Citation: Yixuan Wang, Canhui Zhang, Xingkun Wang, Jiarui Duan, Kecheng Tong, Shuixing Dai, Lei Chu, Minghua Huang. Engineering Carbon-Chainmail-Shell Coated Co₉Se₈ Nanoparticles as Efficient and Durable Catalysts in Seawater-Based Zn-Air Batteries[J]. Acta Physico-Chimica Sinica, ;2024, 40(6): 230500. doi: 10.3866/PKU.WHXB202305004 shu

Engineering Carbon-Chainmail-Shell Coated Co₉Se₈ Nanoparticles as Efficient and Durable Catalysts in Seawater-Based Zn-Air Batteries

School of Material Science and Engineering, Ocean University of China, Qingdao 266000, Shandong Province, China

Corresponding author: Xingkun Wang, xingkunwang@163.com Minghua Huang,
Received Date: 8 May 2023
Revised Date: 26 July 2023
Accepted Date: 27 July 2023
Available Online: 10 August 2023
Fund Project: the National Natural Science Foundation of China 52261145700the National Natural Science Foundation of China 22279124the Natural Science Foundation of Shandong Province ZR2022ZD30

With the depletion of fossil fuel resources and the increasing severity of environmental pollution, it has become imperative to seek energy conversion devices with low cost, high efficiency and excellent environmental compatibility. Considering their high theoretical energy density, affordability and environmentally friendly nature, Zn-air batteries (ZABs) are regarded as promising energy storage and conversion devices. The utilization of seawater in ZABs (S-ZABs) holds great potential, given the abundance of seawater reserves, offering economic and social benefits such as reducing electrolyte costs and alleviating competition for freshwater consumption in human activities. However, the application of S-ZABs remains challenging, particularly in constructing high-performance cathode oxygen reduction reaction (ORR) catalysts that are highly resistant to Cl⁻ corrosion in seawater-based electrolytes. In this study, we have engineered an ultrathin carbon-chainmail-shell encapsulated Co₉Se₈ nanoparticles on N-doped mesoporous carbon (named as NMC-Co₉Se₈) electrocatalysts using the high-temperature selenization strategy. The ultrathin carbon-chainmail-shell on the outside improves electron transfer during the electrocatalysis and suppresses nanoparticles agglomeration. Additionally, it could act as armor for protecting the inner active site from the adsorption of corrosive Cl⁻. Benefit from this unique structure, the NMC-Co₉Se₈ catalyst exhibits excellent ORR performance, with an onset potential of 0.904 V and a half-wave potential of 0.860 V in seawater-based electrolytes. The catalyst also affords the lowest Tafel slope (35.5 mV∙dec⁻¹) and the highest kinetics current density of 9.816 mA∙cm⁻² at 0.85 V among all investigated samples. Owing to the protective effect of the ultrathin carbon-chainmail-shell on the inner active sites, the NMC-Co₉Se₈ catalyst retains 91.6% of its initial activity after continuous operation for 50000 s, surpassing the commercial Pt/C catalyst (with a current retention rate of 62.8%). More importantly, the S-ZABs based on the NMC-Co₉Se₈ catalyst deliver a high maximum power density of 172.4 mW∙cm⁻² and a high specific capacity of 643.9 mAh∙g⁻¹, exceeding those of S-ZABs powered by the commercial Pt/C catalyst (151.2 mW∙cm⁻² and 548.3 mAh∙g⁻¹). Furthermore, the S-ZABs driven by the NMC-Co₉Se₈ catalyst demonstrate a discharge stability for up to 150 h and maintain a stable charge-discharge cycle stability over 200 h, demonstrating the practical application performance of the NMC-Co₉Se₈ catalyst. In practical applications, the S-ZABs driven by the NMC-Co₉Se₈ catalyst can illuminate a light-emitting diode (LED) with a driving voltage of 2 V for several hours. This work provides new ideas for developing efficient and durable catalysts with high Cl⁻ corrosion resistance for applications in seawater-based Zn-air batteries and other energy conversion technologies.
- Co₉Se₈ nanoparticle,
- Oxygen reduction reaction,
- Ultrathin carbon-chainmail-shell,
- Seawater-based Zn-air battery,
- Cl^- corrosion-resistant
1. [1]
  Wang, Y.; Wu, J.; Tang, S.; Yang, J.; Ye, C.; Chen, J.; Lei, Y.; Wang, D. Angew. Chem. Int. Ed. 2023, 62, 202219191. doi: 10.1002/anie.202219191 doi: 10.1002/anie.202219191
2. [2]
  Yao, H.; Wang, X.; Li, K.; Li, C.; Zhang, C.; Zhou, J.; Cao, Z.; Wang, H.; Gu, M.; Huang, M.; et al. Appl. Catal. B-Environ. 2022, 312, 121378. doi: 10.1016/j.apcatb.2022.121378 doi: 10.1016/j.apcatb.2022.121378
3. [3]
  Zhou, J.; Han, Z.; Wang, X.; Gai, H.; Chen, Z.; Guo, T.; Hou, X.; Xu, L.; Hu, X.; Huang, M.; et al. Adv. Funct. Mater. 2021, 31, 2102066. doi: 10.1002/adfm.202102066 doi: 10.1002/adfm.202102066
4. [4]
  Zhu, P.; Xiong, X.; Wang, D. Nano Res. 2022, 15, 5792. doi: 10.1007/s12274-022-4265-y doi: 10.1007/s12274-022-4265-y
5. [5]
  Zhao, C. X.; Liu, J. N.; Wang, J.; Ren, D.; Yu, J.; Chen, X.; Li, B. Q.; Zhang, Q. Adv. Mater. 2021, 33, 2008606. doi: 10.1002/adma.202008606 doi: 10.1002/adma.202008606
6. [6]
  Han, A.; Wang, X.; Tang, K.; Zhang, Z.; Ye, C.; Kong, K.; Hu, H.; Zheng, L.; Jiang, P.; Zhao, C.; et al. Angew. Chem. Int. Ed. 2021, 60, 19262. doi: 10.1002/anie.202105186 doi: 10.1002/anie.202105186
7. [7]
  Jing, H.; Zhu, P.; Zheng, X.; Zhang, Z.; Wang, D.; Li, Y. Adv. Powder Mater. 2022, 1, 100013. doi: 10.1016/j.apmate.2021.10.004 doi: 10.1016/j.apmate.2021.10.004
8. [8]
  Wang, Y.; Wan, X.; Liu, J.; Li, W.; Li, Y.; Guo, X.; Liu, X.; Shang, J.; Shui, J. Nano Res. 2022, 15, 3082. doi: 10.1007/s12274-021-3966-y doi: 10.1007/s12274-021-3966-y
9. [9]
  Xiong, Y.; Li, H.; Liu, C.; Zheng, L.; Liu, C.; Wang, J. O.; Liu, S.; Han, Y.; Gu, L.; Qian, J.; et al. Adv. Mater. 2022, 34, 2110653. doi: 10.1002/adma.202110653 doi: 10.1002/adma.202110653
10. [10]
  Zhang, C.; Wang, X.; Song, K.; Chen, K.; Dai, S.; Wang, H.; Huang, M. Nano Res. 2023, 16, 1. doi: 10.1007/s12274-023-5578-1 doi: 10.1007/s12274-023-5578-1
11. [11]
  Zhang, J.; Zhou, Q.; Tang, Y.; Zhang, L.; Li, Y. Chem. Sci. 2019, 10, 8924. doi: 10.1039/c9sc04221k doi: 10.1039/c9sc04221k
12. [12]
  Wang, T.; Wu, J.; Liu, Y.; Cui, X.; Ding, P.; Deng, J.; Zha, C.; Coy, E.; Li, Y. Energy Storage Mater. 2019, 16, 24. doi: 10.1016/j.ensm.2018.04.020 doi: 10.1016/j.ensm.2018.04.020
13. [13]
  Cui, B.; Shi, Y.; Li, G.; Chen, Y.; Chen, W.; Deng, Y.; Hu, W. Acta Phys. -Chim. Sin. 2021, 38, 2106010. doi: 10.3866/PKU.WHXB202106010
14. [14]
  Zhang, Y. X.; Zhang, S.; Huang, H.; Liu, X.; Li, B.; Lee, Y.; Wang, X.; Bai, Y.; Sun, M.; Wu, Y.; et al. J. Am. Chem. Soc. 2023, 145, 4819. doi: 10.1021/jacs.2c13886 doi: 10.1021/jacs.2c13886
15. [15]
  Pan, Y.; Li, M.; Mi, W.; Wang, M.; Li, J.; Zhao, Y.; Ma, X.; Wang, B.; Zhu, W.; Cui, Z.; et al. Nano Res. 2022, 15, 7976. doi: 10.1007/s12274-022-4502-4 doi: 10.1007/s12274-022-4502-4
16. [16]
  Yu, Y.; Xia, F.; Wang, C.; Wu, J.; Fu, X.; Ma, D.; Lin, B.; Wang, J.; Yue, Q.; Kang, Y. Nano Res. 2022, 15, 7868. doi: 10.1007/s12274-022-4432-1 doi: 10.1007/s12274-022-4432-1
17. [17]
  Li, W. H.; Yang, J.; Wang, D. Angew. Chem. Int. Ed. 2022, 61, 202213318. doi: 10.1002/anie.202213318 doi: 10.1002/anie.202213318
18. [18]
  Cai, C.; Liu, K.; Zhu, Y.; Li, P.; Wang, Q.; Liu, B.; Chen, S.; Li, H.; Zhu, L.; Li, H.; et al. Angew. Chem. Int. Ed. 2022, 61, 202113664. doi: 10.1002/anie.202113664 doi: 10.1002/anie.202113664
19. [19]
  Luo, M.; Zhao, Z.; Zhang, Y.; Sun, Y.; Xing, Y.; Lv, F.; Yang, Y.; Zhang, X.; Hwang, S.; Qin, Y.; et al. Nature 2019, 574, 81. doi: 10.1038/s41586-019-1603-7 doi: 10.1038/s41586-019-1603-7
20. [20]
  Zhou, M.; Guo, J.; Zhao, B.; Li, C.; Zhang, L.; Fang, J. J. Am. Chem. Soc. 2021, 143, 15891. doi: 10.1021/jacs.1c08644 doi: 10.1021/jacs.1c08644
21. [21]
  Liu, Z.; Du, Y.; Yu, R.; Zheng, M.; Hu, R.; Wu, J.; Xia, Y.; Zhuang, Z.; Wang, D. Angew. Chem. Int. Ed. 2022, 62, 202212653. doi: 10.1002/anie.202212653 doi: 10.1002/anie.202212653
22. [22]
  Yu, J.; Li, B. Q.; Zhao, C. X.; Zhang, Q. Energy Environ. Sci. 2020, 13, 3253. doi: 10.1039/d0ee01617a doi: 10.1039/d0ee01617a
23. [23]
  Yu, J.; Zhao, C. X.; Liu, J. N.; Li, B. Q.; Tang, C.; Zhang, Q. Green Chem. Eng. 2020, 1, 117. doi: 10.1016/j.gce.2020.09.013 doi: 10.1016/j.gce.2020.09.013
24. [24]
  Cui, X.; Ren, P.; Deng, D.; Deng, J.; Bao, X. Energy Environ. Sci. 2016, 9, 123. doi: 10.1039/c5ee03316k doi: 10.1039/c5ee03316k
25. [25]
  Xiao, Y.; Pei, Y.; Hu, Y.; Ma, R.; Wang, D.; Wang, J. Acta Phys. -Chim. Sin. 2020, 37, 2009051. doi: 10.3866/PKU.WHXB202009051
26. [26]
  Zang, Y.; Liu, T.; Wei, P.; Li, H.; Wang, Q.; Wang, G.; Bao, X. Angew. Chem. Int. Ed. 2022, 134, 202209629. doi: 10.1002/anie.202209629 doi: 10.1002/anie.202209629
27. [27]
  Zheng, X.; Yang, J.; Xu, Z.; Wang, Q.; Wu, J.; Zhang, E.; Dou, S.; Sun, W.; Wang, D.; Li, Y. Angew. Chem. Int. Ed. 2022, 61, 202205946. doi: 10.1002/anie.202205946 doi: 10.1002/anie.202205946
28. [28]
  Kim, S.; Ji, S.; Yang, H.; Son, H.; Choi, H.; Kang, J.; Li, O. L. Appl. Catal. B-Environ. 2022, 310, 121361. doi: 10.1016/j.apcatb.2022.121361 doi: 10.1016/j.apcatb.2022.121361
29. [29]
  Suh, D. H.; Park, S. K.; Nakhanivej, P.; Kim, Y.; Hwang, S. M.; Park, H. S. J. Power Sources 2017, 372, 31. doi: 10.1016/j.jpowsour.2017.10.056 doi: 10.1016/j.jpowsour.2017.10.056
30. [30]
  Ren, W.; Wang, Y.; Zhang, Z.; Tan, Q.; Zhong, Z.; Su, F. J. Mater. Chem. A 2016, 4, 552. doi: 10.1039/C5TA07487H doi: 10.1039/C5TA07487H
31. [31]
  Huang, S.; Zhao, Z.; Wei, Z.; Wang, M.; Chen, Y.; Wang, X.; Shao, F.; Zhong, X.; Li, X.; Wang, J. Green Chem. 2022, 24, 6945. doi: 10.1039/D2GC02161G doi: 10.1039/D2GC02161G
32. [32]
  Jiang, X.; Yan, X.; Hu, X.; Feng, R.; Li, T.; Wang, L. Sep. Purif. Technol. 2022, 297, 121400. doi: 10.1016/j.seppur.2022.121400 doi: 10.1016/j.seppur.2022.121400
33. [33]
  Du, C.; Li, P.; Zhuang, Z.; Fang, Z.; He, S.; Feng, L.; Chen, W. Coord. Chem. Rev. 2022, 466, 214604. doi: 10.1016/j.ccr.2022.214604 doi: 10.1016/j.ccr.2022.214604
34. [34]
  Jhong, H. P.; Chang, S. T.; Huang, H. C.; Wang, K. C.; Lee, J. F.; Yasuzawa, M.; Wang, C. Catal. Sci. Technol. 2019, 9, 3426. doi: 10.1039/C9CY00854C doi: 10.1039/C9CY00854C
35. [35]
  Li, K.; Cheng, R.; Xue, Q.; Meng, P.; Zhao, T.; Jiang, M.; Guo, M.; Li, H.; Fu, C. Chem. Eng. J. 2022, 450, 137991. doi: 10.1016/j.cej.2022.137991 doi: 10.1016/j.cej.2022.137991
36. [36]
  Nekooi, P.; Akbari, M.; Amini, M. K. Int. J. Hydrog. Energy 2010, 35, 6392. doi: 10.1016/j.ijhydene.2010.03.134 doi: 10.1016/j.ijhydene.2010.03.134
37. [37]
  Meng, T.; Qin, J.; Wang, S.; Zhao, D.; Mao, B.; Cao, M. J. Mater. Chem. A 2017, 5, 7001. doi: 10.1039/c7ta01453h doi: 10.1039/c7ta01453h
38. [38]
  Wu, R.; Xue, Y.; Liu, B.; Zhou, K.; Wei, J.; Chan, S. H. J. Power Sources 2016, 330, 132. doi: 10.1016/j.jpowsour.2016.09.001 doi: 10.1016/j.jpowsour.2016.09.001
39. [39]
  Chen, K.; Wang, X.; Zhang, C.; Xu, R.; Wang, H.; Chu, L.; Huang, M. Mater. Today Energy 2022, 30, 101150. doi: 10.1016/j.mtener.2022.101150 doi: 10.1016/j.mtener.2022.101150
40. [40]
  Yuan, Q.; Zhao, J.; Mok, D. H.; Zheng, Z.; Ye, Y.; Liang, C.; Zhou, L.; Back, S.; Jiang, K. Nano Lett. 2022, 22, 1257. doi: 10.1021/acs.nanolett.1c04420 doi: 10.1021/acs.nanolett.1c04420
41. [41]
  Jin, H.; Xu, Z.; Hu, Z. Y.; Yin, Z.; Wang, Z.; Deng, Z.; Wei, P.; Feng, S.; Dong, S.; Liu, J.; et al. Nat. Commun. 2023, 14, 1518. doi: 10.1038/s41467-023-37268-4 doi: 10.1038/s41467-023-37268-4
42. [42]
  Deng, J.; Ren, P.; Deng, D.; Bao, X. Angew. Chem. Int. Ed. 2015, 54, 2100. doi: 10.1002/anie.201409524 doi: 10.1002/anie.201409524
43. [43]
  Song, X. R.; Wang, X.; Yu, S. X.; Cao, J.; Li, S. H.; Li, J.; Liu, G.; Yang, H. H.; Chen, X. Adv. Mater. 2015, 27, 3285. doi: 10.1002/adma.201405634 doi: 10.1002/adma.201405634
44. [44]
  Wang, X.; Kong, D.; Huang, Z. X.; Wang, Y.; Yang, H. Y. Small 2017, 13. 1603980. doi: 10.1002/smll.201603980 doi: 10.1002/smll.201603980
45. [45]
  Xia, C.; Qiu, Y.; Xia, Y.; Zhu, P.; King, G.; Zhang, X.; Wu, Z.; Kim, J. Y.; Cullen, D. A.; Zheng, D.; et al. Nat. Chem. 2021, 13, 887. doi: 10.1038/s41557-021-00734-x doi: 10.1038/s41557-021-00734-x
46. [46]
  Hu, H.; Zhang, J.; Guan, B.; Lou, X. W. Angew. Chem. Int. Ed. 2016, 55, 9514. doi: 10.1002/anie.201603852 doi: 10.1002/anie.201603852
47. [47]
  Hou, L.; Sun, X.; Guo, L.; Meng, X.; Wei, J.; Yuan, C. Energy Technol. 2019, 8, 1901319. doi: 10.1002/ente.201901319 doi: 10.1002/ente.201901319
48. [48]
  Zhou, X.; Gao, J.; Hu, Y.; Jin, Z.; Hu, K.; Reddy, K. M.; Yuan, Q.; Lin, X.; Qiu, H. J. Nano Lett. 2022, 22, 3392. doi: 10.1021/acs.nanolett.2c00658 doi: 10.1021/acs.nanolett.2c00658
49. [49]
  Ba, E. C. T.; Dumont, M. R.; Martins, P. S.; da Silva Pinheiro, B.; da Cruz, M. P. M.; Barbosa, J. W. Diam. Relat. Mat. 2022, 122, 108818. doi: 10.1016/j.diamond.2021.108818 doi: 10.1016/j.diamond.2021.108818
50. [50]
  Song, J.; Chen, Y.; Huang, H.; Wang, J.; Huang, S. C.; Liao, Y. F.; Fetohi, A. E.; Hu, F.; Chen, H. Y.; Li, L.; et al. Adv. Sci. 2022, 9, 2104522. doi: 10.1002/advs.202104522 doi: 10.1002/advs.202104522
51. [51]
  Sheng, J.; Sun, S.; Jia, G.; Zhu, S.; Li, Y. ACS Nano 2022, 16, 15994. doi: 10.1021/acsnano.2c03565 doi: 10.1021/acsnano.2c03565
52. [52]
  Wang, J.; Li, H.; Liu, S.; Hu, Y.; Zhang, J.; Xia, M.; Hou, Y.; Tse, J.; Zhang, J.; Zhao, Y. Angew. Chem. Int. Ed. 2021, 60, 181. doi: 10.1002/anie.202009991 doi: 10.1002/anie.202009991
53. [53]
  Wang, X.; Zhou, X.; Li, C.; Yao, H.; Zhang, C.; Zhou, J.; Xu, R.; Chu, L.; Wang, H.; Gu, M.; et al. Adv. Mater. 2022, 34, 2204021. doi: 10.1002/adma.202204021 doi: 10.1002/adma.202204021
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Engineering Carbon-Chainmail-Shell Coated Co9Se8 Nanoparticles as Efficient and Durable Catalysts in Seawater-Based Zn-Air Batteries

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Engineering Carbon-Chainmail-Shell Coated Co₉Se₈ Nanoparticles as Efficient and Durable Catalysts in Seawater-Based Zn-Air Batteries