Citation: Chunchun Wang, Changjun You, Ke Rong, Chuqi Shen, Fang Yang, Shijie Li. An S-Scheme MIL-101(Fe)-on-BiOCl Heterostructure with Oxygen Vacancies for Boosting Photocatalytic Removal of Cr(Ⅵ)[J]. Acta Physico-Chimica Sinica, ;2024, 40(7): 230704. doi: 10.3866/PKU.WHXB202307045 shu

An S-Scheme MIL-101(Fe)-on-BiOCl Heterostructure with Oxygen Vacancies for Boosting Photocatalytic Removal of Cr(Ⅵ)

Chunchun Wang ^{1, †} ,
Changjun You ^{1, †} ,
Ke Rong ¹ ,
Chuqi Shen ¹ ,
Fang Yang ² ,
Shijie Li ^1,,

1.
Key Laboratory of Health Risk Factors for Seafood of Zhejiang Province, National Engineering Research Center for Marine Aquaculture, College of Marine Science and Technology, Zhejiang Ocean University, Zhoushan 316022, Zhejiang Province, China
2.
School of Mechanical and Automotive Engineering, Shanghai University of Engineering Science, Shanghai 201620, China

Corresponding author: Shijie Li, lishijie@zjou.edu.cn

^†

Received Date: 23 July 2023
Revised Date: 25 August 2023
Accepted Date: 25 August 2023
Available Online: 6 September 2023
Fund Project: National Natural Science Foundation of China U1809214National Natural Science Foundation of China 51708504the Natural Science Foundation of Zhejiang Province of China LY20E080014the Science and Technology Project of Zhoushan of China 2022C41011

Hexavalent chromium (Cr(Ⅵ)) may be a hazardous and non-biodegradable waste matter which will cause substantial environmental damage. Fabricating powerful photosystems to achieve efficacious elimination of Cr(Ⅵ) holds eminent promise in solving environmental issues. Thanks to their outstanding photo/electrical properties, large surface area, and customizable structure, metal-organic framework (MOF) catalysts have attracted widespread attention within the field of pollutant degradation and reduction. Nevertheless, due to the recombination of photo-generated charge carriers, pristine semiconductor MOFs' photocatalytic performance is inadequate. To overcome this challenge, one of the most typical and effective strategies is to create heterojunctions by combining MOFs with another semiconductor. Among these strategies, the innovative step-scheme (S-scheme) heterojunction has gained increasing prominence. Unlike traditional type Ⅱ and Z-scheme heterojunctions, the built-in electric field at the S-scheme heterojunction boundary enhances spatial charge separation and boosts redox capacity, thereby improving photocatalytic performance. In this study, a creative MOF-based S-scheme architecture with oxygen vacancies (OV) was built via in situ growth of MIL-101(Fe) crystals on the surface of OV-rich BiOCl microspheres. The optimized MIL-101(Fe)/BiOCl heterojunction exhibited exceptional photocatalytic performance in photo-reducing high concentrations of Cr(Ⅵ) and 88.5% of Cr(Ⅵ) solution (10 mg∙L^-1], 100 mL) can be removed within 60 min, which is about 4.4 and 9.0 times that of BiOCl and MIL-101(Fe). Besides, the MIL-101(Fe)/BiOCl manifests impressive practical implementation prospect due to its high anti-interference property, robustness and reusability. Photoelectron spectroscopy results validated that built-in electric field, bending band, and Coulomb attraction facilitated the transition of photoelectrons from the conduction band (CB) of BiOCl to the valence band (VB) of MIL-101(Fe), where they recombined with the photo-created holes. This suggests an S-scheme interfacial photo-carrier detachment mechanism at the MIL-101(Fe)/BiOCl interface. In addition, BET measurements indicated a notable increase in surface area with the introduction of MIL-101(Fe). The OV-rich S-scheme MIL-101(Fe)/BiOCl heterostructure boasts more reactive sites, enhanced interfacial charge separation, and optimal redox ability of photo-carriers, leading to enhanced photocatalytic properties. Measurements of active radical scavenging and electron spin resonance (ESR) confirm that e^- and ∙O₂^- are the primary active species during photocatalysis. These discoveries would open up new avenues for developing defective semiconductor/MOF S-scheme photocatalyst for environmental purification.
- MOF,
- S-scheme heterojunction,
- MIL-101(Fe),
- BiOCl,
- Cr(Ⅵ) photoreduction,
- Oxygen vacancy
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