10.1002/adfm.202205985
9. [9]
  Sun, L.; Han, L.; Huang, J.; Luo, X.; Li, X. Int. J. Hydrog. Energy 2022, 47 (40), 17583. doi: 10.1016/j.ijhydene.2022.03.259
10. [10]
  Lei, Y.; Huang, J.; Li, X.; Lv, C.; Hou, C.; Liu, J. Chin. J. Catal. 2022, 43 (8), 2249. doi: 10.1016/S1872-2067(22)64109-3
11. [11]
  Huang, B.; Fu, X.; Wang, K.; Wang, L.; Zhang, H.; Liu, Z.; Liu, B.; Li, J. Adv. Powder. Mater. 2023, doi: 10.1016/j.apmate.2023.100140
12. [12]
  Li, X.; Hu, Y.; Dong, F.; Huang, J.; Han, L.; Deng, F.; Luo, Y.; Xie, Y.; He, C.; Feng, Z.; Chen, Z.; Zhu, Y. Appl. Catal. B 2023, 325, 122341. doi: 10.1016/j.apcatb.2022.122341
13. [13]
  Wang, W.; Li, X.; Deng, F.; Liu, J.; Gao, X.; Huang, J.; Xu, J.; Feng, Z.; Chen, Z.; Han, L. Chin. Chem. Lett. 2022, 33 (12), 5200. doi: 10.1016/j.cclet.2022.01.058
14. [14]
  Zhang, H.; Aierek, A.; Zhou, Y.; Ni, Z.; Feng, L.; Chen, A.; Wågberg, T.; Hu, G. Carbon Energy 2023, 5 (1), e217. doi: 10.1002/cey2.217
15. [15]
  Guo, Y.; Yan, B.; Deng, F.; Shao, P.; Zou, J.; Luo, X.; Zhang, S.; Li, X. Chin. Chem. Lett. 2023, 34 (2), 107468. doi: 10.1016/j.cclet.2022.04.066
16. [16]
  Li, S.; Cai, M.; Liu, Y.; Wang, C.; Lv, K.; Chen, X. Chin. J. Catal. 2022, 43 (10), 2652. doi: 10.1016/S1872-2067(22)64106-8
17. [17]
  Shan, A.; Teng, X.; Zhang, Y.; Zhang, P.; Xu, Y.; Liu, C.; Li, H.; Ye, H.; Wang, R. Nano Energy 2022, 94, 106913. doi: 10.1016/j.nanoen.2021.106913
18. [18]
  王文亮, 张灏纯, 陈义钢, 史海峰. 物理化学学报, 2022, 38 (7), 2201008. doi: 10.3866/PKU.WHXB202201008Wang, W.; Zhang, H.; Chen, Y.; Shi, H. Acta Phys. -Chim. Sin. 2022, 38 (7), 2201008. doi: 10.3866/PKU.WHXB202201008
19. [19]
  Wang, K.; Qin, H.; Li, J.; Cheng, Q.; Zhu, Y.; Hu, H.; Peng, J.; Chen, S.; Wang, G.; Chou, S.; et al. Appl. Catal. B 2023, 332, 122763. doi: 10.1016/j.apcatb.2023.122763
20. [20]
  韩高伟, 徐飞燕, 程蓓, 李佑稷, 余家国, 张留洋. 物理化学学报, 2022, 38 (7), 2112037. doi: 10.3866/PKU.WHXB202112037Han, G.; Xu, F.; Cheng, B.; Li, Y.; Yu, J.; Zhang, L. Acta Phys. -Chim. Sin. 2022, 38 (7), 2112037. doi: 10.3866/PKU.WHXB202112037
21. [21]
  何科林, 沈荣晨, 郝磊, 李佑稷, 张鹏, 江吉周, 李鑫. 物理化学学报, 2022, 38 (11), 2201021. doi: 10.3866/PKU.WHXB202201021He, K.; Shen, R.; Hao, L.; Li, Y.; Zhang, P.; Jiang, J.; Li, X. Acta Phys. -Chim. Sin. 2022, 38 (11), 2201021. doi: 10.3866/PKU.WHXB202201021
22. [22]
  李喜宝, 刘积有, 黄军同, 何朝政, 冯志军, 陈智, 万里鹰, 邓芳. 物理化学学报, 2021, 37 (6), 22010030. doi: 10.3866/PKU.WHXB202010030Li, X.; Liu, J.; Huang, J.; He, C.; Feng, Z.; Chen, Z.; Wan, L.; Deng, F. Acta Phys. -Chim. Sin. 2021, 37 (6), 22010030. doi: 10.3866/PKU.WHXB202010030
23. [23]
  Zhu, Q.; Hailili, R.; Xin, Y.; Zhou, Y.; Hu, Y.; Pang, X.; Zhang, K.; Robertson, P.; Bahnemann, D.; Wang, C. Appl. Catal. B 2022, 319, 121888. doi: 10.1016/j.apcatb.2022.121888
24. [24]
  Wang, Y.; Liu, Q.; Wong, N. -H.; Sunarso, J.; Huang, J.; Dai, G.; Hou, X.; Li, X. Ceram. Int. 2022, 48 (2), 2459. doi: 10.1016/j.ceramint.2021.10.027
25. [25]
  Wang, H.; Liu, J.; Xiao, X.; Meng, H.; Wu, J.; Guo, C.; Zheng, M.; Wang, X.; Guo, S.; Jiang, B. Chin. Chem. Lett. 2023, 34 (1), 107125. doi: 10.1016/j.cclet.2022.01.018
26. [26]
  Yang, H.; Zhang, J.; Dai, K. Chin. J. Catal. 2022, 43 (2), 255. doi: 10.1016/S1872-2067(20)63784-6
27. [27]
  Zhang, X.; Wang, Y.; Liu, B.; Sang, Y.; Liu, H. Appl. Catal. B 2017, 202, 620. doi: 10.1016/j.apcatb.2016.09.068
28. [28]
  Li, X.; Kang, B.; Dong, F.; Deng, F.; Han, L.; Gao, X.; Xu, J.; Hou, X.; Feng, Z.; Chen, Z.; et al. Appl. Surf. Sci. 2022, 593, 153422. doi: 10.1016/j.apsusc.2022.153422
29. [29]
  Dai, M.; He, Z.; Cao, W.; Zhang, J.; Chen, W.; Jin, Q.; Que, W.; Wang, S. Sep. Purif. Technol. 2023, 309, 123004. doi: 10.1016/j.seppur.2022.123004
30. [30]
  Hua, J.; Wang, Z.; Zhang, J.; Dai, K.; Shao, C.; Fan, K. J. Mater. Sci. Technol. 2023, 156, 64. doi: 10.1016/j.jmst.2023.03.003
31. [31]
  He, H.; Wang, Z.; Dai, K.; Li, S.; Zhang, J. Chin. J. Catal. 2023, 48, 267. doi: 10.1016/S1872-2067(23)64420-1
32. [32]
  Liu, L.; Wang, Z.; Zhang, J.; Ruzimuradov, O.; Dai, K.; Low, J. Adv. Mater. 2023, 35 (26), 2300643. doi: 10.1002/adma.202300643
33. [33]
  Zhao, Z.; Dai, K.; Zhang, J.; Dawson, G. Adv. Sustain. Syst. 2023, 7 (1), 2100498. doi: 10.1002/adsu.202100498
34. [34]
  Zhao, Z.; Wang, Z.; Zhang, J.; Shao, C.; Dai, K.; Fan, K.; Liang, C. Adv. Func. Mater. 2023, 33 (23), 2214470. doi: 10.1002/adfm.202214470
35. [35]
  王中辽, 汪静, 张金锋, 代凯. 物理化学学报, 2023, 39 (6), 2209037. doi: 10.3866/PKU.WHXB202209037Wang, Z.; Wang, J.; Zhang, J.; Dai, K. Acta Phys. -Chim. Sin. 2023, 39 (6), 2209037. doi: 10.3866/PKU.WHXB202209037
36. [36]
  Wang, Z.; Liu, R.; Zhang, J; Dai, K. Chin. J. Struc. Chem. 2022, 41 (06), 15. doi: 10.14102/j.cnki.0254-5861.2022-0108
37. [37]
  Liu, Q.; He, X.; Peng, J.; Yu, X.; Tang, H.; Zhang, J. Chin. J. Catal. 2021, 42 (9), 1478. doi: 10.1016/s1872-2067(20)63753-6
38. [38]
  Cui, Q.; Gu, X.; Zhao, Y.; Qi, K.; Yan, Y. J. Taiwan Inst. Chem. Eng. 2023, 142, 104679. doi: 10.1016/j.jtice.2023.104679
39. [39]
  Li, J.; Li, M.; Jin, Z. J. Colloid Interface Sci. 2021, 592, 237. doi: 10.1016/j.jcis.2021.02.053
40. [40]
  Cheng, C.; Zhang, J.; Zhu, B.; Liang, G.; Zhang, L.; Yu, J. Angew. Chem. Int. Ed. 2023, 135 (8), e202218688. doi: 10.1002/ange.202218688
41. [41]
  Ruan, X.; Huang, C.; Cheng, H.; Zhang, Z.; Cui, Y.; Li, Z.; Xie, T.; Ba, K.; Zhang, H.; Zhang, L.; et al. Adv. Mater. 2023, 35(6), 2209141. doi: 10.1002/adma.202209141
42. [42]
  Cheng, C.; He, B.; Fan, J.; Cheng, B.; Cao, S.; Yu, J. Adv. Mater. 2021, 33 (22), 2100317. doi: 10.1002/adma.202100317
43. [43]
  Wang, Z.; Wang, D.; Deng, F.; Liu, X.; Li, X.; Luo, X.; Peng, Y.; Zhang, J.; Zou, J.; Ding, L.; et al. Chem. Eng. J. 2023, 463, 142313. doi: 10.1016/j.cej.2023.142313
44. [44]
  Bai, J.; Shen, R.; Jiang, Z.; Zhang, P.; Li, Y.; Li, X. Chin. J. Catal. 2022, 43 (2), 359. doi: 10.1016/S1872-2067(21)63883-4
45. [45]
  Peng, Y.; Guo, X.; Xu, S.; Guo, Y.; Zhang, D.; Wang, M.; Wei, G.; Yang, X.; Li, Z.; Zhang, Y.; et al. J. Energy Chem. 2022, 75, 276. doi: 10.1016/j.jechem.2022.06.027
46. [46]
  黄悦, 梅飞飞, 张金锋, 代凯, Dawson, G. 物理化学学报, 2022, 38 (7), 2108028. doi: 10.3866/PKU.WHXB202108028Huang, Y.; Mei, F.; Zhang, J.; Dai, K.; Dawson, G. Acta Phys. -Chim. Sin. 2022, 38 (7), 2108028. doi: 10.3866/PKU.WHXB202108028
47. [47]
  Zheng, J.; Zhou, H.; Zou, Y.; Wang, R.; Lyu, Y.; Jiang, S.; Wang, S. Energy Environ. Sci. 2019, 12 (8), 2345. doi: 10.1039/C9EE00524B
48. [48]
  Zhang, C.; Guo, Z.; Tian, Y.; Yu, C.; Liu, K.; Jiang, L. Nano Res. Energy 2023, 2 (2), e9120063. doi: 10.26599/NRE.2023.9120063
49. [49]
  Zhang, H.; Zhou, Y.; Xu, M.; Chen, A.; Ni, Z.; Akdim, O.; Wågberg, T.; Huang, X.; Hu, G. ACS Nano 2023, 17(1), 636. doi: 10.1021/acsnano.2c09880
50. [50]
  Lin, K.; Wang, Z.; Hu, Z.; Luo, P.; Yang, X.; Zhang, X.; Rafiq, M.; Huang, F.; Cao, Y. J. Mater. Chem. A 2019, 7 (32), 19087. doi: 10.1039/C9TA06219J
51. [51]
  Tian, Y.; Cui, Q.; Xu, L.; Jiao, A.; Li, S.; Wang, X.; Chen, M. J. Mater. Sci. Technol. 2021, 94, 10. doi: 10.1016/j.jmst.2021.02.062
52. [52]
  Chen, J.; Abazari, R.; Adegoke, K.; Maxakato, N.; Bello, O.; Tahir, M.; Tasleem, S.; Sanati, S.; Kirillov, A.; Zhou, Y. Coord. Chem. Rev. 2022, 469, 214664. doi: 10.1016/j.ccr.2022.214664
53. [53]
  Zhao, X.; Chen, J.; Zhao, C.; Liu, Y.; Liang, Q.; Zhou, M.; Li, Z.; Zhou, Y. Appl. Surf. Sci. 2021, 570, 151183. doi: 10.1016/j.apsusc.2021.151183
54. [54]
  Zhu, Q.; Dar, A.; Zhou, Y.; Zhang, K.; Qin, J.; Pan, B.; Lin, J.; Patrocinio, A.; Wang, C. ACS EST Eng. 2022, 2 (8), 1365. doi: 10.1021/acsestengg.1c00479
55. [55]
  Zhao, X.; Chen, J.; Bi, Z.; Chen, S.; Feng, L.; Zhou, X.; Zhang, H.; Zhou, Y.; Wågberg, T.; Hu, G. Adv. Sci. 2023, 10 (8), 2205889. doi: 10.1002/advs.202205889
56. [56]
  Han, L.; Jing, F.; Zhang, J.; Luo, X.; Zhong, Y.; Wang, K.; Zang, S.; Teng, D.; Liu, Y.; Chen, J.; et al. Appl. Catal. B 2021, 282, 119602. doi: 10.1016/j.apcatb.2020.119602
57. [57]
  Li, Q.; Gao, Y.; Zhang, M.; Gao, H.; Chen, J.; Jia, H. Appl. Catal. B 2022, 303, 120905. doi: 10.1016/j.apcatb.2021.120905
58. [58]
  Tang, M.; Li, X.; Deng, F.; Han, L.; Xie, Y.; Huang, J.; Chen, Z.; Feng, Z.; Zhou, Y. Catalysts 2023, 13 (3), 634. doi: 10.3390/catal13030634
59. [59]
  Zhang, J.; Gu, X.; Zhao, Y.; Zhang, K.; Yan, Y.; Qi, K. Nanomaterials 2023, 13 (2), 305. doi: 10.3390/nano13020305
60. [60]
  Guan, Y.; Liu, Y.; Lv, Q.; Wu, J. J. Hazard. Mater. 2021, 418, 126280. doi: 10.1016/j.jhazmat.2021.126280
61. [61]
  Li, L.; Yang, Y.; Li, G.; Zhang, L. Small 2006, 2 (4), 548. doi: 10.1002/smll.200500382
62. [62]
  Meng, Z.; Qiu, Z.; Shi, Y.; Wang, S.; Zhang, G.; Pi, Y.; Pang, H. eScience 2023, 3 (2), 100092. doi: 10.1016/j.esci.2023.100092
63. [63]
  Dong, S.; Xia, L.; Chen, X.; Cui, L.; Zhu, W.; Lu, Z.; Sun, J.; Fan, M. Compos. Part B Eng. 2021, 215, 108765. doi: 10.1016/j.compositesb.2021.108765
64. [64]
  Peng, Z.; Jiang, Y.; Xiao, Y.; Xu, H.; Zhang, W.; Ni, L. Appl. Surf. Sci. 2019, 487, 1084. doi: 10.1016/j.apsusc.2019.05.163
65. [65]
  Shen, J.; Zai, J.; Yuan, Y.; Qian, X. Int. J. Hydrog. Energy 2012, 37 (12), 16986. doi: 10.1016/j.ijhydene.2012.08.038
66. [66]
  Bai, J.; Chen, W.; Shen, R.; Jiang, Z.; Zhang, P.; Liu, W.; Li, X. J. Mater. Sci. Technol. 2022, 112, 85. doi: 10.1016/j.jmst.2021.11.003
67. [67]
  Zhao, X.; Chen, M.; Zhou, Y.; Zhang, H.; Hu, G. J. Mater. Chem. A 2023, 11 (11), 5830. doi: 10.1039/D2TA09698F
68. [68]
  Lei, Z.; You, W.; Liu, M.; Zhou, G.; Takata, T.; Hara, M.; Domen, K. Chem. Commun. 2003, 17, 2142. doi: 10.1039/B306813G
69. [69]
  Xiao, Y.; Jiang, Y.; Liu, X.; Zhang, W.; Zhu, Z.; Gao, Y.; Xu, H.; Zhang, J.; Liu, Z.; Ni, L. J. Mater. Sci. 2020, 55, 14211. doi: 10.1007/s10853-020-05004-8
70. [70]
  Dong, S.; Zhao, Y.; Yang, J.; Liu, X.; Li, W.; Zhang, L.; Wu, Y.; Sun, J.; Feng, J.; Zhu, Y. Appl. Catal. B 2021, 291, 120127. doi: 10.1016/j.apcatb.2021.120127
71. [71]
  Lei, Z.; Cao, X.; Fan, J.; Hu, X.; Hu, J.; Li, N.; Sun, T.; Liu, E. Chem. Eng. J. 2023, 457, 141249. doi: 10.1016/j.cej.2022.14124
72. [72]
  Dong, S.; Cui, L.; Tian, Y.; Xia, L.; Wu, Y.; Yu, J.; Bagley, D-M.; Sun, J.; Fan, M. J. Hazard. Mater. 2020, 399, 123017. doi: 10.1016/j.jhazmat.2020.123017
73. [73]
  昝忠奇, 李喜宝, 高晓明, 黄军同, 罗一丹, 韩露. 物理化学学报, 2023, 39 (6), 2209016. doi: 10.3866/PKU.WHXB202209016Zan, Z.; Li, X.; Gao, X.; Huang, J.; Luo, Y.; Han, L. Acta Phys. -Chim. Sin. 2023, 39 (6), 2209016. doi: 10.3866/PKU.WHXB202209016
74. [74]
  Shen, S.; Li, X.; Zhou, Y.; Han, L.; Xie, Y.; Deng, F.; Huang, J.; Chen, Z.; Feng, Z.; Xu, J.; et al. J. Mater. Sci. Technol. 2023, 155, 148. doi: 10.1016/j.jmst.2023.03.006

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沈阳化工大学材料科学与工程学院沈阳 110142

调控ZnIn₂S₄/Bi₂O₃ S型异质结的电子结构和润湿性增强光催化析氢

通讯作者: 廖润华, 001072@jcu.edu.cn; 周英棠, zhouyingtang@zjou.edu.cn; 李喜宝, lixibao@nchu.edu.cn

English

Enhancing Photocatalytic Hydrogen Evolution through Electronic Structure and Wettability Adjustment of ZnIn₂S₄/Bi₂O₃ S-Scheme Heterojunction

Corresponding author: Email: 001072@jcu.edu.cn (R.L.); Email: zhouyingtang@zjou.edu.cn (Y.Z.); Email: lixibao@nchu.edu.cn (X.L.)

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通讯作者: 陈斌, bchen63@163.com

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