RuP Nanoparticles Anchored on N-doped Graphene Aerogels for Hydrazine Oxidation-Boosted Hydrogen Production

Citation: Zheng-Min Wang, Qing-Ling Hong, Xiao-Hui Wang, Hao Huang, Yu Chen, Shu-Ni Li. RuP Nanoparticles Anchored on N-doped Graphene Aerogels for Hydrazine Oxidation-Boosted Hydrogen Production[J]. Acta Physico-Chimica Sinica, 2023, 39(12): 230302. doi: 10.3866/PKU.WHXB202303028 shu

氮掺杂石墨烯气凝胶锚定RuP纳米粒子用于水合肼氧化辅助产氢

王正慜 ^1, ,
洪庆玲 ^2, ,
王晓慧 ^1, ,
黄昊 ^{3,
,} ,
陈煜 ^{2,
,} ,
李淑妮 ^{1,
,}

1.
陕西师范大学化学化工学院, 陕西省大分子科学重点实验室, 西安 710062
2.
陕西师范大学材料科学与工程学院, 西安 710062
3.
挪威东南大学微系统系, 博尔 3184, 挪威

通讯作者: 黄昊, huanghao881015@163.com
陈煜, ndchenyu@gmail.com
李淑妮, lishuni@snnu.edu.cn

基金项目:
国家自然科学基金 21972089

国家自然科学基金 22002083

陕西省创新能力支撑计划 2023-CX-TD-27

中央高校基本科研业务费 GK202202001

摘要: 氢能是替代传统燃料的理想清洁能源。电解水析氢由于其环保和低成本的特性而受到广泛关注，然而，阳极析氧反应(OER)的缓慢动力学降低了制氢效率。因此，肼氧化反应(HzOR)以其低的理论电压电位(−0.33 V vs. RHE)成为了OER的合理替代方案。本工作中，以三维多孔的石墨烯气凝胶(GA)为导电基底，将Ru^Ⅲ-聚乙烯亚胺(Ru^Ⅲ-PEI)配合物吸附在GA表面。通过植酸(PA)和PEI之间的氢键相互作用GA进一步吸附PA，形成Ru^Ⅲ-PEI-GA-PA复合物。对Ru^Ⅲ-PEI-GA-PA复合物前驱体进行磷化后，合成了锚定在N掺杂GA上的RuP纳米粒子(RuP/N-GA)。在热解过程中，在GA表面形成了超小的RuP纳米粒子。此外，PEI和PA的分解可以将丰富的N和P杂原子引入GA的结构中。因此，RuP/N-GA复合物具有高效的HzOR性能，在10 mA∙cm⁻²时的工作电位低至−54 mV。此外，这种低Ru负载的新型RuP/N-GA复合物具有良好的析氢反应(HER)活性，电流密度为10 mA∙cm⁻²时的HER过电势为−19.6 mV。在各种RuP/N-GA复合物中，RuP/N-GA-900具有最小的HER塔菲尔斜率(37.03 mV∙dec⁻¹)，表现出了最快的HER动力学。同时也表明RuP/N-GA-900的HER过程具有与Pt类似的Heyrovsky机制。理论计算结果表明，锚定结构和N杂原子的存在可以促进肼在RuP纳米粒子上的氧化。肼分子吸附在RuP/N-GA上的自由能为−0.68 eV，表明掺杂的N可以调节Ru活性位点的电子结构，有助于增强Ru的HzOR活性。此外，RuP/N-GA复合物对HER和HzOR均表现出优于商业Pt/C的循环稳定性和长期稳定性。基于RuP/N-GA复合物的双功能活性，所构建的双电极肼分解系统在10 mA∙cm⁻²下表现出41 mV的极低分解电压就可以产氢，实现了低电压下节能制氢的目标。RuP/N-GA复合物优异的电催化活性归因于超小的RuP纳米粒子提供了丰富的Ru活性位点。此外，GA骨架中N的掺杂与RuP纳米颗粒之间的协同效应有助于提高RuP/N-GA复合物的活性。三维多孔的N-GA加速了电荷转移和传质过程，并且N-GA和RuP纳米粒子之间的相互作用增强了RuP纳米粒子对HER和HzOR的电催化活性。这项工作提出了一种HzOR辅助制氢的双功能电催化剂，并为通过吸附-磷化法设计和合成先进电催化剂提供了新思路。

关键词:

English

RuP Nanoparticles Anchored on N-doped Graphene Aerogels for Hydrazine Oxidation-Boosted Hydrogen Production

Zheng-Min Wang ^1, ,
Qing-Ling Hong ^2, ,
Xiao-Hui Wang ^1, ,
Hao Huang ^{3,
,} ,
Yu Chen ^{2,
,} ,
Shu-Ni Li ^{1,
,}

1.
Key Laboratory of Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710062, China
2.
School of Materials Science and Engineering, Shaanxi Normal University, Xi'an 710062, China
3.
Department of Microsystems, University of South-Eastern Norway, Borre 3184, Norway

Corresponding author: Hao Huang, huanghao881015@163.com Yu Chen, ndchenyu@gmail.com Shu-Ni Li, lishuni@snnu.edu.cn

Received Date: 13 March 2023
Accepted Date: 04 April 2023
Revised Date: 03 April 2023
Available Online: 15 December 2023
Fund Project:

Abstract: 'Green hydrogen' is a promising clean energy carrier for use instead of traditional fuels. For obtaining 'green hydrogen', electrochemical water splitting has been receiving considerable attention due to its eco-friendly and low-cost properties. However, the sluggish kinetics of the anodic oxygen evolution reaction (OER) reduces the efficiency of hydrogen production. Accordingly, the hydrazine oxidation reaction (HzOR) with low theoretical potential (−0.33 V vs. RHE) has been proposed as a reasonable alternative for the OER. In this study, graphene aerogel (GA) was utilized as a conductive substrate with a 3D porous framework. Ru^Ⅲ-polyethyleneimine (Ru^Ⅲ-PEI) complexes were adsorbed on the GA surface. Phytic acid (PA) was further adsorbed to form Ru^Ⅲ-PEI-GA-PA hybrids through the hydrogen bond interaction between PA and PEI, which can serve as a precursor to synthesize RuP nanoparticles anchored on N-doped GA (RuP/N-GA) through the phosphorization reaction. In the pyrolysis process, the ultra-small RuP was formed at the GA surface. Additionally, the decomposition of PEI and PA can introduce abundant N and P heteroatoms into the structure of GA. As a result, RuP/N-GA hybrids achieve efficient HzOR with a low working potential of −54 mV at 10 mA∙cm⁻². Moreover, the novel RuP/N-GA hybrids with low Ru loading also exhibit a promising hydrogen evolution reaction (HER) activity with an overpotential of −19.6 mV at 10 mA∙cm⁻². Among various RuP/N-GA hybrids, the Tafel plot of HER at RuP/N-GA-900 reveals the smallest value to be 37.03 mV∙dec⁻¹, which affords the fastest HER kinetics. Meanwhile, the result suggests that the HER at RuP/N-GA-900 undergoes a Heyrovsky mechanism similar to that of Pt. The theoretical results revealed that the anchored structure and the presence of N heteroatoms can promote the HzOR on RuP nanoparticles. The free energy of hydrazine molecular adsorption on RuP/N-GA was −0.68 eV, indicating that N-doping in the RuP/N-GA structure can adjust the electronic structure of the Ru active site, which also contributes to the enhanced HzOR activity of the Ru site. Additionally, RuP/N-GA hybrids exhibited excellent cycling and long-term stability for both HER and HzOR, superior to those of commercial Pt/C. Based on the bifunctional activity of RuP/N-GA hybrids, the constructed two-electrode hydrazine split system exhibits an extremely low cell voltage of 41 mV at 10 mA∙cm⁻² for the hydrogen production, which achieves the goal of energy-saved hydrogen production at low voltage. The excellent electrocatalytic activity of RuP/N-GA hybrids is attributed to the ultrasmall RuP nanoparticles for abundant Ru active sites. Meanwhile, the synergistic effect between N-doping in GA frameworks with RuP nanoparticles contributes to the activity enhancement of RuP/N-GA hybrids, in which the 3D porous N-GA with few-layer morphology accelerates the electron and mass transfer and the electron interaction between N-GA and RuP nanoparticles promotes the electrocatalytic activity of RuP nanoparticles for both HER and HzOR. This study extends the bifunctional electrocatalyst for the HER and HzOR to achieve energy-saved hydrogen production and sheds new light on the design and synthesis of advanced electrocatalysts via the adsorption-phosphatization method.

Key words:

1. [1]
  高增强, 王聪勇, 李俊俊, 朱亚廷, 张志成, 胡文平. 物理化学学报, 2021, 37, 2010025. doi: 10.3866/PKU.WHXB202010025Gao, Z. Q.; Wang, C. Y.; Li, J. J.; Zhu, Y. T.; Zhang, Z. C.; Hu, W. P. Acta Phys. -Chim. Sin. 2021, 37, 2010025. doi: 10.3866/PKU.WHXB202010025
2. [2]
  Wang, T. J.; Jiang, Y. C.; He, J. W.; Li, F. M.; Ding, Y.; Chen, P.; Chen, Y. Carbon Energy 2022, 4, 283. doi: 10.1002/cey2.170
3. [3]
  Hong, Q. L.; Miao, B. Q.; Wang, T. J.; Li, F. M.; Chen, Y.; Energy Lab. 2023, 1, 220022. doi: 10.54227/elab.20220022
4. [4]
  秦睿, 王鹏彦, 林灿, 曹菲, 张金咏, 陈磊, 木士春. 物理化学学报, 2021, 37, 2009099. doi: 10.3866/PKU.WHXB202009099Qin, R.; Wang, P. Y.; Lin, C.; Cao, F.; Zhang, J. Y.; Chen, L.; Mu S. C. Acta Phys. -Chim. Sin. 2021, 37, 2009099. doi: 10.3866/PKU.WHXB202009099
5. [5]
  雷卓楠, 马心怡, 胡晓云, 樊君, 刘恩周. 物理化学学报, 2022, 38, 2110049. doi: 10.3866/PKU.WHXB202110049Lei, Z. N.; Ma, X. Y.; Hu, X. Y.; Fan, J.; Liu, E. Z. Acta Phys. -Chim. Sin. 2022, 38, 2110049. doi: 10.3866/PKU.WHXB202110049
6. [6]
  Xue, Q.; Bai, X. Y.; Zhao, Y.; Li, Y. N.; Wang, T. J.; Li, Y. N.; Sun, H. Y.; Li, F. M.; Chen, P.; Jin, P. J.; Yin, S. B.; et al. J. Energy Chem. 2022, 65, 94. doi: 10.1016/j.jechem.2021.05.034
7. [7]
  Song, W.; Li, M.; Wang, C.; Lu, X. Carbon Energy 2021, 3, 101. doi: 10.1002/cey2.85
8. [8]
  Zhao, T. W.; Wang, Y.; Karuturi, S.; Catchpole, K.; Zhang, Q.; Zhao, C. Carbon Energy 2020, 2, 582. doi: 10.1002/cey2.79
9. [9]
  刘源, 李卫东, 吴捍, 卢思宇. 物理化学学报, 2021, 37, 2009082. doi: 10.3866/PKU.WHXB202009082Liu, Y.; Li, W. D.; Wu, H.; Lu, S. Y. Acta Phys. -Chim. Sin. 2021, 37, 2009082. doi: 10.3866/PKU.WHXB202009082
10. [10]
  Hu, Q.; Gao, K.; Wang, X.; Zheng, H. J.; Cao, J. G.; Mi, L. R.; Huo, Q. H.; Yang, H. P.; Liu, J. H.; He, C. X. Nat. Commun. 2022, 13, 3958. doi: 10.1038/s41467-022-31660-2
11. [11]
  Li, C.; Jang, H.; Kim, M. G.; Hou, L.; Liu, X.; Cho, J. Appl. Catal. B 2022, 307, 121204. doi: 10.1016/j.apcatb.2022.121204
12. [12]
  Ding, Y.; Cao, K. W.; He, J. W.; Li, F. M.; Huang, H.; Chen, P.; Chen, Y. Chin. J. Catal. 2022, 43, 1535. doi: 10.1016/S1872-2067(21)63977-3
13. [13]
  Zhang, F.; Zhu, Y. L.; Chen, Y.; Lu, Y.; Lin, Q.; Zhang L.; Tao, S. W.; Zhang, X. W.; Wang, H. T. J. Mater. Chem. A 2020, 8, 12810. doi: 10.1039/D0TA04491A
14. [14]
  Chang, Q. B.; Ma, J. W.; Zhu, Y. Z.; Li, Z.; Xu, D. Y.; Duan, X. Z.; Peng, W. C.; Li, Y.; Zhang, G.L.; Zhang, F. B. ACS Sustain. Chem. Eng. 2018, 6, 6388. doi: 10.1021/acssuschemeng.8b00187
15. [15]
  Chi, J. Q.; Gao, W. K.; Lin, J. H.; Dong, B.; Yan, K. L.; Qin, J. F.; Liu, Bin.; Chai, Y. M.; Liu, C.G. ChemSusChem 2018, 11, 743. doi: 10.1002/cssc.201702010
16. [16]
  Guo, L.; Luo, F.; Guo, F.; Zhang, Q.; Qu, K.; Yang, Z. H.; Cai, W. W. Chem. Commun. 2019, 55, 7623. doi: 10.1039/C9CC03675J
17. [17]
  Li, Y.; Luo, Y.; Zhang, Z. Q.; Yu, Li, C. Zhang, Q.; Zheng, Z.; Liu, H. K.; Liu, B. L.; Dou, S. X. Carbon 2021, 183, 362. doi: 10.1016/j.carbon.2021.07.039
18. [18]
  Chen, Y. J.; Li, J.; Wang, N.; Zhou, Y. N.; Zheng, J.; Chu, W. J. Energy Chem. 2022, 448, 137611. doi: 10.1016/j.cej.2022.137611
19. [19]
  Zhu, Y.; Zhang, J.; Qian, Q.; Li, Y.; Li, Z.; Liu, Y.; Xiao, C.; Zhang, G. Q.; Xie Y. Angew. Chem. Int. Ed. 2022, 61, e202113082. doi: 10.1002/anie.202113082
20. [20]
  Qian, Q. Z.; Zhang, J. H.; Li, J. M.; Li, Y. P.; Jin, X.; Zhu, Y.; Liu, Y.; Li, Z. Y.; El-Harairy, A.; Xiao, C.; Zhang G. Q.; Xie, Y. Angew. Chem. Int. Ed. 2021, 60, 5984. doi: 10.1002/anie.202014362
21. [21]
  Wang, Z.; Xu, L.; Huang, F.; Qu, L.; Li, J.; Owusu, K. A.; Liu, Z. A.; Lin, Z. F.; Xiang, B. H.; Liu, X. Adv. Energy Mater. 2019, 9, 1900390. doi: 10.1002/aenm.201900390
22. [22]
  Liu, Y.; Zhang, J.; Li, Y.; Qian, Li, Q. Z.; Zhu, Y.; Zhang G. Q. Nat. Commun. 2020, 11, 1853. doi: 10.1038/s41467-020-15563-8
23. [23]
  Cui, S. F.; Wu, W.; Liu, C.; Wang, Y.; Chen, Q. M.; Liu, X. R. Nanoscale 2021, 13, 18247. doi: 10.1039/D1NR04075H
24. [24]
  Xue, Q.; Ding, Y.; Xue, Y. Y.; Li, F. M.; Chen, P.; Chen, Y. Carbon 2018, 139, 137. doi: 10.1016/j.Carbon.2018.06.052
25. [25]
  Wang, Y. H.; Li, R. Q.; Li, H. B.; Huang, H. L.; Guo, Z. J.; Chen, H. Y.; Zheng, Y.; Qu, K. G. Rare Metals 2021, 40, 1040. doi: 10.1007/s12598-020-01665-1
26. [26]
  Primo, A.; Neatu, F.; Florea, M.; Parvulescu, V.; Garcia, H. Nat. Commun. 2014, 5, 5291. doi: 10.1038/ncomms6291
27. [27]
  Ge, R.; Wang, S.; Su, J.; Dong, Y.; Lin, Y.; Zhang, Q.; Chen, L. Nanoscale 2018, 10, 13930. doi: 10.1039/C8NR03554G
28. [28]
  Li, Y.; Sun, Y.; Qin, Y.; Zhang, W.; Wang, L.; Luo, M. H.; Yang, H.; Guo, S. Adv. Energy Mater. 2020, 10, 1903120. doi: 10.1002/aenm.201903120
29. [29]
  Li, Y.; Chu, F.; Liu, Y.; Kong, Y.; Tao, Y.; Li, Y.; Qin, Y. Chem. Commun. 2018, 54, 13076. doi: 10.1039/C8CC08276F
30. [30]
  Kweon, D. H.; Okyay, M. S.; Kim, S. J.; Jeon, J. P.; Noh, H. J.; Park, N.; Mahmood, J.; Baek, J. B. Nat. Commun. 2020, 11, 1278. doi: 10.1038/s41467-020-15069-3
31. [31]
  Sun, H. C.; Yang, J. M.; Li, J. G.; Li, Z. S.; Ao, X.; Liu, Y. Z.; Zhang, Y.; Li, Y.; Wang, C.; Tang, H. Appl. Catal. B 2020, 272, 118988. doi: 10.1016/j.apcatb.2020.118988
32. [32]
  Zhao, Y. M.; Wang, X. W.; Cheng, G. Z.; Luo, W. ACS Catal. 2020, 10, 11751. doi: 10.1021/acscatal.0c03148
33. [33]
  Liu, X.; Liu, F.; Yu, J.; Xiong, G.; Zhao, L.; Sang, Y.; Zuo, S.; Zhang, J.; Liu, H.; Zhou, W. Adv. Sci. 2020, 7, 2001526. doi: 10.1002/advs.202001526
34. [34]
  Guo, J. X.; Yan, D. Y.; Qiu, K. W.; Mu, C.; Jiao, D.; Wang, H.; Lin, T. J. Energy Chem. 2019, 37, 143. doi: 10.1016/j.jechem.2018.12.011
35. [35]
  Xu, J.; Wang, S. I.; Yang, C. L.; Li, T. T.; Liu, Q. C.; Kong, X. Chem. Eng. J. 2021, 421, 129741. doi: 10.1016/j.cej.2021.129741
36. [36]
  Muthurasu, A.; Chhetri, K.; Dahal, B.; Kim, H. Y. Nanoscale 2022, 14, 6557. doi: 10.1039/D2NR00060A
37. [37]
  Yang, Q.; Zhu, B.; Wang, F.; Zhang, C.; Cai, J. J. Nano Res. 2022, 15, 5134. doi: 10.1007/s12274-022-4148-2
38. [38]
  Li, J.; Zhang, C.; Zhang, C.; Ma, H.; Yang, Y.; Guo, Z.; Wang, Y.; Ma, H. Chem. Eng. J. 2022, 430, 132953. doi: 10.1016/j.cej.2021.132953
39. [39]
  Wang, J.; Guan, X.; Li, H.; Zeng, S.; Li, R.; Yao, Q.; Chen, H.; Zheng, Y.; Qu, K. Nano Energy, 2022, 100, 107467. doi: 10.1016/j.nanoen.2022.107467
40. [40]
  Li, Y.; Zhang, J.; Liu, Y.; Qian, Q.; Li, Z.; Zhu, Y.; Zhang, G. Sci. Adv. 2020, 6, 131099. doi: 10.1126/sciadv.abb4197
41. [41]
  Yang, Q. F.; Cui, Y. C.; Li, Q. Y.; Cai, J. H.; Wang, D.; Feng L. Chem. Eng. 2020, 8, 12089. doi: 10.1021/acssuschemeng.0c03410
42. [42]
  Li, Y.; Wang, W.; Cheng, M.; Qian, Q.; Zhu, Y.; Zhang, G. Catal. Sci. Technol. 2022, 12, 6258. doi: 10.1039/D2CY00055E
43. [43]
  Wang, H.; Tao, S. Nanoscale Adv. 2021, 3, 2280. doi: 10.1039/D1NA00043H
44. [44]
  Zhou, B.; Li, M. Y.; Li, Y. Y.; Liu, Y. B.; Lu, Y. X.; Li, W.; Wu, Y. J.; Huo, J.; Wang, Y. Y.; Tao, L.; Wang, S. Y. Chin. J. Catal. 2022, 43, 1131. doi: 10.1016/S1872-2067(21)63951-7
45. [45]
  Ao, Y.; Chen, S.; Wang, C.; Lu, X. J. Colloid Interface Sci. 2021, 601, 495. doi: 10.1016/j.jcis.2021.05.119
46. [46]
  Chen, S.; Wang, C.; Liu, S.; Huang, M.; Lu, J. J. Phys. Chem. Lett. 2021, 12, 4849. doi: 10.1021/acs.jpclett.1c00963
47. [47]
  Zhang, J.; Liu, Y.; Li, J.; Jin, X.; Li, Y.; Qian, Q.; Wang, Y.; El-Harairy, A.; Li, Z.; Zhu, Y. et al. ACS Appl. Mater. Interfaces 2021, 13, 3881. doi: 10.1021/acsami.0c18684
48. [48]
  Deng, K.; Mao, Q.; Wang, W.; Wang, P.; Wang, Z.; Xu, Y.; Li, X.; Wang, H. J.; Wang, L. Appl. Catal. B 2022, 310, 121338. doi: 10.1016/j.apcatb.2022
49. [49]
  Zhang, M.; Wang, Z.; Duan, Z.; Wang, S.; Xu, Y.; Li, X. N.; Wang, L.; Wang, H. J. J. Mater. Chem. A 2021, 9, 18323. doi: 10.1039/D1TA05564J
50. [50]
  Song, Q.; Li, J.; Wang, S.; Liu, J.; Liu, X.; Pang, L. Y.; Li, H.; Liu, H. Small 2019, 15, e1903395. doi: 10.1002/smll.201903395
51. [51]
  Zhou, L.; Shao, M.; Zhang, C.; Zhao, J.; He, S.; Rao, D.; Wei, M.; Evans, D. G.; Duan, X. Adv. Mater. 2017, 29, 1604080. doi: 10.1002/adma.201604080

扫一扫看文章

计量

PDF下载量: 9
文章访问数: 2198
HTML全文浏览量: 120

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

氮掺杂石墨烯气凝胶锚定RuP纳米粒子用于水合肼氧化辅助产氢

通讯作者: 黄昊, huanghao881015@163.com
陈煜, ndchenyu@gmail.com
李淑妮, lishuni@snnu.edu.cn

English

RuP Nanoparticles Anchored on N-doped Graphene Aerogels for Hydrazine Oxidation-Boosted Hydrogen Production

Corresponding author: Hao Huang, huanghao881015@163.com Yu Chen, ndchenyu@gmail.com Shu-Ni Li, lishuni@snnu.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

氮掺杂石墨烯气凝胶锚定RuP纳米粒子用于水合肼氧化辅助产氢

通讯作者: 黄昊, huanghao881015@163.com 陈煜, ndchenyu@gmail.com 李淑妮, lishuni@snnu.edu.cn

English

RuP Nanoparticles Anchored on N-doped Graphene Aerogels for Hydrazine Oxidation-Boosted Hydrogen Production

Corresponding author: Hao Huang, huanghao881015@163.com Yu Chen, ndchenyu@gmail.com Shu-Ni Li, lishuni@snnu.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

通讯作者: 黄昊, huanghao881015@163.com
陈煜, ndchenyu@gmail.com
李淑妮, lishuni@snnu.edu.cn

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs