Citation: Lu Zhuoran, Li Shengkai, Lu Yuxuan, Wang Shuangyin, Zou Yuqin. Cleavage of C―C Bonds for Biomass Upgrading on Transition Metal Electrocatalysts[J]. Acta Physico-Chimica Sinica, ;2024, 40(4): 230600. doi: 10.3866/PKU.WHXB202306003 shu

Cleavage of C―C Bonds for Biomass Upgrading on Transition Metal Electrocatalysts

Lu Zhuoran ¹ ,
Li Shengkai ^{1, 2} ,
Lu Yuxuan ^{1, 3} ,
Wang Shuangyin ¹ ,
Zou Yuqin ^1,,

1.
State Key Laboratory of Chemo/Bio-Sensing and Chemometrics, Advanced Catalytic Engineering Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China
2.
Shenzhen Institute of Hunan University, Shenzhen 518057, Guangdong Province, China
3.
School of Chemistry and Chemical Engineering, Jishou University, Jishou 416000, Hunan Province, China

Corresponding author: Zou Yuqin, yuqin_zou@hnu.edu.cn
Received Date: 1 June 2023
Revised Date: 3 July 2023
Accepted Date: 3 July 2023
Available Online: 10 July 2023
Fund Project: the National Key R&D Program of China 2020YFA0710000the National Natural Science Foundation of China 22122901the Provincial Natural Science Foundation of Hunan, China 2021JJ0008the Provincial Natural Science Foundation of Hunan, China 2021JJ20024the Provincial Natural Science Foundation of Hunan, China 2021RC3054the Shenzhen Science and Technology Program, China JCYJ20210324140610028

Transforming the current structure of energy production and consumption, which currently excessively relies on fossil fuels, into a more efficient utilization of renewable energy, is an effective solution for addressing the energy crisis and achieving carbon neutrality. Biomass represents one of the most promising sources of renewable energy, capable of replacing fossil fuels and yielding valuable organic compounds. In recent years, the vigorous utilization of biomass energy sources has become an inevitable trend. The conventional thermochemical catalysis method used for biomass conversion often requires harsh conditions, such as high temperatures and pressures, and even external sources of hydrogen or oxygen. In comparison, the electrocatalytic conversion of organic molecules derived from biomass offers a greener and more efficient strategy for producing high-value chemicals under relatively mild conditions. Particularly, the cleavage of carbon chains through C―C bond cleavage is crucial in transforming biomass-derived molecules into short-chain chemicals of high value. Numerous studies have demonstrated that transition metal (TM) electrocatalysts play a critical role in the C―C bond cleavage of organic compounds, owing to their rich 3d electron structure and unique e_g orbitals that enhance the covalence of transition metal-oxygen bonds. Moreover, the coordination environments and electronic structures of TM electrocatalysts can influence the selectivity of the products. Undoubtedly, well-defined active sites and reaction pathways facilitate a comprehensive understanding of the structure-activity relationship between catalyst structure and reaction activity. However, the electrocatalytic cleavage of C―C bonds for biomass upgrading on TM electrocatalysts is still in its initial stages, and the reaction mechanism and catalytic processes remain unclear. Therefore, there is a need to systematically comprehend the role of electrocatalysts at the atomic level during the C―C bond cleavage process. This review begins by providing an overview of the extensively studied TM electrocatalysts that mediate C―C bond cleavage reactions of organic molecules derived from biomass, including glycerol, cyclohexanol, lignin, and furfural. Several representative examples and corresponding reaction pathways are presented. Subsequently, we systematically review the reaction mechanisms underlying the catalytic C―C bond cleavage by transition metal compounds, elucidate interfacial behaviors, and establish a structure-activity relationship between the structure of TM electrocatalysts and cleavage reaction activity. Finally, we provide a brief summary of the content covered and highlight the challenges and prospects in exploring C―C bond cleavage on TM electrocatalysts. It is anticipated that this work will serve as a guide for the controlled conversion of biomass and the rational design of TM electrocatalysts for C―C bond cleavage.
- Electrocatalytic biomass upgrading,
- C―C bond cleavage,
- Electrocatalysis,
- Transition metal catalyst
1. [1]
  Araji, N.; Madjinza, D. D.; Chatel, G.; Moores, A.; Jérôme, F.; Vigier, K. D. O. Green Chem. 2017, 19, 98. doi: 10.1039/C6GC02620F doi: 10.1039/C6GC02620F
2. [2]
  Li, K.; Sun, Y. Chem-Eur. J. 2018, 24, 18258. doi: 10.1002/chem.201803319 doi: 10.1002/chem.201803319
3. [3]
  Du, L.; Shao, Y.; Sun, J.; Yin, G.; Du, C.; Wang, Y. Catal. Sci. Technol. 2018, 8, 3216. doi: 10.1039/c8cy00533h doi: 10.1039/c8cy00533h
4. [4]
  Kim, H. J.; Kim, Y.; Lee, D.; Kim, J.-R.; Chae, H.-J.; Jeong, S.-Y.; Kim, B. -S.; Lee, J.; Huber, G. W.; Byun, J.; et al. ACS Sustain. Chem. Eng. 2017, 5, 6626. doi: 10.1021/acssuschemeng.7b00868 doi: 10.1021/acssuschemeng.7b00868
5. [5]
  Wang, H.; Thia, L.; Li, N.; Ge, X.; Liu, Z.; Wang, X. ACS Catal. 2015, 5, 3174. doi: 10.1021/acscatal.5b00183 doi: 10.1021/acscatal.5b00183
6. [6]
  Dodekatos, G.; Schünemann, S.; Tüysüz, H. ACS Catal. 2018, 8, 6301. doi: 10.1021/acscatal.8b01317 doi: 10.1021/acscatal.8b01317
7. [7]
  Si, D.; Xiong, B.; Chen, L.; Shi, J. Chem Catal. 2021, 1, 941. doi: 10.1016/j.checat.2021.08.001 doi: 10.1016/j.checat.2021.08.001
8. [8]
  Li, Y.; Peng, Y.-K.; Hu, L.; Zheng, J.; Prabhakaran, D.; Wu, S.; Puchtler, T. J.; Li, M.; Wong, K.-Y.; Taylor, R. A. Nat. Commun. 2019, 10, 4421. doi: 10.1038/s41467-019-12385-1 doi: 10.1038/s41467-019-12385-1
9. [9]
  Bambagioni, V.; Bianchini, C.; Marchionni, A.; Filippi, J.; Vizza, F.; Teddy, J.; Serp, P.; Zhiani, M. J. Power Sources 2009, 190, 241. doi: 10.1016/j.jpowsour.2009.01.044 doi: 10.1016/j.jpowsour.2009.01.044
10. [10]
  Caliman, C. C.; Palma, L.; Ribeiro, J. J. Electrochem. Soc. 2013, 160, F853. doi: 10.1149/2.073308jes doi: 10.1149/2.073308jes
11. [11]
  Habibi, B.; Ghaderi, S. Int. J. Hydrog. Energy 2015, 40, 5115. doi: 10.1016/j.ijhydene.2015.02.103 doi: 10.1016/j.ijhydene.2015.02.103
12. [12]
  Fernández, P. S.; Martins, C. A.; Martins, M. E.; Camara, G. A. Electrochim. Acta 2013, 112, 686. doi: 10.1016/j.electacta.2013.09.032 doi: 10.1016/j.electacta.2013.09.032
13. [13]
  Lopes, F. S.; Nogueira, T.; Do Lago, C. L.; Gutz, I. G. Electroanalysis 2011, 23, 2516. doi: 10.1002/elan.201100321 doi: 10.1002/elan.201100321
14. [14]
  Jeffery, D. Z.; Camara, G. A. Electrochem. Commun. 2010, 12, 1129. doi: 10.1016/j.elecom.2010.06.001 doi: 10.1016/j.elecom.2010.06.001
15. [15]
  Kwon, Y.; Birdja, Y.; Spanos, I.; Rodriguez, P.; Koper, M. T. M. ACS Catal. 2012, 2, 759. doi: 10.1021/cs200599g doi: 10.1021/cs200599g
16. [16]
  Kwon, Y.; Lai, S. C.; Rodriguez, P.; Koper, M. T. J. Am. Chem. Soc. 2011, 133, 6914. doi: 10.1021/ja200976j doi: 10.1021/ja200976j
17. [17]
  Simões, M.; Baranton, S.; Coutanceau. Appl. Catal. B. Environ. 2010, 93, 354. doi: 10.1016/j.apcatb.2009.10.008 doi: 10.1016/j.apcatb.2009.10.008
18. [18]
  Yongprapat, S.; Therdthianwong, A.; Therdthianwong, S. J. Appl. Electrochem. 2012, 42, 483. doi: 10.1007/s10800-012-0423-3 doi: 10.1007/s10800-012-0423-3
19. [19]
  Yongprapat, S.; Therdthianwong, S.; Therdthianwong, A. Electrochim. Acta 2012, 83, 87. doi: 10.1016/j.electacta.2012.08.031 doi: 10.1016/j.electacta.2012.08.031
20. [20]
  Zhang, Z.; Xin, L.; Li, W. Int. J. Hydrog. Energy 2012, 37, 9393. doi: 10.1016/j.ijhydene.2012.03.019 doi: 10.1016/j.ijhydene.2012.03.019
21. [21]
  Zhou, H.; Li, Z.; Xu, S. M.; Lu, L.; Xu, M.; Ji, K.; Ge, R.; Yan, Y.; Ma, L.; Kong, X.; et al. Angew. Chem. Int. Ed. 2021, 60, 8976. doi: 10.1002/anie.202015431 doi: 10.1002/anie.202015431
22. [22]
  Dash, S.; Munichandraiah, N. J. Electrochem. Soc. 2013, 160, H197. doi: 10.1149/2.007304jes doi: 10.1149/2.007304jes
23. [23]
  Renard, D.; Mccain, C.; Baidoun, B.; Bondy, A.; Bandyopadhyay, K. Colloids Surf. A 2014, 463, 44. doi: 10.1016/j.colsurfa.2014.09.027 doi: 10.1016/j.colsurfa.2014.09.027
24. [24]
  Zhiani, M.; Rostami, H.; Majidi, S.; Karami, K. Int. J. Hydrog. Energy 2013, 38, 5435. doi: 10.1016/j.ijhydene.2012.09.001 doi: 10.1016/j.ijhydene.2012.09.001
25. [25]
  Zalineeva, A.; Baranton, S.; Coutanceau, C. Electrochim. Acta 2015, 176, 705. doi: 10.1016/j.electacta.2015.07.073 doi: 10.1016/j.electacta.2015.07.073
26. [26]
  Dai, C.; Sun, L.; Liao, H.; Khezri, B.; Webster, R. D.; Fisher, A. C.; Xu, Z. J. J. Catal. 2017, 356, 14. doi: 10.1016/j.jcat.2017.10.010 doi: 10.1016/j.jcat.2017.10.010
27. [27]
  Bender, M. T.; Lam, Y. C.; Hammes-Schiffer, S.; Choi, K.-S. J. Am. Chem. Soc. 2020, 142, 21538. doi: 10.1021/jacs.0c10924 doi: 10.1021/jacs.0c10924
28. [28]
  Bender, M. T.; Warburton, R. E.; Hammes-Schiffer, S.; Choi, K.-S. ACS Catal. 2021, 11, 15110. doi: 10.1021/acscatal.1c04163 doi: 10.1021/acscatal.1c04163
29. [29]
  Franceschini, F.; Taurino, I. J. P. I. M. Phys. Med. 2022, 100054. doi: 10.1016/j.phmed.2022.100054 doi: 10.1016/j.phmed.2022.100054
30. [30]
  Li, Y.; Wei, X.; Chen, L.; Shi, J.; He, M. Nat. Commun. 2019, 10, 5335. doi: 10.1038/s41467-019-13375-z doi: 10.1038/s41467-019-13375-z
31. [31]
  Wu, J.; Liu, X.; Hao, Y.; Wang, S.; Wang, R.; Du, W.; Cha, S.; Ma, X. Y.; Yang, X.; Gong, M. Angew. Chem. Int. Ed. 2023, 62, e202216083. doi: 10.1002/anie.202216083 doi: 10.1002/anie.202216083
32. [32]
  Sun, S.; Sun, L.; Xi, S.; Du, Y.; Prathap, M. A.; Wang, Z.; Zhang, Q.; Fisher, A.; Xu, Z. J. Electrochim. Acta 2017, 228, 183. doi: 10.1016/j.electacta.2017.01.086 doi: 10.1016/j.electacta.2017.01.086
33. [33]
  Han, X.; Sheng, H.; Yu, C.; Walker, T. W.; Huber, G. W.; Qiu, J.; Jin, S. ACS Catal. 2020, 10, 6741. doi: 10.1021/acscatal.0c01498 doi: 10.1021/acscatal.0c01498
34. [34]
  Li, Y.; Wei, X.; Han, S.; Chen, L.; Shi, J. Angew. Chem. Int. Ed. 2021, 60, 21464. doi: 10.1002/anie.202107510 doi: 10.1002/anie.202107510
35. [35]
  Kruyer, N. S.; Peralta-Yahya, P. Curr. Opin. Biotechnol. 2017, 45, 136. doi: 10.1016/j.copbio.2017.03.006 doi: 10.1016/j.copbio.2017.03.006
36. [36]
  Yan, W.; Zhang, G.; Wang, J.; Liu, M.; Sun, Y.; Zhou, Z.; Zhang, W.; Zhang, S.; Xu, X.; Shen, J.; et al. Front. Chem. 2020, 8, 185. doi: 10.3389/fchem.2020.00185 doi: 10.3389/fchem.2020.00185
37. [37]
  Yang, J.; Liu, J.; Neumann, H.; Franke, R.; Jackstell, R.; Beller, M. Science 2019, 366, 1514. doi: 10.1126/science.aaz1293 doi: 10.1126/science.aaz1293
38. [38]
  Rios, J.; Lebeau, J.; Yang, T.; Li, S.; Lynch, M. D. Green. Chem. 2021, 23, 3172. doi: 10.1039/d1gc00638j doi: 10.1039/d1gc00638j
39. [39]
  Schaub, T. Science 2019, 366, 1447. doi: 10.1126/science.aaz6459 doi: 10.1126/science.aaz6459
40. [40]
  Van De Vyver, S.; Román-Leshkov, Y. Catal. Sci. Technol. 2013, 3, 1465. doi: 10.1039/c3cy20728e doi: 10.1039/c3cy20728e
41. [41]
  Skoog, E.; Shin, J. H.; Saez-Jimenez, V.; Mapelli, V.; Olsson, L. Biotechnol. Adv. 2018, 36, 2248. doi: 10.1016/j.biotechadv.2018.10.012 doi: 10.1016/j.biotechadv.2018.10.012
42. [42]
  Wang, R.; Kang, Y.; Wu, J.; Jiang, T.; Wang, Y.; Gu, L.; Li, Y.; Yang, X.; Liu, Z.; Gong, M. Angew. Chem. Int. Ed. 2022, 61, e202214977. doi: 10.1002/anie.202214977 doi: 10.1002/anie.202214977
43. [43]
  Chaenko, N.; Kornienko, G.; Sokolenko, V.; Kornienko, B. Russ. J. Appl. Chem. 2014, 87, 444. doi: 10.1134/s1070427214040089 doi: 10.1134/s1070427214040089
44. [44]
  Rauen, A. L.; Weinelt, F.; Waldvogel, S. R. Green Chem. 2020, 22, 5956. doi: 10.1039/d0gc02210a doi: 10.1039/d0gc02210a
45. [45]
  Zhao, H.; Qu, X.; Qin, M.; Yang, W. J. Solid State Electrochem. 2016, 20, 2773. doi: 10.1007/s10008-016-3286-4 doi: 10.1007/s10008-016-3286-4
46. [46]
  Li, Z.; Li, X.; Zhou, H.; Xu, Y.; Xu, S. M.; Ren, Y.; Yan, Y.; Yang, J.; Ji, K.; Li, L.; et al. Nat. Commun. 2022, 13, 5009. doi: 10.1038/s41467-022-32769-0 doi: 10.1038/s41467-022-32769-0
47. [47]
  Lyalin, B.; Petrosyan, V. Russ. Chem. Bull. 2009, 58, 2426. doi: 10.1007/s11172-009-0339-1 doi: 10.1007/s11172-009-0339-1
48. [48]
  Hasanzadeh, M.; Karim-Nezhad, G.; Mahjani, M. G.; Jafarian, M.; Shadjou, N.; Khalilzadeh, B.; Saghatforoush, L. A. Catal. Commun. 2008, 10, 295. doi: 10.1016/j.catcom.2008.09.010 doi: 10.1016/j.catcom.2008.09.010
49. [49]
  Collinson, S.; Thielemans, W. Coord. Chem. Rev. 2010, 254, 1854. doi: 10.1016/j.ccr.2010.04.007 doi: 10.1016/j.ccr.2010.04.007
50. [50]
  Vennestrøm, P.; Osmundsen, C. M.; Christensen, C.; Taarning, E. Angew. Chem. Int. Ed. 2011, 50, 10502. doi: 10.1002/anie.201102117 doi: 10.1002/anie.201102117
51. [51]
  Shuai, L.; Amiri, M. T.; Questell-Santiago, Y. M.; Héroguel, F.; Li, Y.; Kim, H.; Meilan, R.; Chapple, C.; Ralph, J.; Luterbacher, J. S. Science 2016, 354, 329. doi: 10.1126/science.aaf7810 doi: 10.1126/science.aaf7810
52. [52]
  Rahimi, A.; Ulbrich, A.; Coon, J. J.; Stahl, S. S. Nature 2014, 515, 249. doi: 10.1038/nature13867 doi: 10.1038/nature13867
53. [53]
  Jiang, L.; Sheng, L.; Fan, Z. Sci. China Mater. 2018, 61, 133. doi: 10.1007/s40843-017-9169-4 doi: 10.1007/s40843-017-9169-4
54. [54]
  Wong, S. S.; Shu, R.; Zhang, J.; Liu, H.; Yan, N. Chem. Soc. Rev. 2020, 49, 5510. doi: 10.1039/d0cs00134a doi: 10.1039/d0cs00134a
55. [55]
  Tian, H.; Fu, X.; Zheng, M.; Wang, Y.; Li, Y.; Xiang, A.; Zhong, W. -H. Nano Res. 2018, 11, 4265. doi: 10.1007/s12274-018-2013-0 doi: 10.1007/s12274-018-2013-0
56. [56]
  Constant, S.; Wienk, H. L.; Frissen, A. E.; De Peinder, P.; Boelens, R.; Van Es, D. S.; Grisel, R. J.; Weckhuysen, B. M.; Huijgen, W. J.; Gosselink, R. J. Green Chem. 2016, 18, 2651. doi: 10.1039/C5GC03043A doi: 10.1039/C5GC03043A
57. [57]
  Sun, Z.; Fridrich, B.; De Santi, A.; Elangovan, S.; Barta, B. Chem. Rev. 2018, 118, 614. doi: 10.1021/acs.chemrev.7b00588 doi: 10.1021/acs.chemrev.7b00588
58. [58]
  Bosque, I.; Magallanes, G.; Rigoulet, M.; KäRkäS, M. D.; Stephenson, C. R. ACS Cent. Sci. 2017, 3, 621. doi: 10.1021/acscentsci.7b00140 doi: 10.1021/acscentsci.7b00140
59. [59]
  Han, S.; Wang, C.; Wang, Y.; Yu, Y.; Zhang, B. Angew. Chem. Int. Ed. 2021, 133, 4524. doi: 10.1002/anie.202014017 doi: 10.1002/anie.202014017
60. [60]
  Möhle, S.; Zirbes, M.; Rodrigo, E.; Gieshoff, T.; Wiebe, A.; Waldvogel, S. R. Angew. Chem. Int. Ed. 2018, 57, 6018. doi: 10.1002/anie.201712732 doi: 10.1002/anie.201712732
61. [61]
  Yuan, Y.; Lei, A. Acc. Chem. Res. 2019, 52, 3309. doi: 10.1021/acs.accounts.9b00512 doi: 10.1021/acs.accounts.9b00512
62. [62]
  Xu, C.; Arancon, R. a. D.; Labidi, J.; Luque, R. Chem. Soc. Rev. 2014, 43, 7485. doi: 10.1039/c4cs00235k doi: 10.1039/c4cs00235k
63. [63]
  Nichols, J. M.; Bishop, L. M.; Bergman, R. G.; Ellman, J. A. J. Am. Chem. Soc. 2010, 132, 12554. doi: 10.1021/ja109016b doi: 10.1021/ja109016b
64. [64]
  Wu, A.; Patrick, B. O.; Chung, E.; James, B. R. Dalton Trans. 2012, 41, 11093. doi: 10.1039/C2DT31065A doi: 10.1039/C2DT31065A
65. [65]
  Norman, C. Science 2011, 332, 1263. doi: 10.1126/science.332.6035.1263-c doi: 10.1126/science.332.6035.1263-c
66. [66]
  Lahive, C. W.; Deuss, P. J.; Lancefield, C. S.; Sun, Z.; Cordes, D. B.; Young, C. M.; Tran, F.; Slawin, A. M.; De Vries, J. G.; Kamer, P. C.; et al. J. Am. Chem. Soc. 2016, 138, 8900. doi: 10.1021/jacs.6b04144 doi: 10.1021/jacs.6b04144
67. [67]
  Luo, N.; Wang, M.; Li, H.; Zhang, J.; Hou, T.; Chen, H.; Zhang, X.; Lu, J.; Wang, F. ACS Catal. 2017, 7, 4571. doi: 10.1021/acscatal.7b01043 doi: 10.1021/acscatal.7b01043
68. [68]
  Luo, N.; Wang, M.; Li, H.; Zhang, J.; Liu, H.; Wang, F. ACS Catal. 2016, 6, 7716. doi: 10.1021/acscatal.6b02212 doi: 10.1021/acscatal.6b02212
69. [69]
  Lancefield, C. S.; Ojo, O. S.; Tran, F.; Westwood, N. Angew. Chem. Int. Ed. 2015, 127, 260. doi: 10.1002/anie.201409408 doi: 10.1002/anie.201409408
70. [70]
  Sedai, B.; Baker, R. T. Adv. Synth. Catal. 2014, 356, 3563. doi: 10.1002/adsc.201400463 doi: 10.1002/adsc.201400463
71. [71]
  Tran, F.; Lancefield, C.; Kamer, P.; Lebl, T.; Westwood, N. Green Chem. 2015, 17, 244. doi: 10.1039/c4gc01012d doi: 10.1039/c4gc01012d
72. [72]
  Hanson, S. K.; Wu, R.; Silks, L. A. P. Angew. Chem. Int. Ed. 2012, 124, 3466. doi: 10.1002/anie.201107020 doi: 10.1002/anie.201107020
73. [73]
  Cho, D. W.; Parthasarathi, R.; Pimentel, A. S.; Maestas, G. D.; Park, H. J.; Yoon, U. C.; Dunaway-Mariano, D.; Gnanakaran, S.; Langan, P.; Mariano, P. S. J. Org. Chem. 2010, 75, 6549. doi: 10.1021/jo1012509 doi: 10.1021/jo1012509
74. [74]
  Lim, S. H.; Nahm, K.; Ra, C. S.; Cho, D. W.; Yoon, U. C.; Latham, J. A.; Dunaway-Mariano, D.; Mariano, P. S. J. Org. Chem. 2013, 78, 9431. doi: 10.1021/jo401680z doi: 10.1021/jo401680z
75. [75]
  Hanson, S. K.; Baker, R. T. Acc. Chem. Res. 2015, 48, 2037. doi: 10.1021/acs.accounts.5b00104 doi: 10.1021/acs.accounts.5b00104
76. [76]
  Parthasarathi, R.; Romero, R. A.; Redondo, A.; Gnanakaran, S. J. Phys. Chem. Lett. 2011, 2, 2660. doi: 10.1021/jz201201q doi: 10.1021/jz201201q
77. [77]
  Kim, S.; Chmely, S. C.; Nimlos, M. R.; Bomble, Y. J.; Foust, T. D.; Paton, R. S.; Beckham, G. T. J. Phys. Chem. Lett. 2011, 2, 2846. doi: 10.1021/jz201182w doi: 10.1021/jz201182w
78. [78]
  Kleine, T.; Buendia, J.; Bolm, C. Green Chem. 2013, 15, 160. doi: 10.1039/c2gc36456e doi: 10.1039/c2gc36456e
79. [79]
  Cui, T.; Ma, L.; Wang, S.; Ye, C.; Liang, X.; Zhang, Z.; Meng, G.; Zheng, L.; Hu, H. S.; Zhang, J.; et al. J. Am. Chem. Soc. 2021, 143, 9429. doi: 10.1021/jacs.1c02328 doi: 10.1021/jacs.1c02328
80. [80]
  Yan, K.; Zhang, Y.; Tu, M.; Sun, Y. Energy Fuels 2020, 34, 12703. doi: 10.1021/acs.energyfuels.0c02284 doi: 10.1021/acs.energyfuels.0c02284
81. [81]
  Lange, J. P.; Van Der Heide, E.; Van Buijtenen, J.; Price, R. ChemSusChem 2012, 5, 150. doi: 10.1002/cssc.201100648 doi: 10.1002/cssc.201100648
82. [82]
  Mariscal, R.; Maireles-Torres, P.; Ojeda, M.; Sádaba, I.; Granados, M. L. Energy Environ. Sci. 2016, 9, 1144. doi: 10.1039/C5EE02666K doi: 10.1039/C5EE02666K
83. [83]
  Caes, B. R.; Teixeira, R. E.; Knapp, K. G.; Raines, R. T. ACS Sustain. Chem. Eng. 2015, 3, 2591. doi: 10.1021/acssuschemeng.5b00473 doi: 10.1021/acssuschemeng.5b00473
84. [84]
  Ye, W.; Yang, Y.; Fang, X.; Arif, M.; Chen, X.; Yan, D. ACS Sustain. Chem Eng. 2019, 7, 18085. doi: 10.1021/acssuschemeng.9b05126 doi: 10.1021/acssuschemeng.9b05126
85. [85]
  Li, X.; Ho, B.; Lim, D. S.; Zhang, Y. Green Chem. 2017, 19, 914. doi: 10.1039/C6GC03020C doi: 10.1039/C6GC03020C
86. [86]
  Wu, H.; Song, J.; Liu, H.; Xie, Z.; Xie, C.; Hu, Y.; Huang, X.; Hua, M.; Han, B. Chem. Sci. 2019, 10, 4692. doi: 10.1039/c9sc00322c doi: 10.1039/c9sc00322c
87. [87]
  Wojcieszak, R.; Santarelli, F.; Paul, S.; Dumeignil, F.; Cavani, F.; Gonçalves, R. V. Sustain. Chem. Proc. 2015, 3, 1. doi: 10.1186/s40508-015-0034-5/ doi: 10.1186/s40508-015-0034-5/
88. [88]
  Centi, G.; Trifiro, F.; Ebner, J. R.; Franchetti, V. M. Chem. Rev. 1988, 88, 55. doi: 10.1021/cr00083a003 doi: 10.1021/cr00083a003
89. [89]
  Li, X.; Ko, J.; Zhang, Y. ChemSusChem 2018, 11, 612. doi: 10.1002/cssc.201701866 doi: 10.1002/cssc.201701866
90. [90]
  Murthy, M.; Rajamani, K. Chem. Eng. Sci. 1974, 29, 601. doi: 10.1016/0009-2509[74]80071-0 doi: 10.1016/0009-2509[74]80071-0
91. [91]
  Lan, J.; Chen, Z.; Lin, J.; Yin, G. Green Chem. 2014, 16, 4351. doi: 10.1039/C4GC00829D doi: 10.1039/C4GC00829D
92. [92]
  Guo, H.; Yin, G. J. Phys. Chem. C 2011, 115, 17516. doi: 10.1021/jp2054712 doi: 10.1021/jp2054712
93. [93]
  Shi, S.; Guo, H.; Yin, G. Catal. Commun. 2011, 12, 731. doi: 10.1016/j.catcom.2010.12.033 doi: 10.1016/j.catcom.2010.12.033
94. [94]
  Li, X.; Lan, X.; Wang, T. Catal. Today 2016, 276, 97. doi: 10.1016/j.cattod.2015.11.036 doi: 10.1016/j.cattod.2015.11.036
95. [95]
  Román, A. M.; Hasse, J. C.; Medlin, J. W.; Holewinski, A. ACS Catal. 2019, 9, 10305. doi: 10.1021/acscatal.9b02656 doi: 10.1021/acscatal.9b02656
96. [96]
  Kubota, S. R.; Choi, K.-S. ACS Sustain. Chem. Eng. 2018, 6, 9596. doi: 10.1021/acssuschemeng.8b02698 doi: 10.1021/acssuschemeng.8b02698
1. [1]
  Ruizhi Duan , Xiaomei Wang , Panwang Zhou , Yang Liu , Can Li . The role of hydroxyl species in the alkaline hydrogen evolution reaction over transition metal surfaces. Acta Physico-Chimica Sinica, 2025, 41(9): 100111-0. doi: 10.1016/j.actphy.2025.100111
2. [2]
  Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . Electrochemical CO₂ Reduction to C₂₊ Products with Ampere-Level Current on Carbon-Modified Copper Catalysts. Acta Physico-Chimica Sinica, 2025, 41(3): 2404012-0. doi: 10.3866/PKU.WHXB202404012
3. [3]
  Xinlong XU , Chunxue JING , Yuzhen CHEN . Bimetallic MOF-74 and derivatives: Fabrication and efficient electrocatalytic biomass conversion. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1545-1554. doi: 10.11862/CJIC.20250046
4. [4]
  Tongtong Zhao , Yan Wang , Shiyue Qin , Liang Xu , Zhenhua Li . New Experiment Development: Upgrading and Regeneration of Discarded PET Plastic through Electrocatalysis. University Chemistry, 2024, 39(3): 308-315. doi: 10.3866/PKU.DXHX202309003
5. [5]
  Tao Wang , Qin Dong , Cunpu Li , Zidong Wei . Sulfur Cathode Electrocatalysis in Lithium-Sulfur Batteries: A Comprehensive Understanding. Acta Physico-Chimica Sinica, 2024, 40(2): 2303061-0. doi: 10.3866/PKU.WHXB202303061
6. [6]
  Jiajie Li , Xiaocong Ma , Jufang Zheng , Qiang Wan , Xiaoshun Zhou , Yahao Wang . Recent Advances in In-Situ Raman Spectroscopy for Investigating Electrocatalytic Organic Reaction Mechanisms. University Chemistry, 2025, 40(4): 261-276. doi: 10.12461/PKU.DXHX202406117
7. [7]
  Jianchun Wang , Ruyu Xie . The Fantastical Dance of Miss Electron: Contra-Thermodynamic Electrocatalytic Reactions. University Chemistry, 2025, 40(4): 331-339. doi: 10.12461/PKU.DXHX202406082
8. [8]
  Xueting Cao , Shuangshuang Cha , Ming Gong . Interfacial Electrical Double Layer in Electrocatalytic Reactions: Fundamentals, Characterizations and Applications. Acta Physico-Chimica Sinica, 2025, 41(5): 100041-0. doi: 10.1016/j.actphy.2024.100041
9. [9]
  Xinyi Zhang , Kai Ren , Yanning Liu , Zhenyi Gu , Zhixiong Huang , Shuohang Zheng , Xiaotong Wang , Jinzhi Guo , Igor V. Zatovsky , Junming Cao , Xinglong Wu . Progress on Entropy Production Engineering for Electrochemical Catalysis. Acta Physico-Chimica Sinica, 2024, 40(7): 2307057-0. doi: 10.3866/PKU.WHXB202307057
10. [10]
  Ye Wang , Ruixiang Ge , Xiang Liu , Jing Li , Haohong Duan . An Anion Leaching Strategy towards Metal Oxyhydroxides Synthesis for Electrocatalytic Oxidation of Glycerol. Acta Physico-Chimica Sinica, 2024, 40(7): 2307019-0. doi: 10.3866/PKU.WHXB202307019
11. [11]
  Fangfang WANG , Jiaqi CHEN , Weiyin SUN . CuBi@Cu-MOF composite catalysts for electrocatalytic CO₂ reduction to HCOOH. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 97-104. doi: 10.11862/CJIC.20240350
12. [12]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
13. [13]
  Xiting Zhou , Zhipeng Han , Xinlei Zhang , Shixuan Zhu , Cheng Che , Liang Xu , Zhenyu Sun , Leiduan Hao , Zhiyu Yang . Dual Modulation via Ag-Doped CuO Catalyst and Iodide-Containing Electrolyte for Enhanced Electrocatalytic CO₂ Reduction to Multi-Carbon Products: A Comprehensive Chemistry Experiment. University Chemistry, 2025, 40(7): 336-344. doi: 10.12461/PKU.DXHX202412070
14. [14]
  Yan Kong , Wei Wei , Lekai Xu , Chen Chen . Electrochemical Synthesis of Organonitrogen Compounds from N-integrated CO₂ Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2307049-0. doi: 10.3866/PKU.WHXB202307049
15. [15]
  Wentao Xu , Xuyan Mo , Yang Zhou , Zuxian Weng , Kunling Mo , Yanhua Wu , Xinlin Jiang , Dan Li , Tangqi Lan , Huan Wen , Fuqin Zheng , Youjun Fan , Wei Chen . Bimetal Leaching Induced Reconstruction of Water Oxidation Electrocatalyst for Enhanced Activity and Stability. Acta Physico-Chimica Sinica, 2024, 40(8): 2308003-0. doi: 10.3866/PKU.WHXB202308003
16. [16]
  Qing Li , Guangxun Zhang , Yuxia Xu , Yangyang Sun , Huan Pang . P-Regulated Hierarchical Structure Ni₂P Assemblies toward Efficient Electrochemical Urea Oxidation. Acta Physico-Chimica Sinica, 2024, 40(9): 2308045-0. doi: 10.3866/PKU.WHXB202308045
17. [17]
  Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195
18. [18]
  Yanhui Guo , Li Wei , Zhonglin Wen , Chaorong Qi , Huanfeng Jiang . Recent Progress on Conversion of Carbon Dioxide into Carbamates. Acta Physico-Chimica Sinica, 2024, 40(4): 2307004-0. doi: 10.3866/PKU.WHXB202307004
19. [19]
  Haoyu Sun , Dun Li , Yuanyuan Min , Yingying Wang , Yanyun Ma , Yiqun Zheng , Hongwen Huang . Hierarchical Palladium-Copper-Silver Porous Nanoflowers as Efficient Electrocatalysts for CO₂ Reduction to C₂₊ Products. Acta Physico-Chimica Sinica, 2024, 40(6): 2307007-0. doi: 10.3866/PKU.WHXB202307007
20. [20]
  Wei Sun , Yongjing Wang , Kun Xiang , Saishuai Bai , Haitao Wang , Jing Zou , Arramel , Jizhou Jiang . CoP Decorated on Ti₃C₂T_x MXene Nanocomposites as Robust Electrocatalyst for Hydrogen Evolution Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2308015-0. doi: 10.3866/PKU.WHXB202308015

Get Citation

PDF

XML

Metrics

PDF Downloads(15)
Abstract views(957)
HTML views(172)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142