Citation: Xianhong Chen, Pengchao Ruan, Xianwen Wu, Shuquan Liang, Jiang Zhou. Crystal Structures, Reaction Mechanisms, and Optimization Strategies of MnO₂ Cathode for Aqueous Rechargeable Zinc Batteries[J]. Acta Physico-Chimica Sinica, ;2022, 38(11): 211100. doi: 10.3866/PKU.WHXB202111003 shu

Crystal Structures, Reaction Mechanisms, and Optimization Strategies of MnO₂ Cathode for Aqueous Rechargeable Zinc Batteries

Xianhong Chen ¹ ,
Pengchao Ruan ¹ ,
Xianwen Wu ³ ,
Shuquan Liang ^{1, 2} ,
Jiang Zhou ^{1, 2,,}

1.
School of Materials Science & Engineering, Central South University, Changsha 410083, China
2.
Key Laboratory of Electronic Packaging and Advanced Functional Materials of Hunan Province, Central South University, Changsha 410083, China
3.
College of Chemistry and Chemical Engineering, Jishou University, Jishou 416000, Hunan Province, China

Corresponding author: Jiang Zhou, zhou_jiang@csu.edu.cn
Received Date: 1 November 2021
Revised Date: 3 December 2021
Accepted Date: 7 December 2021
Available Online: 21 December 2021
Fund Project: the Hunan Outstanding Youth Talents 2021JJ10064the Program of Youth Talent Support for Hunan Province 2020RC3011the National Natural Science Foundation of China 51932011the National Natural Science Foundation of China 51972346the National Natural Science Foundation of China 51872334the Innovation-Driven Project of Central South University 2020CX024

Because of the advantages of high safety, environment-friendliness, affordability, and ease of processing, aqueous rechargeable zinc batteries (ARZBs) are promising candidates for next-generation large-scale energy storage systems. In recent years, various cathode materials based on vanadium/manganese/cobalt oxides, Prussian blue analogs, and organic compounds have been reported. Among them, manganese dioxide (MnO₂) is widely used in ARZBs due to their outstanding advantages of low toxicity, eco-friendliness, and high capacity (616 mAh∙g⁻¹ based on two-electron transfer). However, the diversity of the crystal structures of MnO₂ and the unpredictability of the electrochemical reaction make it difficult to investigate the specific internal storage mechanism, which impedes further development of the optimal modification strategies. To date, the main recognized energy storage mechanisms are (de)intercalation and dissolution-deposition mechanisms. In the traditional (de)intercalation mechanism, the predominant issues related to MnO₂ during the cycling process include Mn dissolution, irreversible phase transformation, structural collapse, and sluggish ion diffusion kinetics. On the other hand, the detailed reaction path for the dissolution-deposition mechanism, which was developed in recent years, remains controversial. In addition, the incomplete dissolution-deposition of MnO₂ and the highly acidic environment inevitably leads to corrosion and hydrogen evolution of the zinc anode, as well as low Coulombic efficiency. Accordingly, optimization strategies for different reaction mechanisms have been proposed to make zinc-manganese batteries more competitive. For the (de)intercalation mechanism, modification of composite materials and nanostructure optimization strategies can be adopted to inhibit the dissolution of MnO₂ and increase the number of highly active reaction sites, thus enhancing the electrochemical performance. Moreover, the guest pre-intercalation strategy can help optimize the crystal structure of MnO₂, preventing the collapse of the internal structure during cycling. Besides, defect engineering and element doping strategies focus on regulating the distribution of the electronic structure for affecting the properties of MnO₂, resulting in lowering the energy barrier of zinc insertion. For the dissolution-deposition mechanism, the introduction of a neutral acetate and a halide mediator can effectively facilitate the dissolution-deposition of MnO₂. Meanwhile, metal element catalysis can accelerate the reaction kinetics of the MnO₂ dissolution-deposition, so that high-rate performance can be achieved. Furthermore, the decoupling battery system can separate the cathodic and anodic electrolytes to restrain the hydrogen and oxygen evolution reactions and enhance the potential difference. The flow battery system can effectively eliminate the influence of concentration polarization and stabilize the ion concentration in the electrolytes, thus leading to a large capacity (> 100 mAh). Undoubtedly, MnO₂ as a high-capacity, high-voltage cathode material has broad development prospects for ARZBs. Here, we systematically summarize the crystal structures and reaction mechanisms of MnO₂. We also discuss the optimization strategies toward advanced MnO₂ cathode materials for resolving the highlighted issues in zinc-manganese batteries, which are expected to provide research directions for the design and development of high-performance ARZBs.
- Aqueous rechargeable zinc battery,
- Manganese dioxide,
- Crystal structure,
- Reaction mechanism,
- Optimization strategy
1. [1]
  Guduru, R. K.; Icaza, J. C. Nanomater. (Basel) 2016, 6, 41. doi: 10.3390/nano6030041 doi: 10.3390/nano6030041
2. [2]
  Cao, R.; Mishra, K.; Li, X.; Qian, J.; Engelhard, M. H.; Bowden, M. E.; Han, K. S.; Mueller, K. T.; Henderson, W. A.; Zhang, J. -G. Nano Energy 2016, 30, 825. doi: 10.1016/j.nanoen.2016.09.013 doi: 10.1016/j.nanoen.2016.09.013
3. [3]
  Gummow, R. J.; Vamvounis, G.; Kannan, M. B.; He, Y. Adv. Mater. 2018, 30, 1801702. doi: 10.1002/adma.201801702 doi: 10.1002/adma.201801702
4. [4]
  Pan, H. Y.; Li, Q.; Yu, X. Q.; Li, H. Acta Phys. -Chim. Sin. 2021, 37, 2008091. doi: 10.3866/PKU.WHXB202008091
5. [5]
  Zhao, Y.; Ren, L.; Wang, A.; Luo, J. Acta Phys. -Chim. Sin. 2021, 37, 2008090. doi: 10.3866/PKU.WHXB202008090
6. [6]
  Liu, H.; Wang, J. -G.; You, Z.; Wei, C.; Kang, F.; Wei, B. Mater. Today 2021, 42, 73. doi: 10.1016/j.mattod.2020.08.021 doi: 10.1016/j.mattod.2020.08.021
7. [7]
  Li, C.; Xie, X.; Liu, H.; Wang, P.; Deng, C.; Lu, B.; Zhou, J.; Liang, S. Natl. Sci. Rev. 2021, nwab177. doi: 10.1093/nsr/nwab177/6370612 doi: 10.1093/nsr/nwab177/6370612
8. [8]
  Zhu, K.; Wu, T.; Sun, S.; Wen, Y.; Huang, K. ChemElectroChem 2020, 7, 2714. doi: 10.1002/celc.202000472 doi: 10.1002/celc.202000472
9. [9]
  Tang, F.; He, T.; Zhang, H.; Wu, X.; Li, Y.; Long, F.; Xiang, Y.; Zhu, L.; Wu, J.; Wu, X. J. Electroanal. Chem. 2020, 873, 114368. doi: 10.1016/j.jelechem.2020.114368 doi: 10.1016/j.jelechem.2020.114368
10. [10]
  Fang, G.; Zhou, J.; Pan, A.; Liang, S. ACS Energy Lett. 2018, 3, 2480. doi: 10.1021/acsenergylett.8b01426 doi: 10.1021/acsenergylett.8b01426
11. [11]
  Yang, S.; Zhang, M.; Wu, X.; Wu, X.; Zeng, F.; Li, Y.; Duan, S.; Fan, D.; Yang, Y.; Wu, X. J. Electroanal. Chem. 2019, 832, 69. doi: 10.1016/j.jelechem.2018.10.051 doi: 10.1016/j.jelechem.2018.10.051
12. [12]
  Cui, J.; Wu, X.; Yang, S.; Li, C.; Tang, F.; Chen, J.; Chen, Y.; Xiang, Y.; Wu, X.; He, Z. Front Chem. 2018, 6, 352. doi: 10.3389/fchem.2018.00352 doi: 10.3389/fchem.2018.00352
13. [13]
  Heng, Y.; Gu, Z.; Guo, J.; Wu, X. Acta Phys. -Chim. Sin. 2021, 37, 2005013. doi: 10.3866/PKU.WHXB202005013
14. [14]
  Venkatkarthick, R.; Rodthongkum, N.; Zhang, X.; Wang, S.; Pattananuwat, P.; Zhao, Y.; Liu, R.; Qin, J. ACS Appl. Energy Mater. 2020, 3, 4677. doi: 10.1021/acsaem.0c00309 doi: 10.1021/acsaem.0c00309
15. [15]
  Zampardi, G.; La Mantia, F. Curr. Opin. Electrochem. 2020, 21, 84. doi: 10.1016/j.coelec.2020.01.014 doi: 10.1016/j.coelec.2020.01.014
16. [16]
  Zhang, S.; Long, S.; Li, H.; Xu, Q. Chem. Eng. J. 2020, 400, 125898. doi: 10.1016/j.cej.2020.125898 doi: 10.1016/j.cej.2020.125898
17. [17]
  He, P.; Yan, M.; Zhang, G.; Sun, R.; Chen, L.; An, Q.; Mai, L. Adv. Energy Mater. 2017, 7, 1601920. doi: 10.1002/aenm.201601920 doi: 10.1002/aenm.201601920
18. [18]
  Yan, J.; Ang, E. H.; Yang, Y.; Zhang, Y.; Ye, M.; Du, W.; Li, C. C. Adv. Funct. Mater. 2021, 31, 2010213. doi: 10.1002/adfm.202010213 doi: 10.1002/adfm.202010213
19. [19]
  Mei, L.; Xu, J.; Wei, Z.; Liu, H.; Li, Y.; Ma, J.; Dou, S. Small 2017, 13, 1701441. doi: 10.1002/smll.201701441 doi: 10.1002/smll.201701441
20. [20]
  Zhang, N.; Chen, X.; Yu, M.; Niu, Z.; Cheng, F.; Chen, J. Chem. Soc. Rev. 2020, 49, 4203. doi: 10.1039/c9cs00349e doi: 10.1039/c9cs00349e
21. [21]
  Liu, X.; Yi, J.; Wu, K.; Jiang, Y.; Liu, Y.; Zhao, B.; Li, W.; Zhang, J. Nanotechnology2020, 31, 122001. doi: 10.1088/1361-6528/ab5b38 doi: 10.1088/1361-6528/ab5b38
22. [22]
  Zhao, Y.; Zhu, Y.; Zhang, X. InfoMat 2019, 2, 237. doi: 10.1002/inf2.12042 doi: 10.1002/inf2.12042
23. [23]
  Tang, B.; Shan, L.; Liang, S.; Zhou, J. Energy Environ. Sci. 2019, 12, 3288. doi: 10.1039/c9ee02526j doi: 10.1039/c9ee02526j
24. [24]
  Huang, S.; Zhu, J.; Tian, J.; Niu, Z. Chemistry 2019, 25, 14480. doi: 10.1002/chem.201902660 doi: 10.1002/chem.201902660
25. [25]
  Gao, J.; Xie, X.; Liang, S.; Lu, B.; Zhou, J. Nanomicro. Lett. 2021, 13, 69. doi: 10.1007/s40820-021-00595-6 doi: 10.1007/s40820-021-00595-6
26. [26]
  Feng, Q.; Kanoh, H.; Miyai, Y.; Ooi, K. Chem. Mater. 1995, 7, 1722. doi: 10.1021/cm00057a023 doi: 10.1021/cm00057a023
27. [27]
  Chen, Y.; Liu, C.; Li, F.; Cheng, H. J. Alloys Compd. 2005, 397, 282. doi: 10.1016/j.jallcom.2004.12.049 doi: 10.1016/j.jallcom.2004.12.049
28. [28]
  Xu, C.; Du, H.; Li, B.; Kang, F.; Zeng, Y. Electrochem. Solid-State Lett. 2009, 12, 4. doi: 10.1149/1.3065967 doi: 10.1149/1.3065967
29. [29]
  Xu, C.; Li, B.; Du, H.; Kang, F. Angew. Chem. Int. Ed. Engl. 2012, 51, 933. doi: 10.1002/anie.201106307 doi: 10.1002/anie.201106307
30. [30]
  Islam, S.; Alfaruqi, M. H.; Mathew, V.; Song, J.; Kim, S.; Kim, S.; Jo, J.; Baboo, J. P.; Pham, D. T.; Putro, D. Y.; Sun, Y. -K.; Kim, J. J. Mater. Chem. A 2017, 5, 23299. doi: 10.1039/c7ta07170a doi: 10.1039/c7ta07170a
31. [31]
  Kim, S.; Koo, B. -R.; Jo, Y. -R.; An, H. -R.; Lee, Y. -G.; Huang, C.; An, G. -H. J. Mater. Chem. A 2021, 5, 1900740. doi: 10.1039/D1TA04051K doi: 10.1039/D1TA04051K
32. [32]
  Ding, S.; Zhang, M.; Qin, R.; Fang, J.; Ren, H.; Yi, H.; Liu, L.; Zhao, W.; Li, Y.; Yao, L.; Li, S.; Zhao, Q.; Pan, F. Nanomicro. Lett. 2021, 13, 173. doi: 10.1007/s40820-021-00691-7 doi: 10.1007/s40820-021-00691-7
33. [33]
  Devaraj, S.; Munichandraiah, N. J. Phys. Chem. C 2008, 112, 4406. doi: 10.1021/jp7108785 doi: 10.1021/jp7108785
34. [34]
  Chabre, Y.; Pannetier Prog, J. Solid. State Chem. 1995, 23, 1. doi: 10.1016/0079-6786(94)00005-2 doi: 10.1016/0079-6786(94)00005-2
35. [35]
  Takakazu, Y.; Takayuki, S. Inorganica Chim. Acta 1986, 117, L27. doi: 10.1016/S0020-1693(00)82175-1 doi: 10.1016/S0020-1693(00)82175-1
36. [36]
  Kumar, G.; Sampath, S. Solid State Ionics 2003, 160, 289. doi: 10.1016/s0167-2738(03)00209-1 doi: 10.1016/s0167-2738(03)00209-1
37. [37]
  Alfaruqi, M. H.; Mathew, V.; Gim, J.; Kim, S.; Song, J.; Baboo, J. P.; Choi, S. H.; Kim, J. Chem. Mater. 2015, 27, 3609. doi: 10.1021/cm504717p doi: 10.1021/cm504717p
38. [38]
  Dose, W. M.; Sharma, N.; Webster, N. A. S.; Peterson, V. K.; Donne, S. W. J. Phys. Chem. C 2014, 118, 24257. doi: 10.1021/jp506914j doi: 10.1021/jp506914j
39. [39]
  Yang, R.; Fan, Y.; Ye, R.; Tang, Y.; Cao, X.; Yin, Z.; Zeng, Z. Adv Mater 2021, 33, 2004862. doi: 10.1002/adma.202004862 doi: 10.1002/adma.202004862
40. [40]
  Hunter, J. C. J. Solid State Chem. 1981, 39, 142. doi: 10.1016/0022-4596(81)90323-6 doi: 10.1016/0022-4596(81)90323-6
41. [41]
  Yuan, C.; Zhang, Y.; Pan, Y.; Liu, X.; Wang, G.; Cao, D. Electrochim. Acta 2014, 116, 404. doi: 10.1016/j.electacta.2013.11.090 doi: 10.1016/j.electacta.2013.11.090
42. [42]
  Alfaruqi, M. H.; Gim, J.; Kim, S.; Song, J.; Pham, D. T.; Jo, J.; Xiu, Z.; Mathew, V.; Kim, J. Electrochem Commun. 2015, 60, 121. doi: 10.1016/j.elecom.2015.08.019 doi: 10.1016/j.elecom.2015.08.019
43. [43]
  Jin, Y.; Zou, L.; Liu, L.; Engelhard, M. H.; Patel, R. L.; Nie, Z.; Han, K. S.; Shao, Y.; Wang, C.; Zhu, J.; et al. Adv. Mater. 2019, 31, 1900567. doi: 10.1002/adma.201900567 doi: 10.1002/adma.201900567
44. [44]
  Li, Y.; Wang, S.; Salvador, J. R.; Wu, J.; Liu, B.; Yang, W.; Yang, J.; Zhang, W.; Liu, J.; Yang, J. Chem. Mater. 2019, 31, 2036. doi: 10.1021/acs.chemmater.8b05093 doi: 10.1021/acs.chemmater.8b05093
45. [45]
  Zhang, N.; Cheng, F.; Liu, J.; Wang, L.; Long, X.; Liu, X.; Li, F.; Chen, J. Nat. Commun. 2017, 8, 405. doi: 10.1038/s41467-017-00467-x doi: 10.1038/s41467-017-00467-x
46. [46]
  Jiang, Y.; Ba, D.; Li, Y.; Liu, J. Adv. Sci. (Weinh) 2020, 7, 1902795. doi: 10.1002/advs.201902795 doi: 10.1002/advs.201902795
47. [47]
  Song, M.; Tan, H.; Chao, D.; Fan, H. J. Adv. Funct. Mater. 2018, 28, 1802564. doi: 10.1002/adfm.201802564 doi: 10.1002/adfm.201802564
48. [48]
  Zeng, L.; Zhang, G.; Huang, X.; Wang, H.; Zhou, T.; Xie, H. Vacuum 2021, 192, 110398. doi: 10.1016/j.vacuum.2021.110398 doi: 10.1016/j.vacuum.2021.110398
49. [49]
  Xue, T.; Fan, H. J. J. Energy Chem. 2021, 54, 194. doi: 10.1016/j.jechem.2020.05.056 doi: 10.1016/j.jechem.2020.05.056
50. [50]
  Guo, X.; Zhou, J.; Bai, C.; Li, X.; Fang, G.; Liang, S. Mater. Today Energy 2020, 16, 100396. doi: 10.1016/j.mtener.2020.100396 doi: 10.1016/j.mtener.2020.100396
51. [51]
  Lee, B.; Lee, H. R.; Kim, H.; Chung, K. Y.; Cho, B. W.; Oh, S. H. Chem. Commun. (Camb) 2015, 51, 9265. doi: 10.1039/c5cc02585k doi: 10.1039/c5cc02585k
52. [52]
  Sun, W.; Wang, F.; Hou, S.; Yang, C.; Fan, X.; Ma, Z.; Gao, T.; Han, F.; Hu, R.; Zhu, M.; Wang, C. J. Am. Chem. Soc. 2017, 139, 9775. doi: 10.1021/jacs.7b04471 doi: 10.1021/jacs.7b04471
53. [53]
  Zhou, J.; Shan, L.; Tang, B.; Liang, S. Chinese Sci. Bull. 2020, 65, 3562. doi: 10.1360/tb-2020-0352 doi: 10.1360/tb-2020-0352
54. [54]
  Huang, J.; Wang, Z.; Hou, M.; Dong, X.; Liu, Y.; Wang, Y.; Xia, Y. Nat. Commun. 2018, 9, 2906. doi: 10.1038/s41467-018-04949-4 doi: 10.1038/s41467-018-04949-4
55. [55]
  Wang, S.; Yuan, Z.; Zhang, X.; Bi, S.; Zhou, Z.; Tian, J.; Zhang, Q.; Niu, Z. Angew. Chem. Int. Ed. 2021, 60, 7056. doi: 10.1002/anie.202017098 doi: 10.1002/anie.202017098
56. [56]
  Pan, H.; Shao, Y.; Yan, P.; Cheng, Y.; Han, K. S.; Nie, Z.; Wang, C.; Yang, J.; Li, X.; Bhattacharya, P.; Mueller, K. T.; Liu, J. Nat. Energy 2016, 1, 16039. doi: 10.1038/nenergy.2016.39 doi: 10.1038/nenergy.2016.39
57. [57]
  Lee, B.; Seo, H. R.; Lee, H. R.; Yoon, C. S.; Kim, J. H.; Chung, K. Y.; Cho, B. W.; Oh, S. H. ChemSusChem 2016, 9, 2948. doi: 10.1002/cssc.201600702 doi: 10.1002/cssc.201600702
58. [58]
  Yang, J.; Cao, J.; Peng, Y.; Yang, W.; Barg, S.; Liu, Z.; Kinloch, I. A.; Bissett, M. A.; Dryfe, R. A. W. ChemSusChem 2020, 13, 4103. doi: 10.1002/cssc.202001216 doi: 10.1002/cssc.202001216
59. [59]
  Wang, M.; Zheng, X.; Zhang, X.; Chao, D.; Qiao, S. Z.; Alshareef, H. N.; Cui, Y.; Chen, W. Adv. Energy Mater. 2020, 11, 2002904. doi: 10.1002/aenm.202002904 doi: 10.1002/aenm.202002904
60. [60]
  Liu, Z.; Yang, Y.; Liang, S.; Lu, B.; Zhou, J. Small Struct. 2021, 2, 2100119. doi: 10.1002/sstr.202100119 doi: 10.1002/sstr.202100119
61. [61]
  Liang, G.; Mo, F.; Li, H.; Tang, Z.; Liu, Z.; Wang, D.; Yang, Q.; Ma, L.; Zhi, C. Adv. Energy Mater. 2019, 9, 1901838. doi: 10.1002/aenm.201901838 doi: 10.1002/aenm.201901838
62. [62]
  Chao, D.; Zhou, W.; Ye, C.; Zhang, Q.; Chen, Y.; Gu, L.; Davey, K.; Qiao, S. Z. Angew. Chem. Int. Ed. 2019, 58, 7823. doi: 10.1002/anie.201904174 doi: 10.1002/anie.201904174
63. [63]
  Wu, D.; Housel, L. M.; Kim, S. J.; Sadique, N.; Quilty, C. D.; Wu, L.; Tappero, R.; Nicholas, S. L.; Ehrlich, S.; Zhu, Y.; et al. Energy Environ. Sci. 2020, 13, 4322. doi: 10.1039/d0ee02168g doi: 10.1039/d0ee02168g
64. [64]
  Han, M.; Qin, L.; Liu, Z.; Zhang, L.; Li, X.; Lu, B.; Huang, J.; Liang, S.; Zhou, J. Mater. Today Energy 2021, 20, 100626. doi: 10.1016/j.mtener.2020.100626 doi: 10.1016/j.mtener.2020.100626
65. [65]
  Chen, X.; Li, W.; Zeng, Z.; Reed, D.; Li, X.; Liu, X. Chem. Eng. J. 2021, 405, 126969. doi: 10.1016/j.cej.2020.126969 doi: 10.1016/j.cej.2020.126969
66. [66]
  Corpuz, R. D.; Juan-Corpuz, L. M.; Nguyen, M. T.; Yonezawa, T.; Wu, H. L.; Somwangthanaroj, A.; Kheawhom, S. Int. J. Mol. Sci. 2020, 21, 3113. doi: 10.3390/ijms21093113 doi: 10.3390/ijms21093113
67. [67]
  Zhang, Y.; Deng, S.; Li, Y.; Liu, B.; Pan, G.; Liu, Q.; Wang, X.; Xia, X.; Tu, J. Energy Stor. Mater. 2020, 29, 52. doi: 10.1016/j.ensm.2020.04.003 doi: 10.1016/j.ensm.2020.04.003
68. [68]
  Fu, Y.; Wei, Q.; Zhang, G.; Wang, X.; Zhang, J.; Hu, Y.; Wang, D.; Zuin, L.; Zhou, T.; Wu, Y.; Sun, S. Adv. Energy Mater. 2018, 8, 1801445. doi: 10.1002/aenm.201801445 doi: 10.1002/aenm.201801445
69. [69]
  Bi, S.; Wu, Y.; Cao, A.; Tian, J.; Zhang, S.; Niu, Z. Mater. Today Energy 2020, 18, 100548. doi: 10.1016/j.mtener.2020.100548 doi: 10.1016/j.mtener.2020.100548
70. [70]
  Wu, B.; Zhang, G.; Yan, M.; Xiong, T.; He, P.; He, L.; Xu, X.; Mai, L. Small 2018, 14, 1703850. doi: 10.1002/smll.201703850 doi: 10.1002/smll.201703850
71. [71]
  Guo, S.; Liang, S.; Zhang, B.; Fang, G.; Ma, D.; Zhou, J. ACS Nano 2019, 13, 13456. doi: 10.1021/acsnano.9b07042 doi: 10.1021/acsnano.9b07042
72. [72]
  Zeng, Y.; Zhang, X.; Meng, Y.; Yu, M.; Yi, J.; Wu, Y.; Lu, X.; Tong, Y. Adv. Mater. 2017, 29, 1700274. doi: 10.1002/adma.201700274 doi: 10.1002/adma.201700274
73. [73]
  Li, Z.; Huang, Y.; Zhang, J.; Jin, S.; Zhang, S.; Zhou, H. Nanoscale 2020, 12, 4150. doi: 10.1039/c9nr09870d doi: 10.1039/c9nr09870d
74. [74]
  Mao, J.; Wu, F. -F.; Shi, W. -H.; Liu, W. -X.; Xu, X. -L.; Cai, G. -F.; Li, Y. -W.; Cao, X. -H. Chinese J. Polym. Sci. 2019, 38, 514. doi: 10.1007/s10118-020-2353-6 doi: 10.1007/s10118-020-2353-6
75. [75]
  Guo, G. Y.; JinSong, H.; LiJun, W. Adv. Mater. 2008, 20, 2878. doi: 10.1002/adma.200800627 doi: 10.1002/adma.200800627
76. [76]
  Kim, J. M.; Huh, Y. S.; Han, Y. -K.; Cho, M. S.; Kim, H. J. Electrochem. Commun. 2012, 14, 32. doi: 10.1016/j.elecom.2011.10.023 doi: 10.1016/j.elecom.2011.10.023
77. [77]
  Liu, D. -S.; Mai, Y.; Chen, S.; Liu, S.; Ang, E. H.; Ye, M.; Yang, Y.; Zhang, Y.; Geng, H.; Li, C. C. Electrochimica Acta 2021, 370, 137740. doi: 10.1016/j.electacta.2021.137740 doi: 10.1016/j.electacta.2021.137740
78. [78]
  Alfaruqi, M. H.; Gim, J.; Kim, S.; Song, J.; Jo, J.; Kim, S.; Mathew, V.; Kim, J. J. Power Sources 2015, 288, 320. doi: 10.1016/j.jpowsour.2015.04.140 doi: 10.1016/j.jpowsour.2015.04.140
79. [79]
  Guo, C.; Liu, H.; Li, J.; Hou, Z.; Liang, J.; Zhou, J.; Zhu, Y.; Qian, Y. Electrochim. Acta 2019, 304, 370. doi: 10.1016/j.electacta.2019.03.008 doi: 10.1016/j.electacta.2019.03.008
80. [80]
  Wang, Y.; Wu, Z.; Jiang, L.; Tian, W.; Zhang, C.; Cai, C.; Hu, L. Nanoscale Adv. 2019, 1, 4365. doi: 10.1039/c9na00519f doi: 10.1039/c9na00519f
81. [81]
  Liu, Y.; Chi, X.; Han, Q.; Du, Y.; Huang, J.; Liu, Y.; Yang, J. J. Power Sources 2019, 443, 227244. doi: 10.1016/j.jpowsour.2019.227244 doi: 10.1016/j.jpowsour.2019.227244
82. [82]
  Huang, J.; Zhou, J.; Liang, S. Acta Phys. -Chim. Sin. 2021, 37, 2005020. doi: 10.3866/PKU.WHXB202005020
83. [83]
  Nam, K. W.; Kim, H.; Choi, J. H.; Choi, J. W. Energy Environ. Sci. 2019, 12, 1999. doi: 10.1039/c9ee00718k doi: 10.1039/c9ee00718k
84. [84]
  Zhao, Q.; Song, A.; Ding, S.; Qin, R.; Cui, Y.; Li, S.; Pan, F. Adv. Mater. 2020, 32, 2002450. doi: 10.1002/adma.202002450 doi: 10.1002/adma.202002450
85. [85]
  Wang, J.; Sun, X.; Zhao, H.; Xu, L.; Xia, J.; Luo, M.; Yang, Y.; Du, Y. J. Phys. Chem. C 2019, 123, 22735. doi: 10.1021/acs.jpcc.9b05535 doi: 10.1021/acs.jpcc.9b05535
86. [86]
  Yan, M.; He, P.; Chen, Y.; Wang, S.; Wei, Q.; Zhao, K.; Xu, X.; An, Q.; Shuang, Y.; Shao, Y.; et al. Adv. Mater. 2018, 30, 1703725. doi: 10.1002/adma.201703725 doi: 10.1002/adma.201703725
87. [87]
  Wang, D.; Wang, L.; Liang, G.; Li, H.; Liu, Z.; Tang, Z.; Liang, J.; Zhi, C. ACS Nano 2019, 13, 10643. doi: 10.1021/acsnano.9b04916 doi: 10.1021/acsnano.9b04916
88. [88]
  Zhang, H.; Liu, Q.; Wang, J.; Chen, K.; Xue, D.; Liu, J.; Lu, X. J. Mater. Chem. A 2019, 7, 22079. doi: 10.1039/c9ta08418e doi: 10.1039/c9ta08418e
89. [89]
  Zhai, D.; Li, B.; Xu, C.; Du, H.; He, Y.; Wei, C.; Kang, F. J. Power Sources 2011, 196, 7860. doi: 10.1016/j.jpowsour.2011.05.015 doi: 10.1016/j.jpowsour.2011.05.015
90. [90]
  Du, M.; Miao, Z.; Li, H.; Sang, Y.; Liu, H.; Wang, S. J. Mater. Chem. A 2021, 9, 19245. doi: 10.1039/d1ta03620c doi: 10.1039/d1ta03620c
91. [91]
  Lian, S.; Sun, C.; Xu, W.; Huo, W.; Luo, Y.; Zhao, K.; Yao, G.; Xu, W.; Zhang, Y.; Li, Z.; et al. Nano Energy 2019, 62, 79. doi: 10.1016/j.nanoen.2019.04.038 doi: 10.1016/j.nanoen.2019.04.038
92. [92]
  Fang, G.; Zhu, C.; Chen, M.; Zhou, J.; Tang, B.; Cao, X.; Zheng, X.; Pan, A.; Liang, S. Adv. Funct. Mater. 2019, 29, 1808375. doi: 10.1002/adfm.201808375 doi: 10.1002/adfm.201808375
93. [93]
  Liu, Z.; Qin, L.; Chen, X.; Xie, X.; Zhu, B.; Gao, Y.; Zhou, M.; Fang, G.; Liang, S. Mater. Today Energy 2021, 22, 100851. doi: 10.1016/j.mtener.2021.100851 doi: 10.1016/j.mtener.2021.100851
94. [94]
  Alfaruqi, M. H.; Islam, S.; Mathew, V.; Song, J.; Kim, S.; Tung, D. P.; Jo, J.; Kim, S.; Baboo, J. P.; Xiu, Z.; Kim, J. Appl. Surf. Sci. 2017, 404, 435. doi: 10.1016/j.apsusc.2017.02.009 doi: 10.1016/j.apsusc.2017.02.009
95. [95]
  Zhang, Z.; Li, S.; Zhao, B.; Zhang, X.; Wang, X.; Wen, Z.; Ji, S.; Sun, J. J. Phys. Chem. C 2021, 125, 20195. doi: 10.1021/acs.jpcc.1c05417 doi: 10.1021/acs.jpcc.1c05417
96. [96]
  Zhang, M.; Wu, W.; Luo, J.; Zhang, H.; Liu, J.; Liu, X.; Yang, Y.; Lu, X. J. Mater. Chem. A 2020, 8, 11642. doi: 10.1039/d0ta03706k doi: 10.1039/d0ta03706k
97. [97]
  Liu, K.; Tan, S.; Moon, J.; Jafta, C. J.; Li, C.; Kobayashi, T.; Lyu, H.; Bridges, C. A.; Men, S.; Guo, W.; et al. Adv. Energy Mater. 2020, 10, 2000135. doi: 10.1002/aenm.202000135 doi: 10.1002/aenm.202000135
98. [98]
  Zeng, X.; Liu, J.; Mao, J.; Hao, J.; Wang, Z.; Zhou, S.; Ling, C. D.; Guo, Z. Adv. Energy Mater. 2020, 10, 1904163. doi: 10.1002/aenm.201904163 doi: 10.1002/aenm.201904163
99. [99]
  Lei, J.; Yao, Y.; Wang, Z.; Lu, Y. -C. Energy Environ. Sci. 2021, 14, 4418. doi: 10.1039/d1ee01120k doi: 10.1039/d1ee01120k
100. [100]
  Zheng, X.; Wang, Y.; Xu, Y.; Ahmad, T.; Yuan, Y.; Sun, J.; Luo, R.; Wang, M.; Chuai, M.; Chen, N.; et al. Nano Lett. 2021, 21, 8863. doi: 10.1021/acs.nanolett.1c03319 doi: 10.1021/acs.nanolett.1c03319
101. [101]
  Zhong, Y.; Xu, X.; Veder, J. P.; Shao, Z. iScience 2020, 23, 100943. doi: 10.1016/j.isci.2020.100943 doi: 10.1016/j.isci.2020.100943
102. [102]
  Zhou, M.; Weng, Q.; Popov, Z. I.; Yang, Y.; Antipina, L. Y.; Sorokin, P. B.; Wang, X.; Bando, Y.; Golberg, D. ACS Nano 2018, 12, 4148. doi: 10.1021/acsnano.7b08724 doi: 10.1021/acsnano.7b08724
103. [103]
  Suen, N. T.; Hung, S. F.; Quan, Q.; Zhang, N.; Xu, Y. J.; Chen, H. M. Chem. Soc. Rev. 2017, 46, 337. doi: 10.1039/c6cs00328a doi: 10.1039/c6cs00328a
104. [104]
  Dai, L.; Wang, Y.; Sun, L.; Ding, Y.; Yao, Y.; Yao, L.; Drewett, N. E.; Zhang, W.; Tang, J.; Zheng, W. Adv. Sci. (Weinh) 2021, 8, 2004995. doi: 10.1002/advs.202004995 doi: 10.1002/advs.202004995
105. [105]
  Zhong, C.; Liu, B.; Ding, J.; Liu, X.; Zhong, Y.; Li, Y.; Sun, C.; Han, X.; Deng, Y.; Zhao, N.; Hu, W. Nat. Energy 2020, 5, 440. doi: 10.1038/s41560-020-0584-y doi: 10.1038/s41560-020-0584-y
106. [106]
  Chao, D.; Ye, C.; Xie, F.; Zhou, W.; Zhang, Q.; Gu, Q.; Davey, K.; Gu, L.; Qiao, S. Z. Adv. Mater. 2020, 32, 2001894. doi: 10.1002/adma.202001894 doi: 10.1002/adma.202001894
107. [107]
  Huang, J.; Xie, Y.; Yan, L.; Wang, B.; Kong, T.; Dong, X.; Wang, Y.; Xia, Y. Energy Environ. Sci. 2021, 14, 883. doi: 10.1039/d0ee03639k doi: 10.1039/d0ee03639k
108. [108]
  Gong, K.; Fang, Q.; Gu, S.; Li, S. F. Y.; Yan, Y. Energy Environ. Sci. 2015, 8, 3515. doi: 10.1039/c5ee02341f doi: 10.1039/c5ee02341f
109. [109]
  Xie, C.; Li, T.; Deng, C.; Song, Y.; Zhang, H.; Li, X. Energy Environ. Sci. 2020, 13, 135. doi: 10.1039/c9ee03702k doi: 10.1039/c9ee03702k
110. [110]
  Li, G.; Chen, W.; Zhang, H.; Gong, Y.; Shi, F.; Wang, J.; Zhang, R.; Chen, G.; Jin, Y.; Wu, T.; et al. Adv. Energy Mater. 2020, 10, 1902085. doi: 10.1002/aenm.201902085 doi: 10.1002/aenm.201902085
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Crystal Structures, Reaction Mechanisms, and Optimization Strategies of MnO2 Cathode for Aqueous Rechargeable Zinc Batteries

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Crystal Structures, Reaction Mechanisms, and Optimization Strategies of MnO₂ Cathode for Aqueous Rechargeable Zinc Batteries