Citation: Lutian Zhao, Yangge Guo, Liuxuan Luo, Xiaohui Yan, Shuiyun Shen, Junliang Zhang. Electrochemical Synthesis for Metallic Nanocrystal Electrocatalysts: Principle, Application and Challenge[J]. Acta Physico-Chimica Sinica, ;2024, 40(7): 230602. doi: 10.3866/PKU.WHXB202306029 shu

Electrochemical Synthesis for Metallic Nanocrystal Electrocatalysts: Principle, Application and Challenge

Lutian Zhao ¹ ,
Yangge Guo ¹ ,
Liuxuan Luo ¹ ,
Xiaohui Yan ¹ ,
Shuiyun Shen ^{1, 2,,} ,
Junliang Zhang ^{1, 2}

1.
Institute of Fuel Cells, School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
2.
MOE Key Laboratory of Power & Machinery Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

Corresponding author: Shuiyun Shen, shuiyun_shen@sjtu.edu.cn
Received Date: 14 June 2023
Revised Date: 30 July 2023
Accepted Date: 23 August 2023
Available Online: 29 August 2023
Fund Project: the National Key Research and Development Program of China 2021YFB4001301the Oceanic Interdisciplinary Program of Shanghai Jiao Tong University SL2021ZD105

Nanoscale metallic catalysts are garnering increased attention in the advancement of electrochemical energy conversion technologies. The precise control of nanocrystal morphology, size, and crystalline structures offers the ability to manipulate electronic properties and enhance intrinsic catalytic performance. Consequently, a profound understanding of the nanocrystal growth mechanism becomes imperative for the design and production of highly active catalysts. However, mechanism studies in colloidal methods generally depend on operando technics and the development is hindered by expensive cost and limited resources. And high-temperature or high-pressure reaction conditions always bring trouble for the application of the equipment, so the in situ methods have been widely used. While ex situ methods need to detach the samples from the reaction environment, which might lose information about the process and thus fail to reflect the real situation. Furthermore, in conventional methods, the use of macromolecular organics to regulate crystal morphology results in intricate post-treatment processes, and any residual substances can adversely affect catalyst performance. Electrochemical synthesis offers a clean and controllable protocol for producing metallic nanocrystals and supported heterogeneous nanoparticle catalysts. In this review, building upon the classic principles of crystal growth in chemical colloidal methods and electrodeposition, it is proposed that the processes occurring during crystal formation could be visualized or monitored through electrochemical tests. By fine-tuning electrochemical parameters and refining deposition procedures, nucleation density and growth rates along specific facet orientations of nanocrystals can be precisely managed. Electrochemical signals provide insights into in situ reduction and deposition behaviors at the electrode-electrolyte interfaces through professional analysis. The direct loading of nanocrystals onto substrates amplifies their synergistic effects, mitigates exfoliation issues, and consequently enhances catalytic activity and stability. Additionally, due to its broader potential window compared to H₂O, non-aqueous liquids hold promise as a solution for preparing active metals and alloys that exhibit distinctive catalytic performance. Furthermore, electrochemical methods facilitate the synthesis of compounds composed of metallic and nonmetal elements, including metal oxides and phosphides. Thus, electrochemical techniques are poised to offer potential high-performance nanoscale metallic catalysts along with profound insights into the crystal growth mechanism. Nevertheless, a critical challenge hindering the application of electrochemical methods lies in bridging the considerable gap between catalysts and the preparation of electrode-level catalyst layers. The electrochemical signal proves highly sensitive to variations in the reaction environment, and discrepancies in electrode and system properties can lead to distinct electrochemical responses. Consequently, thorough investigations are imperative to address these issues.
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沈阳化工大学材料科学与工程学院沈阳 110142