Citation: Shijie Ren, Mingze Gao, Rui-Ting Gao, Lei Wang. Bimetallic Oxyhydroxide Cocatalyst Derived from CoFe MOF for Stable Solar Water Splitting[J]. Acta Physico-Chimica Sinica, ;2024, 40(7): 230704. doi: 10.3866/PKU.WHXB202307040 shu

Bimetallic Oxyhydroxide Cocatalyst Derived from CoFe MOF for Stable Solar Water Splitting

Shijie Ren ^† ,
Mingze Gao ^† ,
Rui-Ting Gao ^, ,
Lei Wang ^,

College of Chemistry and Chemical Engineering, College of Energy Material and Chemistry, Inner Mongolia University, Hohhot 010021, China

Corresponding author: Rui-Ting Gao, gao-ruiting@imu.edu.cn Lei Wang, wanglei@imu.edu.cn

^†

Received Date: 20 July 2023
Revised Date: 11 August 2023
Accepted Date: 11 August 2023
Available Online: 31 August 2023
Fund Project: the National Key Research and Development Program of China 2022YFA1205200the National Natural Science Foundation of China 21965024the National Natural Science Foundation of China 22269016

Metal-organic frameworks (MOFs) as efficient electrocatalysts can be employed as the promising cocatalysts in photoelectrochemistry. Herein, a strategy is developed to metal-organic frameworks as oxygen evolution cocatalyst (OEC) combined with semiconductor for improving the charge transport and reducing the bulk/surface carrier recombination. This advanced CoFe MOF/BiVO₄ photoanode exhibits a photocurrent density of 4.5 mA·cm^-2 at 1.23 V (vs. RHE) under AM 1.5G illumination, achieving outstanding long-term photostability. Remarkably, with the reconstruction of MOF in the long-term water oxidation reaction, more stable metal oxyhydroxides are formed on the surface of BiVO₄ and the photocurrent density of the photoelectrode is further enhanced to 5 mA·cm^-2. From density functional theory calculations, the enhanced photoelectrochemical (PEC) performance can be attributed to the coupling effect between Co and Fe decreasing the free energy barriers and accelerating the reaction kinetics. This work focuses on the reconfiguration of CoFe MOF catalyst to bimetallic hydroxide during long-term water oxidation. This work enables us to develop an effective pathway to design and fabricate efficient and stable photoanodes through MOFs catalysts for feasible PEC water splitting.
- CoFe MOF,
- Solar water splitting,
- Surface modification,
- Surface reconstruction,
- BiVO₄
1. [1]
  Landman, A.; Dotan, H.; Shter, G. E.; Wullenkord, M.; Houaijia, A.; Maljusch, A.; Grader, G. S.; Rothschild, A. Nat. Mater. 2017, 16, 646. doi: 10.1038/NMAT4876 doi: 10.1038/NMAT4876
2. [2]
  Zhang, P. L.; Sheng, X.; Chen, X. Y.; Fang, Z. Y.; Jiang, J.; Wang, M.; Li, F. S.; Fan, L. Z.; Ren, Y. S.; Zhang, B. B.; et al. Angew. Chem. Int. Ed. 2019, 58, 9155. doi: 10.1002/ange.201903936 doi: 10.1002/ange.201903936
3. [3]
  Jorge, A. B.; Jervis, R.; Periasamy, A. P.; Qiao, M.; Feng, J. Y.; Tran, L. N.; Titirici, M. -M. Adv. Energy Mater. 2020, 10, 1902494. doi: 10.1002/aenm.201902494 doi: 10.1002/aenm.201902494
4. [4]
  Li, G.; Wang, X. L.; Seo, M. H.; Hemmati, S.; Yu, A. P.; Chen, Z. W. J. Mater. Chem. A 2017, 5, 10895. doi: 10.1039/C7TA02745A doi: 10.1039/C7TA02745A
5. [5]
  Yu, M. Z.; Wang, Z. Y.; Liu, J. S.; Sun, F.; Yang, P. J.; Qiu, J. S. Nano Energy 2019, 63, 103880. doi: 10.1016/j.nanoen.2019.103880 doi: 10.1016/j.nanoen.2019.103880
6. [6]
  Jin, L.; AlOtaibi, B.; Benetti, D.; Li, S.; Zhao, H. G.; Mi, Z. T.; Vomiero, A.; Rosei, F. Adv. Sci. 2016, 3, 1500345. doi: 10.1002/advs.201500345 doi: 10.1002/advs.201500345
7. [7]
  Samuel, E.; Joshi, B.; Kim, M. -W.; Swihart, M. T.; Yoon, S. S. Nano Energy 2020, 72, 104648. doi: 10.1016/j.nanoen.2020.104648 doi: 10.1016/j.nanoen.2020.104648
8. [8]
  Lin, X.; Guo, X. Y.; Wang, Q. W.; Chang, L. M.; Zhai, H. J. Acta Phys. -Chim. Sin. 2014, 30, 2113. doi: 10.3866/PKU.WHXB201409052 doi: 10.3866/PKU.WHXB201409052
9. [9]
  Zhang, A. P.; Zhang, J. Z. Acta Phys. -Chim. Sin. 2010, 26, 1337. doi: 10.3866/PKU.WHXB20100533 doi: 10.3866/PKU.WHXB20100533
10. [10]
  Lin, X.; Yu, L. L.; Yan, L. N.; Guan, Q. F.; Yan, Y. S.; Zhao, H. Acta Phys. -Chim. Sin. 2013, 29, 1771. doi: 10.3866/PKU.WHXB201305131 doi: 10.3866/PKU.WHXB201305131
11. [11]
  Li, Y.; Hu, X. S.; Huang, J. W.; Wang, L.; She, H. D.; Wang Q. Z. Acta Phys. -Chim. Sin. 2021, 37, 2009022. doi: 10.3866/PKU.WHXB202009022 doi: 10.3866/PKU.WHXB202009022
12. [12]
  Kuang, P. Y.; Zhang, L. Y.; Cheng, B.; Yu, J. G. Appl. Catal. B-Environ. 2017, 218, 570. doi: 10.1016/j.apcatb.2017.07.002 doi: 10.1016/j.apcatb.2017.07.002
13. [13]
  Yin, S. F. Acta Phys. -Chim. Sin. 2020, 36, 1910034. doi: 10.3866/PKU.WHXB201910034 doi: 10.3866/PKU.WHXB201910034
14. [14]
  Rettie, A. J. E.; Lee, H. C.; Marshall, L. G.; Lin, J. F.; Capan, C.; Lindemuth, J.; McCloy, J. S.; Zhou, J.; Bard, A. J.; Mullins, C. B. J. Am. Chem. Soc. 2013, 135, 11389. doi: 10.1021/ja405550k doi: 10.1021/ja405550k
15. [15]
  Lu, H.; Andrei, V.; Jenkinson, K. J.; Regoutz, A.; Li, N.; Creissen, C. E.; Wheatley, A. E. H.; Hao, H.; Reisner, E.; Wright, D. S.; et al. Adv. Mater. 2018, 30, 1804033. doi: 10.1002/adma.201804033 doi: 10.1002/adma.201804033
16. [16]
  Grigioni, I.; Ganzer, L.; Camargo, V. A.; Bozzini, F. B.; Cerullo, G.; Selli, E. ACS Energy Lett. 2019, 4, 2213. doi: 10.1021/acsenergylett.9b01150 doi: 10.1021/acsenergylett.9b01150
17. [17]
  Li, H. F.; Yu, H. T.; Quan, X.; Chen, S.; Zhao, H. M. Adv. Funct. Mater. 2015, 25, 3074. doi: 10.1002/adfm.201500521 doi: 10.1002/adfm.201500521
18. [18]
  Gao, R. -T.; He, D.; Wu, L.; Hu, K.; Liu, X. H.; Su, Y. G.; Wang, L. Angew. Chem. Int. Ed. 2020, 59, 6213. doi: 10.1002/anie.201915671 doi: 10.1002/anie.201915671
19. [19]
  Pan, J. B.; Wang, B. H.; Wang, J. B.; Ding, H. -Z.; Zhou, W.; Liu, X.; Zhang, J. R.; Shen, S.; Guo, J. K.; Chen, L.; et al. Angew. Chem. Int. Ed. 2021, 60, 1433. doi: 10.1002/anie.202012550 doi: 10.1002/anie.202012550
20. [20]
  Zhou, S. Q.; Chen, K. Y.; Huang, J. W.; Wang, L.; Zhang, M. Y.; Bai, B.; Liu, H.; Wang, Q. Z. Appl. Catal. B-Environ. 2020, 266, 118513. doi: 10.1016/j.apcatb.2019.118513 doi: 10.1016/j.apcatb.2019.118513
21. [21]
  Tian, W. J.; Zhang, H. Y.; Sibbons, J.; Sun, H. Q.; Wang, H.; Wang, S. B. Adv. Energy Mater. 2021, 2100911. doi: 10.1002/aenm.202100911 doi: 10.1002/aenm.202100911
22. [22]
  Hou, X. A.; Han, Z. K.; Xu, X. J.; Sarker, D.; Zhou, J.; Wu, M. A.; Liu, Z. C.; Huang, M. H.; Jiang, H. Q. Chem. Eng. J. 2021, 418, 129330. doi: 10.1016/j.cej.2021.129330 doi: 10.1016/j.cej.2021.129330
23. [23]
  Ling, X. T.; Du, F.; Zhang, Y. T.; Shen, Y.; Gao, W.; Zhou, B.; Wang, Z. Y.; Li, G. L.; Li, T.; Shen, Q.; et al. J. Mater. Chem. A 2021, 9, 13271. doi: 10.1039/d1ta90130c doi: 10.1039/d1ta90130c
24. [24]
  Wang, Y. Q.; Tao, S.; Lin, H.; Wang, G. P.; Zhao, K. N.; Cai, R. M.; Tao, K. W.; Zhang, C. X.; Sun, M. Z.; Hu, J.; et al. Nano Energy 2021, 81, 105606. doi: 10.1016/j.nanoen.2020.105606 doi: 10.1016/j.nanoen.2020.105606
25. [25]
  Ge, K.; Sun, S. J.; Zhao, Y.; Yang, K.; Wang, S.; Zhang, Z. H.; Cao, J. Y.; Yang, Y. F.; Zhang, Y.; Pan, M. W.; et al. Angew. Chem. Int. Ed. 2021, 60, 12097. doi: 10.1002/anie.202102632 doi: 10.1002/anie.202102632
26. [26]
  He, W. H.; Wang, R. R.; Zhang, L.; Zhu, J.; Xiang, X.; Li, F. J. Mater. Chem. A 2015, 3, 17977. doi: 10.1039/c5ta04105h doi: 10.1039/c5ta04105h
27. [27]
  Nishimoto, M.; Kitano, S.; Kowalski, D.; Aoki, Y.; Habazaki, H. ACS Sustain. Chem. Eng. 2021, 9, 9465. doi: 10.1021/acssuschemeng.1c03116 doi: 10.1021/acssuschemeng.1c03116
28. [28]
  Zhao, S. L.; Wang, Y.; Dong, J. C.; He, C. -T.; Yin, H. J.; An, P. F.; Zhao, K.; Zhang, X. F.; Gao, C.; Zhang, L. J.; et al. Nat. Energy 2016, 1, 16184. doi: 10.1038/NENERGY.2016.184 doi: 10.1038/NENERGY.2016.184
29. [29]
  Chen, J. Y. C.; Dang, L. N.; Liang, H. F.; Bi, W. L.; Gerken, J. B.; Jin, S.; Alp, E. E.; Stahl, S. S. J. Am. Chem. Soc. 2015, 137, 15090. doi: 10.1021/jacs.5b10699 doi: 10.1021/jacs.5b10699
30. [30]
  Hutchings, G. S.; Zhang, Y.; Li, J.; Yonemoto, B. T.; Zhou, X.; Zhu, K.; Jiao, F. J. J. Am. Chem. Soc. 2015, 137, 4223. doi: 10.1021/jacs.5b01006 doi: 10.1021/jacs.5b01006
31. [31]
  Zhuang, L.; Ge, L.; Liu, H.; Jiang, Z.; Jia, Y.; Li, Z.; Yang, D.; Hocking, R. K.; Li, M.; Zhang, L.; et al. Angew. Chem. Int. Ed. 2019, 58, 13565. doi: 10.1002/anie.201907600 doi: 10.1002/anie.201907600
32. [32]
  Zhang, M.; Zhang, A. M.; Wang, X. X.; Huang, Q.; Zhu, X.; Wang, X. L.; Dong, L. Z.; Li, S. L.; Lan, Y. Q. J. Mater. Chem. A 2018, 6, 8735. doi:10.1039/c8ta01062e doi: 10.1039/c8ta01062e
1. [1]
  Jiahui YU , Jixian DONG , Yutong ZHAO , Fuping ZHAO , Bo GE , Xipeng PU , Dafeng ZHANG . The morphology control and full-spectrum photodegradation tetracycline performance of microwave-hydrothermal synthesized BiVO₄:Yb³⁺,Er³⁺ photocatalyst. Journal of Fuel Chemistry and Technology, 2025, 53(3): 348-359. doi: 10.1016/S1872-5813(24)60514-1
2. [2]
  Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO₄ photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225
3. [3]
  Jie WU , Zhihong LUO , Xiaoli CHEN , Fangfang XIONG , Li CHEN , Biao ZHANG , Bin SHI , Quansheng OUYANG , Jiaojing SHAO . Critical roles of AlPO₄ coating in enhancing cycling stability and rate capability of high voltage LiNi_0.5Mn_1.5O₄ cathode materials. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 948-958. doi: 10.11862/CJIC.20240400
4. [4]
  Yu Wang , Haiyang Shi , Zihan Chen , Feng Chen , Ping Wang , Xuefei Wang . 具有富电子Pt^δ−壳层的空心AgPt@Pt核壳催化剂：提升光催化H₂O₂生成选择性与活性. Acta Physico-Chimica Sinica, 2025, 41(7): 100081-0. doi: 10.1016/j.actphy.2025.100081
5. [5]
  Sikai Wu , Xuefei Wang , Huogen Yu . Hydroxyl-enriched hydrous tin dioxide-coated BiVO4 with boosted photocatalytic H2O2 production. Chinese Journal of Structural Chemistry, 2024, 43(12): 100457-100457. doi: 10.1016/j.cjsc.2024.100457
6. [6]
  Lan Ma , Cailu He , Ziqi Liu , Yaohan Yang , Qingxia Ming , Xue Luo , Tianfeng He , Liyun Zhang . Magical Surface Chemistry: Fabrication and Application of Oil-Water Separation Membranes. University Chemistry, 2024, 39(5): 218-227. doi: 10.3866/PKU.DXHX202311046
7. [7]
  Honglian Liang , Xiaozhe Kuang , Fuping Wang , Yu Chen . Exploration and Practice of Integrating Ideological and Political Education into Physical Chemistry: a Case on Surface Tension and Gibbs Free Energy. University Chemistry, 2024, 39(10): 433-440. doi: 10.12461/PKU.DXHX202405073
8. [8]
  Longsheng Zhan , Yuchao Wang , Mengjie Liu , Xin Zhao , Danni Deng , Xinran Zheng , Jiabi Jiang , Xiang Xiong , Yongpeng Lei . BiVO₄ as a precatalyst for CO₂ electroreduction to formate at large current density. Chinese Chemical Letters, 2025, 36(3): 109695-. doi: 10.1016/j.cclet.2024.109695
9. [9]
  Lina Wang , Hairu Wang , Qian Bu , Qiong Mei , Junbo Zhong , Bo Bai , Qizhao Wang . Al-O bridged NiFeO_x/BiVO₄ photoanode for exceptional photoelectrochemical water splitting. Chinese Chemical Letters, 2025, 36(4): 110139-. doi: 10.1016/j.cclet.2024.110139
10. [10]
  Hailang Deng , Abebe Reda Woldu , Abdul Qayum , Zanling Huang , Weiwei Zhu , Xiang Peng , Paul K. Chu , Liangsheng Hu . Killing two birds with one stone: Enhancing the photoelectrochemical water splitting activity and stability of BiVO₄ by Fe ions association. Chinese Chemical Letters, 2024, 35(12): 109892-. doi: 10.1016/j.cclet.2024.109892
11. [11]
  Ruiqin Feng , Ye Fan , Yun Fang , Yongmei Xia . Strategy for Regulating Surface Protrusion of Gold Nanoflowers and Their Surface-Enhanced Raman Scattering. Acta Physico-Chimica Sinica, 2024, 40(4): 2304020-0. doi: 10.3866/PKU.WHXB202304020
12. [12]
  Jinwang Wu , Qijing Xie , Chengliang Zhang , Haifeng Shi . Rationally Designed ZnFe_1.2Co_0.8O₄/BiVO₄ S-Scheme Heterojunction with Spin-Polarization for the Elimination of Antibiotic. Acta Physico-Chimica Sinica, 2025, 41(5): 100050-0. doi: 10.1016/j.actphy.2025.100050
13. [13]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
14. [14]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . Remarkable Photocatalytic H₂O₂ Production Efficiency over Ultrathin g-C₃N₄ Nanosheet with Large Surface Area and Enhanced Crystallinity by Two-Step Calcination. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-0. doi: 10.3866/PKU.WHXB202406019
15. [15]
  Xinlong WANG , Zhenguo CHENG , Guo WANG , Xiaokuen ZHANG , Yong XIANG , Xinquan WANG . Enhancement of the fragile interface of high voltage LiCoO₂ by surface gradient permeation of trace amounts of Mg/F. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 571-580. doi: 10.11862/CJIC.20230259
16. [16]
  Zhuomin Zhang , Hanbing Huang , Liangqiu Lin , Jingsong Liu , Gongke Li . Course Construction of Instrumental Analysis Experiment: Surface-Enhanced Raman Spectroscopy for Rapid Detection of Edible Pigments. University Chemistry, 2024, 39(2): 133-139. doi: 10.3866/PKU.DXHX202308034
17. [17]
  Yukai Jiang , Yihan Wang , Yunkai Zhang , Yunping Wei , Ying Ma , Na Du . Characterization and Phase Diagram of Surfactant Lyotropic Liquid Crystal. University Chemistry, 2024, 39(4): 114-118. doi: 10.3866/PKU.DXHX202309033
18. [18]
  Ruilin Han , Xiaoqi Yan . Comparison of Multiple Function Methods for Fitting Surface Tension and Concentration Curves. University Chemistry, 2024, 39(7): 381-385. doi: 10.3866/PKU.DXHX202311023
19. [19]
  Yongjie ZHANG , Bintong HUANG , Yueming ZHAI . Research progress of formation mechanism and characterization techniques of protein corona on the surface of nanoparticles. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2318-2334. doi: 10.11862/CJIC.20240247
20. [20]
  Xia Shu , Longtian Sima , Jiali Wang , Jiacheng Chu , Xieyidai·Yusunjiang , Mubareke·Maimaitijiang , Yingwei Lu , Yan Wang . Analysis of the Report Generated by the QuadraSorb evo BET Surface Area Analyzer. University Chemistry, 2025, 40(5): 391-400. doi: 10.12461/PKU.DXHX202411013

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(242)
HTML views(21)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142