Citation: Yan Kong, Wei Wei, Lekai Xu, Chen Chen. Electrochemical Synthesis of Organonitrogen Compounds from N-integrated CO₂ Reduction Reaction[J]. Acta Physico-Chimica Sinica, ;2024, 40(8): 230704. doi: 10.3866/PKU.WHXB202307049 shu

Electrochemical Synthesis of Organonitrogen Compounds from N-integrated CO₂ Reduction Reaction

Yan Kong ^† ,
Wei Wei ^† ,
Lekai Xu ,
Chen Chen ^,

Engineering Research Center of Advanced Rare Earth Materials, Department of Chemistry, Tsinghua University, Beijing 100084, China

Corresponding author: Chen Chen, cchen@mail.tsinghua.edu.cn

^†

Received Date: 26 July 2023
Revised Date: 9 September 2023
Accepted Date: 11 September 2023
Available Online: 19 September 2023
Fund Project: the National Key R&D Program of China 2021YFF0500503National Natural Science Foundation of China 21925202National Natural Science Foundation of China 21872076

The social development model relying on coal, oil, natural gas, and other fossil fuels as the primary energy sources has not only hastened the depletion of non-renewable resources but also led to a continuous increase in atmospheric CO₂ concentration. As human society's understanding of energy structures deepens and environmental consciousness grows, the pursuit of effective clean CO₂ capture and catalytic conversion technologies has become a research priority. This is essential for promoting adjustments to the energy mix and achieving global carbon neutrality through artificial carbon cycling. Among the various CO₂ capture and catalytic conversion technologies, electrochemical catalytic CO₂ reduction (CO₂RR) at ambient temperature and pressure holds promise for advancing artificial carbon cycling, carbon storage, and mitigating environmental degradation. This technology can be driven by intermittent renewable energy sources such as solar energy, wind energy, tidal power, geothermal energy, etc. Furthermore, using water as a clean proton source, a wide array of chemicals can be synthesized. While recent studies have made significant progress in CO₂RR within aqueous solutions, there remains untapped potential in generating other important small organic molecules like urea, amides, amines, derivatives, and even amino acids. These compounds are of great interest due to their widespread applications in fertilizers, chemical synthesis, pharmaceuticals, and the aerospace industry. The electrocatalytic synthesis of organonitrogen compounds through N-integrated CO₂RR (NCR) is considered crucial for improving the practical applications and offering a reference for biological small molecules. However, NCR involves multi-step electron and proton transfer processes, leading to current challenges, including slow kinetics and a complex reaction mechanism. In this review, we delve into the detailed reaction pathways and the rational design of catalysts for different NCR products, which are vital for developing highly efficient electrocatalysts. Although some progress has been made through various strategies, there are still challenges to overcome, limiting their large-scale practical applications. The discussion concludes by addressing these existing limitations and outlining potential avenues for future improvements. We hope that this feature article will be instrumental in the development of novel electrocatalysts for NCR.
- CO₂ reduction reaction,
- Nitrogenous species,
- Organonitrogen compound,
- Electrocatalysis,
- C-N coupling
1. [1]
  Mongo, M.; Belaid, F.; Ramdani, B. Environ. Sci. Policy 2021, 118, 1. doi: 10.1016/j.envsci.2020.12.004 doi: 10.1016/j.envsci.2020.12.004
2. [2]
  Wang, H.; Zhang, R. Sustain. Prod. Consump. 2022, 29, 259. doi: 10.1016/j.spc.2021.10.016 doi: 10.1016/j.spc.2021.10.016
3. [3]
  Li, W.; Yin, Z.; Gao, Z.; Wang, G.; Li, Z.; Wei, F.; Wei, X.; Peng, H.; Hu, X.; Xiao, L.; et al. Nat. Energy 2022, 7, 835. doi: 10.1038/s41560-022-01092-9 doi: 10.1038/s41560-022-01092-9
4. [4]
  Li, S.; Chen, W.; Dong, X.; Zhu, C.; Chen, A.; Song, Y.; Li, G.; Wei, W.; Sun, Y. Nat. Commun. 2022, 13, 3080. doi: 10.1038/s41467-022-30733-6 doi: 10.1038/s41467-022-30733-6
5. [5]
  Wang, X.; Jiang, Y.; Mao, K.; Gong, W.; Duan, D.; Ma, J.; Zhong, Y.; Li, J.; Liu, H.; Long, R.; et al. J. Am. Chem. Soc. 2022, 144, 22759. doi: 10.1021/jacs.2c11109 doi: 10.1021/jacs.2c11109
6. [6]
  Ma, W. C.; He, X. Y.; Wang, W.; Xie, S. J.; Zhang, Q. H.; Wang, Y. Chem. Soc. Rev. 2021, 50, 12897. doi: 10.1039/D1CS00535A doi: 10.1039/D1CS00535A
7. [7]
  Birdja, Y. Y.; Perez-Gallent, E.; Figueiredo, M. C.; Gottle, A. J.; Calle-Vallejo, F.; Koper, M. T. M. Nat. Energy 2019, 4, 732. doi: 10.1038/s41560-019-0450-y doi: 10.1038/s41560-019-0450-y
8. [8]
  Wang, G. X.; Chen, J. X.; Ding, Y. C.; Cai, P. W.; Yi, L. C.; Li, Y.; Tu, C. Y.; Hou, Y; Wen, Z. H.; Dai, L. M. Chem. Soc. Rev. 2021, 50, 4993. doi: 10.1039/D0CS00071J doi: 10.1039/D0CS00071J
9. [9]
  Pan, F.; Yang, Y. Energy Environ. Sci. 2020, 13, 2275. doi: 10.1039/D0EE00900H doi: 10.1039/D0EE00900H
10. [10]
  Ting, L. R. L.; Garcia-Muelas, R.; Martin, A. J.; Veenstra, F. L. P.; Chen, S. T.; Peng, Y.; Per, E. Y. X.; Pablo-Garcia, S.; Lopez, N.; Perez-Ramirez, J.; et al. Angew. Chem. Int. Ed. 2020, 59, 21072. doi: 10.1002/anie.202008289 doi: 10.1002/anie.202008289
11. [11]
  Chang, X.; Malkani, A.; Yang, X.; Xu, B. J. Am. Chem. Soc. 2020, 142, 2975. doi: 10.1021/jacs.9b11817 doi: 10.1021/jacs.9b11817
12. [12]
  Tang, C.; Zheng, Y.; Jaroniec, M.; Qiao, S. Z. Angew. Chem., Int. Ed. 2021, 60, 19572. doi: 10.1002/anie.202101522 doi: 10.1002/anie.202101522
13. [13]
  Suryanto, B. H. R.; Du, H. L.; Wang, D. B.; Chen, J.; Simonov, A. N.; MacFarlane, D. R. Nat. Catal. 2019, 2, 290. doi: 10.1038/s41929-019-0252-4 doi: 10.1038/s41929-019-0252-4
14. [14]
  Chen, G.; Yuan, Y. F.; Jiang, H.; Ren, S. Y.; Ding, L. X.; Ma, L.; Wu, T. P.; Lu, J.; Wang, H. H. Nat. Energy 2020, 5, 605. doi: 10.1038/s41560-020-0654-1 doi: 10.1038/s41560-020-0654-1
15. [15]
  Peter, A. A.; Norskov, J. L. J. Phys. Chem. Lett. 2012, 3, 251. doi: 10.1021/jz201461P doi: 10.1021/jz201461P
16. [16]
  Ma, W.; Xie, S.; Liu, T.; Fan, Q.; Ye, J.; Sun, F.; Jiang, Z.; Zhang, Q.; Cheng, J.; Wang, Y. Nat. Catal. 2020, 3, 478. doi: 10.1038/s41929-020-0450-0 doi: 10.1038/s41929-020-0450-0
17. [17]
  Li, L.; Ozden, A.; Guo, S.; de Arquer, F. P. G.; Wang, C.; Zhang, M.; Zhang, J.; Jiang, H.; Wang, W.; Dong, H.; et al. Nat. Commun. 2021, 12, 5223. doi: 10.1038/s41467-021-25573-9 doi: 10.1038/s41467-021-25573-9
18. [18]
  Zheng, T.; Liu, C.; Guo, C.; Zhang, M.; Li, X.; Jiang, Q.; Xue, W.; Li, H.; Li, A.; Pao, C.-W.; et al. Nat. Nanotechnol. 2021, 16, 1386. doi: 10.1038/s41565-021-00974-5 doi: 10.1038/s41565-021-00974-5
19. [19]
  Jiang, M. M.; Zhu, M. F.; Wang, M. J.; He, Y.; Luo, X. J.; Wu, C. J.; Zhang, L. Y.; Jin, Z. ACS Nano 2023, 17, 3209. doi: 10.1021/acsnano.2c11046 doi: 10.1021/acsnano.2c11046
20. [20]
  Li, J. N.; Zhang, Y. X.; Kuruvinashetti, K.; Kornienko, N. Nat. Rev. Chem. 2022, 6, 303. doi: 10.1038/s41570-022-00379-5 doi: 10.1038/s41570-022-00379-5
21. [21]
  Bogdanov, D.; Ram, M.; Aghahosseini, A; Gulagi, A.; Oyewo A.; Child, M.; Caldera, U.; Sadovskaia, K.; Farfan, J.; Barbosa. L.; et al. Energy 2021, 227, 120467. doi: 10.1016/j.energy.2021.120467 doi: 10.1016/j.energy.2021.120467
22. [22]
  Lagadec, M. F.; Grimaud, A. Nat. Mater. 2020, 19, 1140. doi: 10.1038/s41563-020-0788-3 doi: 10.1038/s41563-020-0788-3
23. [23]
  Shin, H.; Hansen, K. U.; Jiao, F. Nat. Sustain. 2021, 4, 911. doi: 10.1038/s41893-021-00739-x doi: 10.1038/s41893-021-00739-x
24. [24]
  De Luna, P.; Hahn, C.; Higgins, D.; Jaffer, S.; Jaramillo, T.; Sargent E. Science 2019, 364, eaav3506. doi: 10.1126/science.aav3506 doi: 10.1126/science.aav3506
25. [25]
  Li, J.; Kornienko, N. Chem. Sci. 2022, 13, 3957. doi: 10.1039/d1sc06590d doi: 10.1039/d1sc06590d
26. [26]
  Eller, K.; Henkes, E.; Rossbacher, R.; Hoke, H. Amines, Aliphatic. Ullmann's Encyclopedia of Industrial Chemistry; Wiley-VCH: Weinheim, Germany; 2000, 2, 647. doi: 10.1002/14356007.a02_001
27. [27]
  Vogt, P. F.; Gerulis, J. Amines, Aromatic. Ullmann's Encyclopedia of Industrial Chemistry; Wiley-VCH: Weinheim, Germany; 2000, 2, 699. doi: 10.1002/14356007.a02_037
28. [28]
  Rothgery, E. F. Kirk-Othmer Encyclopedia of Chemical Technology Wiley-VCH, Hoboken, USA; 2004, 13, 562. doi: 10.1002/0471238961.0825041819030809.a01.pub2
29. [29]
  Booth, G. Nitro Compounds, Aromatic, Ullmann's Encyclopedia of Industrial Chemistry; Wiley-VCH, New York, NY, USA; 2000, 24, 301. doi: 10.1002/14356007.a17_411
30. [30]
  McIsaac, G. F.; David, M. B.; Gertner, G. Z.; Goolsby, D. A. Nature 2001, 414, 166. doi: 10.1038/35102672 doi: 10.1038/35102672
31. [31]
  Boyer, E. W.; Alexander, R. B.; Parton, W. J.; Li, C.; Butterbach-Bahl, K.; Donner, S. D.; Skaggs, R. W.; Grosso, S. J. D. Ecol. Appl. 2006, 16, 2123. doi: 10.1890/1051-0761(2006)016[2123:MDITAA]2.0.CO;2 doi: 10.1890/1051-0761(2006)016[2123:MDITAA]2.0.CO;2
32. [32]
  Kayan, D. B.; Koleli, F. Appl. Catal. B: Environ. 2016, 181, 88. doi: 10.1016/j.apcatb.2015.07.045 doi: 10.1016/j.apcatb.2015.07.045
33. [33]
  Chen, C.; Zhu, X.; Wen, X.; Zhou, Y.; Zhou, L.; Li, H.; Tao, L.; Li, Q.; Du, S.; Liu, T.; et al. Nat. Chem. 2020, 12, 717. doi: 10.1038/s41557-020-0481-9 doi: 10.1038/s41557-020-0481-9
34. [34]
  Yuan, M.; Chen, J.; Bai, Y.; Liu, Z.; Zhang, J.; Zhao, T.; Wang, Q.; Li, S.; He, H.; Zhang, G. Angew. Chem. Int. Ed. 2021, 60, 10910. doi: 10.1002/ange.202101275 doi: 10.1002/ange.202101275
35. [35]
  Wu, Y.; Jiang, Z.; Lin, Z.; Liang, Y.; Wang, H. Nat. Sustain. 2021, 4, 725. doi: 10.1038/s41893-021-00705-7 doi: 10.1038/s41893-021-00705-7
36. [36]
  Shibata, M.; Yoshida, K.; Furuya, N. J. Electroanal. Chem. 1995, 387, 143. doi: 10.1016/0022-0728(95)03992-P doi: 10.1016/0022-0728(95)03992-P
37. [37]
  Xian, J.; Li, S.; Su, H.; Liao, P.; Wang, S.; Zhang, Y.; Yang, W.; Yang, J.; Sun, Y.; Jia, Y.; et al. Angew. Chem. Int. Ed. 2023, 62, e202304007. doi: 10.1002/anie.202304007 doi: 10.1002/anie.202304007
38. [38]
  Tao, Z.; Rooney, C. L.; Liang, Y.; Wang, H. J. Am. Chem. Soc. 2021, 143, 19630. doi: 10.1021/jacs.1c10714 doi: 10.1021/jacs.1c10714
39. [39]
  Lv, C.; Zhong, L.; Liu, H.; Fang, Z.; Yan, C.; Chen, M.; Kong, Y.; Lee, C.; Liu, D.; Li, S.; et al. Nat. Sustain. 2021, 4, 868. doi: 10.1038/s41893-021-00741-3 doi: 10.1038/s41893-021-00741-3
40. [40]
  Wei, X.; Wen, X.; Liu, Y.; Chen, C.; Xie, C.; Wang, D.; Qiu, M.; He, N.; Zhou, P.; Chen, W.; et al. J. Am. Chem. Soc. 2022, 144, 11530. doi: 10.1021/jacs.2c03452 doi: 10.1021/jacs.2c03452
41. [41]
  Zhang, X.; Zhu, X.; Bo, S.; Chen, C.; Qiu, M.; Wei, X.; He, N.; Xie, C.; Chen, W.; Zheng, J.; et al. Nat. Commun. 2022, 13, 5337. doi: 10.21203/rs.3.rs-1588933/v1 doi: 10.21203/rs.3.rs-1588933/v1
42. [42]
  Meng, N.; Huang, Y.; Liu, Y.; Yu, Y.; Zhang, B. Cell Rep. Phys. Sci. 2021, 2, 100378. doi: 10.1016/j.xcrp.2021.100378 doi: 10.1016/j.xcrp.2021.100378
43. [43]
  Guo, C.; Zhou, W.; Lan, X.; Wang, Y.; Li, T.; Han, S.; Yu, Y.; Zhang, B. J. Am. Chem. Soc. 2022, 144, 16006. doi: 10.1021/jacs.2c05660 doi: 10.1021/jacs.2c05660
44. [44]
  Jouny, M.; Lv, J. J.; Cheng, T.; Ko, B. H.; Zhu, J. J.; Goddard, W. A.; Jiao, F. Nat. Chem. 2019, 11, 846. doi: 10.1038/s41557-019-0312-z doi: 10.1038/s41557-019-0312-z
45. [45]
  Chernyshova, I.; Somasundaran, P.; Ponnurangam, S. Proc. Natl. Acad. Sci. U. S. A., 2018, 115, E9261. doi: 10.1073/pnas.1802256115 doi: 10.1073/pnas.1802256115
46. [46]
  Tao, Z. X.; Wu, Y. S.; Wu, Z. S.; Shang, B.; Rooney, B.; Wang, H. L. J. Energy Chem. 2022, 65, 367. doi: 10.1016/j.jechem.2021.06.007 doi: 10.1016/j.jechem.2021.06.007
47. [47]
  Kyriakou, V.; Garagounis, I.; Vourros, A.; Vasileiou, E.; Stoukides, M. Joule 2020, 4, 142. doi: 10.1016/j.joule.2019.10.006 doi: 10.1016/j.joule.2019.10.006
48. [48]
  Wu, Y.; Chen, C.; Yan, X.; Sun, X.; Zhu, Q.; Li, P.; Li, Y.; Liu, S.; Ma, J.; Huang, Y.; et al. Angew. Chem. Int. Ed. 2021, 60, 20803. doi: 10.1002/anie.202105263 doi: 10.1002/anie.202105263
49. [49]
  Martín, A. J.; Shinagawa, T.; Pérez-Ramírez, J. Chem 2019, 5, 263. doi: 10.1016/j.chempr.2018.10.010 doi: 10.1016/j.chempr.2018.10.010
50. [50]
  Smith, C.; Hill, A. K.; Torrente-Murciano, L. Energy Environ. Sci. 2020, 13, 331. doi: 10.1039/c9ee02873k doi: 10.1039/c9ee02873k
51. [51]
  Peng, J.; Wang, X.; Wang, Z.; Liu, B.; Zhang, P.; Li, X.; Li, N. Chin. J. Struc. Chem. 2022, 41, 2209094. doi: 10.14102/j.cnki.0254-5861.2022-0100 doi: 10.14102/j.cnki.0254-5861.2022-0100
52. [52]
  Wang, J.; Yao, Z.; Hao, L.; Sun, Z. Curr. Opin. Green Sust. 2022, 37, 100648. doi: 10.1016/j.cogsc.2022.100648 doi: 10.1016/j.cogsc.2022.100648
53. [53]
  Feng, Y.; Yang, H.; Zhang, Y.; Huang, X.; Li, L.; Cheng, T.; Shao, Q. Nano Lett. 2020, 20, 8282. doi: 10.1021/acs.nanolett.0c03400 doi: 10.1021/acs.nanolett.0c03400
54. [54]
  Zhu, X.; Zhou, X.; Jing, Y.; Li, Y. Nat. Commun. 2021, 12, 4080. doi: 10.1038/s41467-021-24400-5 doi: 10.1038/s41467-021-24400-5
55. [55]
  Pan, Y.; Lin, R.; Chen, Y.; Liu, S.; Zhu, W.; Cao, X.; Chen, W.; Wu, K.; Cheong, W.-C.; Wang, Y.; et al. J. Am. Chem. Soc. 2018, 140, 4218. doi: 10.1021/jacs.8b00814 doi: 10.1021/jacs.8b00814
56. [56]
  Leverett, J.; Tran-Phu, T.; Yuwono, J, A.; Kumar, P.; Kim, C.; Zhai, Q.; Han, C.; Qu, J.; Cainey, J.; Simonov, A. N.; et al. Adv. Energy Mater. 2022, 12, 2201500. doi: 10.1002/aenm.202201500 doi: 10.1002/aenm.202201500
57. [57]
  Zhang, X.; Zhu, X.; Bo, S.; Chen, C.; Qiu, M.; Wei, X.; He, N.; Chen, W.; Zheng, J.; Chen, P.; et al. Nat. Commun. 2022, 13, 5337. doi: 10.1038/s41467-022-33066-6 doi: 10.1038/s41467-022-33066-6
58. [58]
  Hadjiivanov, K.; Ivanova, E.; Daturi, M.; Saussey, J.; Lavalley, J. C. Chem. Phys. Lett. 2003, 370, 712. doi: 10.1016/s0009-2614(03)00173-8 doi: 10.1016/s0009-2614(03)00173-8
59. [59]
  Fan, L.; Luo, C.; Li, X.; Lu, F.; Qiu, H.; Sun, M. J. Hazard. Mater. 2012, 215, 272. doi: 10.1016/j.jhazmat.2012.02.068 doi: 10.1016/j.jhazmat.2012.02.068
60. [60]
  Kong, L.; Jiao, D.; Wang, Z.; Liu, Y.; Shang, Y.; Yin, L.; Cai, Q.; Zhao, J. Chem. Eng. J. 2023, 451, 138885. doi: 10.1016/j.cej.2022.138885 doi: 10.1016/j.cej.2022.138885
61. [61]
  Geng, J.; Ji. S.; Jin, M.; Zhang, C.; Xu, M.; Wang, G.; Liang, C.; Zhang, H. Angew. Chem. Int. Ed. 2022, 62, e202210958. doi: 10.1002/anie.202210958 doi: 10.1002/anie.202210958
62. [62]
  Hu, C.; Dai, L. Adv. Mater. 2019, 31, 1804672. doi: 10.1002/adma.201804672 doi: 10.1002/adma.201804672
63. [63]
  Liu, X.; Kumar, P.; Chen, Q.; Zhao, L.; Ye, F.; Ma, X.; Liu, D.; Chen, X.; Dai, L.; Hu, C. Appl. Catal. B. Environ. 2022, 316, 121618. doi: 10.1016/j.apcatb.2022.121618 doi: 10.1016/j.apcatb.2022.121618
64. [64]
  Roy, P.; Pramanik, A.; Sarkar, P. J. Phys. Chem. Lett. 2021, 12, 10837. doi: 10.1021/acs.jpclett.1c03242 doi: 10.1021/acs.jpclett.1c03242
65. [65]
  Meng, N.; Ma, X.; Wang, C.; Wang, Y.; Yang, R.; Shao, J.; Huang, Y.; Xu, Y.; Zhang, B.; Yu, Y. ACS Nano 2022, 16, 9095. doi: 10.1021/acsnano.2c01177 doi: 10.1021/acsnano.2c01177
66. [66]
  Xiong, Z.; Xiao, Y.; Shen, C. Chem. Mater. 2022, 34, 9402. doi: 10.1021/acs.chemmater.2c01572 doi: 10.1021/acs.chemmater.2c01572
67. [67]
  Zhang, D.; Xue, Y.; Zheng, X.; Zhang, C.; Li, Y. Natl. Sci. Rev. 2023, 10, nwac209. doi: 10.1093/nsr/nwac209 doi: 10.1093/nsr/nwac209
68. [68]
  Yuan, M.; Chen, J.; Zhang, H.; Li, Q.; Zhou, L.; Yang, C.; Liu, R.; Liu, Z.; Zhang, S.; Zhang, G. Energy. Environ. Sci. 2022, 15, 2084. doi: 10.1039/d1ee03918k doi: 10.1039/d1ee03918k
69. [69]
  Zhao, D.; Yu, K.; Song, P.; Feng, W.; Hu, B.; Cheong, W.-C.; Zhuang, Z.; Liu, S.; Sun, K.; et al. Energy Environ. Sci. 2022, 15, 3795. doi: 10.1039/D2EE00878E doi: 10.1039/D2EE00878E
70. [70]
  Liu, X.; Jiao, Y.; Zheng, Y.; Jaroniec, M.; Qiao, S. Nat. Commun. 2022, 13, 5471. doi: 10.1038/s41467-022-33258-0 doi: 10.1038/s41467-022-33258-0
71. [71]
  Yang, G.; Hsieh, C.; Ho, Y.; Kuo, T.; Kwon, Y.; Lu, Q.; Cheng, M. ACS Catal. 2022, 12, 11494. doi: 10.1021/acscatal.2c02346 doi: 10.1021/acscatal.2c02346
72. [72]
  Liu, S.; Yin, S.; Wang, Z.; Xu, Y.; Li, X.; Wang, L.; Wang, H. Cell Rep. Phys. Sci. 2022, 3: 100869. doi: 10.1016/j.xcrp.2022.100869 doi: 10.1016/j.xcrp.2022.100869
73. [73]
  Huang, Y.; Yang, R.; Wang, C.; Meng, N.; Shi, Y.; Yu, Y.; Zhang, B. ACS Energy Lett. 2022, 7, 284. doi: 10.1021/acsenergylett.1c02471 doi: 10.1021/acsenergylett.1c02471
74. [74]
  Krzywda, P.; Paradelo Rodríguez A.; Benes, N.; Mei, B.; Mul, G. Appl. Catal. B Environ. 2022, 316, 121512. doi: 10.1016/j.apcatb.2022.121512 doi: 10.1016/j.apcatb.2022.121512
75. [75]
  Wu, W.; Yang, Y.; Wang, Y.; Lu, T.; Dong, Q.; Zhao, J.; Niu, J.; Liu, Q.; Hao, Z.; Song, S. Chem. Catal. 2022, 2, 3225. doi: 10.1016/j.checat.2022.09.012 doi: 10.1016/j.checat.2022.09.012
76. [76]
  Zhang, Y.; Jiao, L.; Yang, W.; Xie, C.; Jiang, H.-L. Angew. Chem. Int. Ed. 2021, 60, 7607. doi: 10.1002/anie.202016219 doi: 10.1002/anie.202016219
77. [77]
  Yuan, M.; Zhang, H.; Xu, Y.; Liu, R.; Wang, R.; Zhao, T.; Zhang, J.; Liu, Z.; He, H.; Yang, C.; Zhang, S.; Zhang, G. Chem Catal. 2022, 2, 309. doi: 10.1016/j.checat.2021.11.009 doi: 10.1016/j.checat.2021.11.009
78. [78]
  Yang, S.; Zhang, W.; Pan, G.; Chen, J.; Deng, J.; Chen, K.; Xie, X.; Han, D.; Dai, M.; Niu, L. Angew. Chem. Int. Ed. 2023, 62, e202312076. doi: 10.1002/anie.202312076 doi: 10.1002/anie.202312076
79. [79]
  Yang, C. H.; Gao, Z. Q.; Wang, D. J.; Li, S. Y.; Li, J. J.; Zhu, Y. T.; Wang, H. Q.; Yang, W. J.; Gao, X. J.; Zhang, Z. C.; et al. Sci. China Mater. 2022, 65, 155. doi: 10.1007/s40843-021-1749-5 doi: 10.1007/s40843-021-1749-5
80. [80]
  Wang, R.; Wang, X. Y.; Weng, W. J.; Yao, Y.; Kidkhunthod, P.; Wang, C. C.; Hou, Y.; Guo, J. Angew. Chem. Int. Ed. 2021, 61, e202115503. doi: 10.1002/anie.202115503 doi: 10.1002/anie.202115503
81. [81]
  Wu, Y. S.; Jiang, Z.; Lu, X.; Liang, Y. Y.; Wang, H. L. Nature 2019, 575, 639. doi: 10.1038/s41586-019-1760-8 doi: 10.1038/s41586-019-1760-8
82. [82]
  Chen, C.; He, N. H.; Wang, S. Y. Small Sci. 2021, 1, 2100070. doi: 10.1002/smsc.202100070 doi: 10.1002/smsc.202100070
83. [83]
  Cao, N.; Quan, Y. L.; Guan, A. X.; Yang, C.; Ji, Y. L.; Zheng, G. F. J. Colloid Interface Sci. 2020, 577, 109. doi: 10.1016/j.jcis.2020.05.014 doi: 10.1016/j.jcis.2020.05.014
84. [84]
  Li, Y.; Chen, C.; Cao, R.; Pan, Z.; He, H.; Zhou, K. Appl. Catal. B 2020, 268, 118747. doi: 10.1016/j.apcatb.2020.118747 doi: 10.1016/j.apcatb.2020.118747
85. [85]
  Jiao, J.; Lin, R.; Liu, S.; Cheong, W.-C.; Zhang, C.; Chen, Z.; Pan, Y.; Tang, J.; Wu, K.; Hung, S.-F.; et al. Nat. Chem. 2019, 11, 222. doi: 10.1038/s41557-018-0201-x doi: 10.1038/s41557-018-0201-x
86. [86]
  Jiang, K.; Siahrostami, S.; Zheng, T.; Hu, Y.; Hwang, S.; Stavitski, E.; Peng, Y.; Dynes, J.; Gangisetty, M.; Su, D.; et al. Energy Environ. Sci. 2018, 11, 893. doi: 10.1039/C7EE03245E doi: 10.1039/C7EE03245E
87. [87]
  Yuan, M. L.; Chen, J. W.; Bai, Y. L.; Liu, Z. J.; Zhang, J. X.; Zhao, T. K.; Shi, Q. N.; Li, S. W.; Wang, X.; Zhang, G. J. Chem. Sci. 2021, 12, 6048. doi: 10.1039/D1SC01467F doi: 10.1039/D1SC01467F
88. [88]
  Fang, Y. X.; Liu, X.; Liu, Z. P.; Han, L.; Ai, J.; Zhao, G.; Terasaki, O.; Cui, C. H.; Yang, J. Z.; Liu, C. Y.; et al. Chem 2023, 9, 460. doi: 10.1016/j.chempr.2022.10.017 doi: 10.1016/j.chempr.2022.10.017
1. [1]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
2. [2]
  Jiajie Li , Xiaocong Ma , Jufang Zheng , Qiang Wan , Xiaoshun Zhou , Yahao Wang . Recent Advances in In-Situ Raman Spectroscopy for Investigating Electrocatalytic Organic Reaction Mechanisms. University Chemistry, 2025, 40(4): 261-276. doi: 10.12461/PKU.DXHX202406117
3. [3]
  Ye Wang , Ruixiang Ge , Xiang Liu , Jing Li , Haohong Duan . An Anion Leaching Strategy towards Metal Oxyhydroxides Synthesis for Electrocatalytic Oxidation of Glycerol. Acta Physico-Chimica Sinica, 2024, 40(7): 2307019-0. doi: 10.3866/PKU.WHXB202307019
4. [4]
  Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . Electrochemical CO₂ Reduction to C₂₊ Products with Ampere-Level Current on Carbon-Modified Copper Catalysts. Acta Physico-Chimica Sinica, 2025, 41(3): 2404012-0. doi: 10.3866/PKU.WHXB202404012
5. [5]
  Fangfang WANG , Jiaqi CHEN , Weiyin SUN . CuBi@Cu-MOF composite catalysts for electrocatalytic CO₂ reduction to HCOOH. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 97-104. doi: 10.11862/CJIC.20240350
6. [6]
  Xiting Zhou , Zhipeng Han , Xinlei Zhang , Shixuan Zhu , Cheng Che , Liang Xu , Zhenyu Sun , Leiduan Hao , Zhiyu Yang . Dual Modulation via Ag-Doped CuO Catalyst and Iodide-Containing Electrolyte for Enhanced Electrocatalytic CO₂ Reduction to Multi-Carbon Products: A Comprehensive Chemistry Experiment. University Chemistry, 2025, 40(7): 336-344. doi: 10.12461/PKU.DXHX202412070
7. [7]
  Xueting Cao , Shuangshuang Cha , Ming Gong . Interfacial Electrical Double Layer in Electrocatalytic Reactions: Fundamentals, Characterizations and Applications. Acta Physico-Chimica Sinica, 2025, 41(5): 100041-0. doi: 10.1016/j.actphy.2024.100041
8. [8]
  Xinyi Zhang , Kai Ren , Yanning Liu , Zhenyi Gu , Zhixiong Huang , Shuohang Zheng , Xiaotong Wang , Jinzhi Guo , Igor V. Zatovsky , Junming Cao , Xinglong Wu . Progress on Entropy Production Engineering for Electrochemical Catalysis. Acta Physico-Chimica Sinica, 2024, 40(7): 2307057-0. doi: 10.3866/PKU.WHXB202307057
9. [9]
  Lu Zhuoran , Li Shengkai , Lu Yuxuan , Wang Shuangyin , Zou Yuqin . Cleavage of C―C Bonds for Biomass Upgrading on Transition Metal Electrocatalysts. Acta Physico-Chimica Sinica, 2024, 40(4): 2306003-0. doi: 10.3866/PKU.WHXB202306003
10. [10]
  Qing Li , Guangxun Zhang , Yuxia Xu , Yangyang Sun , Huan Pang . P-Regulated Hierarchical Structure Ni₂P Assemblies toward Efficient Electrochemical Urea Oxidation. Acta Physico-Chimica Sinica, 2024, 40(9): 2308045-0. doi: 10.3866/PKU.WHXB202308045
11. [11]
  Ruizhi Duan , Xiaomei Wang , Panwang Zhou , Yang Liu , Can Li . The role of hydroxyl species in the alkaline hydrogen evolution reaction over transition metal surfaces. Acta Physico-Chimica Sinica, 2025, 41(9): 100111-0. doi: 10.1016/j.actphy.2025.100111
12. [12]
  Tao Wang , Qin Dong , Cunpu Li , Zidong Wei . Sulfur Cathode Electrocatalysis in Lithium-Sulfur Batteries: A Comprehensive Understanding. Acta Physico-Chimica Sinica, 2024, 40(2): 2303061-0. doi: 10.3866/PKU.WHXB202303061
13. [13]
  Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195
14. [14]
  Tongtong Zhao , Yan Wang , Shiyue Qin , Liang Xu , Zhenhua Li . New Experiment Development: Upgrading and Regeneration of Discarded PET Plastic through Electrocatalysis. University Chemistry, 2024, 39(3): 308-315. doi: 10.3866/PKU.DXHX202309003
15. [15]
  Jianchun Wang , Ruyu Xie . The Fantastical Dance of Miss Electron: Contra-Thermodynamic Electrocatalytic Reactions. University Chemistry, 2025, 40(4): 331-339. doi: 10.12461/PKU.DXHX202406082
16. [16]
  Xinlong XU , Chunxue JING , Yuzhen CHEN . Bimetallic MOF-74 and derivatives: Fabrication and efficient electrocatalytic biomass conversion. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1545-1554. doi: 10.11862/CJIC.20250046
17. [17]
  Wentao Xu , Xuyan Mo , Yang Zhou , Zuxian Weng , Kunling Mo , Yanhua Wu , Xinlin Jiang , Dan Li , Tangqi Lan , Huan Wen , Fuqin Zheng , Youjun Fan , Wei Chen . Bimetal Leaching Induced Reconstruction of Water Oxidation Electrocatalyst for Enhanced Activity and Stability. Acta Physico-Chimica Sinica, 2024, 40(8): 2308003-0. doi: 10.3866/PKU.WHXB202308003
18. [18]
  Qianlang Wang , Jijun Sun , Qian Chen , Quanqin Zhao , Baojuan Xi . The Appeal of Organophosphorus Compounds: Clearing Their Name. University Chemistry, 2025, 40(4): 299-306. doi: 10.12461/PKU.DXHX202405205
19. [19]
  Lili Jiang , Shaoyu Zheng , Xuejiao Liu , Xiaomin Xie . Copper-Catalyzed Oxidative Coupling Reactions for the Synthesis of Aryl Sulfones: A Fundamental and Exploratory Experiment for Undergraduate Teaching. University Chemistry, 2025, 40(7): 267-276. doi: 10.12461/PKU.DXHX202408004
20. [20]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(246)
HTML views(22)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Electrochemical Synthesis of Organonitrogen Compounds from N-integrated CO2 Reduction Reaction

Metrics

通讯作者: 陈斌, bchen63@163.com

Electrochemical Synthesis of Organonitrogen Compounds from N-integrated CO₂ Reduction Reaction