Citation: Xiaoming Li, Yidan Gao, Qingqiang Kong, Lijing Xie, Zhuo liu, Xiaoqian Guo, Yanzhen Liu, Xianxian Wei, Xiao Yang, Xinghua Zhang, Chengmeng Chen. Fabrication of Three-Dimensional Copper@Graphene Phase Change Composite with High Structural Stability and Low Leakage Rate[J]. Acta Physico-Chimica Sinica, ;2022, 38(1): 201209. doi: 10.3866/PKU.WHXB202012091 shu

Fabrication of Three-Dimensional Copper@Graphene Phase Change Composite with High Structural Stability and Low Leakage Rate

Xiaoming Li ^{1, †} ,
Yidan Gao ^{1, †} ,
Qingqiang Kong ¹ ,
Lijing Xie ¹ ,
Zhuo liu ¹ ,
Xiaoqian Guo ¹ ,
Yanzhen Liu ¹ ,
Xianxian Wei ³ ,
Xiao Yang ¹ ,
Xinghua Zhang ¹ ,
Chengmeng Chen ^{1, 2,,}

1.
Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
College of Materials Sciences and Opto-Electronic Technology, University of Chinese Academy of Sciences, Beijing 100049, China
3.
College of Environment and Safety, Taiyuan University of Science and Technology, Taiyuan 030024, China

Corresponding author: Chengmeng Chen, ccm@sxicc.ac.cn

^†

Received Date: 31 December 2020
Revised Date: 15 February 2021
Accepted Date: 18 February 2021
Available Online: 25 February 2021
Fund Project: the National Natural Science Foundation of China 21922815the National Natural Science Foundation of China 51802325the Natural Science Foundation of Shanxi Province 201901D211585the Scientific and Technological Key Project of Shanxi Province 20191102003the Patent Promotion and Implementation Project of Shanxi Province 20200716the Key Research and Development (R&D) Projects of Shanxi Province 201903D121007

Owing to the continuous increase in energy consumption and the growing depletion of traditional fossil fuels, the development of renewable energy is becoming increasingly urgent. Renewable energy has come to the fore, represented by geothermal energy and solar energy. However, the application of these energy sources is highly susceptible to weather, season, location, and time. Thus, these alternative energies are unstable, random, fluctuating, intermittent, and inefficient. The development of energy storage technologies can efficiently solve these problems, storing and releasing energy when needed. Among the key materials used in various energy-storage technologies, phase-change materials (PCMs) are strong candidates for smart thermal energy management and portable thermal energy sectors. As most innate PCMs face issues of low thermal conductivity, environmental pollution, and leakage over their melting point, encapsulating PCMs into supporting materials is necessary. However, these supporting materials face significant challenges in their application. First, skeleton materials should be resistant to the PCM volume changes during melting and solidification processes to achieve suitable structural stability. Second, skeleton materials should also have high thermal conductivity and a low leakage rate. Graphene aerogel (GA) has proven to be an effective supporting skeleton to improve the shape-stability of PCMs; however, the leakage caused by the phase transition and the brittleness of the network structure is a primary problem restricting its application. Skeleton materials play a crucial role in the performance of PCMs. Herein, we propose a double-pulse plating reinforcement strategy for fabricating copper@graphene aerogel (Cu@GA) as a skeleton material for phase change energy. In this design, individual nanosheets of the GA were uniformly covered and interlinked by copper particles. The Cu@GA interlinked networks ensure suitable thermal conductivity and a robust framework, beneficial for phase change heat transfer and leak-suppression performance. In addition, we prepared a PCM composite with high structural stability and low leakage rate by encapsulating octadecylamine (ODA) in Cu@GA through vacuum impregnation to ensure homogeneous ODA dispersion in the Cu@GA porous structure. The influence of different skeletons on the PCM composite leakage rate was investigated by comparing the weight change of the PCM composite. Benefiting from these structural features, the optimized composite phase change material (CPCM) Cu@GA/ODA showed a reduced leakage rate of 19.82% (w, mass fraction) compared to 80.31% (w) of GA/ODA and 72.99% (w) of GOA/ODA after 20 heat storage and release cycles. The cycled skeleton morphology was investigated using scanning electron microscopy to determine the origin of this influence. The skeleton integrity of Cu@GA/ODA was well maintained, while the three-dimensional network structures of GOA/ODA and GA/ODA showed shrinkage or collapse. Thus, the copper coating increased the skeleton's microstructural stability, conducive to high structural stability and reducing the leakage rate of the PCM composite. This study paves the way for the construction of ideal metal-coating GA composites with an excellent comprehensive performance for future phase change energy storage, porous microwave absorption, and energy storage applications.
- Electroplating,
- Copper@graphene aerogel,
- 3D graphene skeleton,
- Phase change material,
- Friability
1. [1]
  Li, M.; Mu, B. Y. Appl. Energy 2019, 242, 695. doi: 10.1016/j.apenergy.2019.03.085 doi: 10.1016/j.apenergy.2019.03.085
2. [2]
  Gao, H. Y.; Wang, J. J.; Chen, X.; Wang, G.; Huang, X. B.; Li, A.; Dong, W. J. Nano Energy 2018, 53, 769. doi: 10.1016/j.nanoen.2018.09.007 doi: 10.1016/j.nanoen.2018.09.007
3. [3]
  Chen, X.; Tang, Z. D.; Gao, H. Y.; Chen, S. Y.; Wang, G. iScience 2020, 23 (6), 101208. doi: 10.1016/j.isci.2020.101208 doi: 10.1016/j.isci.2020.101208
4. [4]
  Aftab, W.; Mahmood, A.; Guo, W. H.; Yousaf, M.; Tabassum, H.; Huang, X. Y.; Liang, Z. B.; Cao, A. Y.; Zou, R. Q. Energy Storage Mater. 2019, 20, 401. doi: 10.1016/j.ensm.2018.10.014 doi: 10.1016/j.ensm.2018.10.014
5. [5]
  Liao, H. H.; Chen, W. H.; Liu, Y.; Wang, Q. Compos. Sci. Technol. 2020, 189, 108010. doi: 10.1016/j.compscitech.2020.108010 doi: 10.1016/j.compscitech.2020.108010
6. [6]
  Sheng, N.; Zhu, R. J.; Nomura, T.; Rao, Z. H.; Zhu, C. Y.; Aoki, Y.; Habazaki, H.; Akiyama, T. Sol. Energy Mater. Sol. Cells 2020, 206, 110280. doi: 10.1016/j.solmat.2019.110280 doi: 10.1016/j.solmat.2019.110280
7. [7]
  Feng, Y. J.; Wang, J. P.; Liu, L. L.; Wang, X. D. Acta Phys. -Chim. Sin. 2019, 35 (6), 644. doi: 10.3866/pku.Whxb201805068
8. [8]
  Nan, G. H.; Wang J. P.; Wang Y.; Wang H.; Li W.; Zhang X. X. . Acta Phys. -Chim. Sin. 2014, 30 (2), 338. doi: 10.3866/pku.Whxb201312231
9. [9]
  Cheng, G.; Wang, X. Z.; He, Y. R. Appl. Therm. Eng. 2020, 178, 115560. doi: 10.1016/j.applthermaleng.2020.115560 doi: 10.1016/j.applthermaleng.2020.115560
10. [10]
  Cao, Y. F.; Fan, D. L.; Lin, S. H.; Mu, L. Y.; Ng, F. T. T.; Pan, Q. M. Chem. Eng. J. 2020, 389, 124318. doi: 10.1016/j.cej.2020.124318 doi: 10.1016/j.cej.2020.124318
11. [11]
  Qi, G. Q.; Yang, J.; Bao, R. Y.; Xia, D. Y.; Cao, M.; Yang, W.; Yang, M. B.; Wei, D. C. Nano Res. 2017, 10 (3), 802. doi: 10.1007/s12274-016-1333-1 doi: 10.1007/s12274-016-1333-1
12. [12]
  Khadiran, T.; Hussein, M. Z.; Zainal, Z.; Rusli, R. Energy 2015, 82, 468. doi: 10.1016/j.energy.2015.01.057 doi: 10.1016/j.energy.2015.01.057
13. [13]
  Sobolciak, P.; Mrlík, M.; AlMaadeed, M. A.; Krupa, I. Thermochim. Acta 2015, 617, 111. doi: 10.1016/j.tca.2015.08.026 doi: 10.1016/j.tca.2015.08.026
14. [14]
  Xiao, X.; Zhang, P.; Li, M. Appl. Energy 2013, 112, 1357. doi: 10.1016/j.apenergy.2013.04.050 doi: 10.1016/j.apenergy.2013.04.050
15. [15]
  Zhang, P.; Meng, Z. N.; Zhu, H.; Wang, Y. L.; Peng, S. P. Appl. Energy 2017, 185, 1971. doi: 10.1016/j.apenergy.2015.10.075 doi: 10.1016/j.apenergy.2015.10.075
16. [16]
  Karthik, M.; Faik, A.; D'Aguanno, B. Sol. Energy Mater. Sol. Cells 2017, 172, 324. doi: 10.1016/j.solmat.2017.08.004 doi: 10.1016/j.solmat.2017.08.004
17. [17]
  Li, G. Y.; Hong, G.; Dong, D. P.; Song, W. H.; Zhang, X. T. Adv. Mater. 2018, 30 (30), 1801754. doi: 10.1002/adma.201801754 doi: 10.1002/adma.201801754
18. [18]
  Gao, Z. Q.; Wang, C. Y.; Li, J. J.; Zhu, Y. T.; Zhang, Z. C.; Hu, W. P. Acta Phys. -Chim. Sin. 2021, 37 (7), 2010025. doi: 10.3866/PKU.WHXB202010025
19. [19]
  Xue, F.; Lu, Y.; Qi, X. D.; Yang, J. H.; Wang, Y. Chem. Eng. J. 2019, 365, 20. doi: 10.1016/j.cej.2019.02.023 doi: 10.1016/j.cej.2019.02.023
20. [20]
  Wu, W. H.; Huang, X. Y.; Yao, R. M.; Chen, R. J.; Li, K.; Zou, R. Q. Acta Phys. -Chim. Sin. 2017, 33 (1), 255. doi: 10.3866/pku.Whxb201610181
21. [21]
  Li, B. L.; Guo, J. G.; Xu, Bing; Xu, H. T.; Dong, Z. j.; Li, X. K. New Carbon Mater. 2020, 35 (5), 567. doi: 10.1016/S1872-5805(20)60510-8 doi: 10.1016/S1872-5805(20)60510-8
22. [22]
  Liu, X.; Deng, H. L.; Zheng, J. H.; Sun, M.; Cui, H.; Zhang, X. H.; Song, G. S. New Carbon Mater. 2020, 35 (5), 576. doi: 10.1016/S1872-5805(20)60511-X doi: 10.1016/S1872-5805(20)60511-X
23. [23]
  Yang, J.; Tang, L. S.; Bao, R. Y.; Bai, L.; Liu, Z. Y.; Yang, W.; Xie, B. H.; Yang, M. B. J. Mater. Chem. A 2016, 4 (48), 18841. doi: 10.1039/c6ta08454k doi: 10.1039/c6ta08454k
24. [24]
  Huang, J. H.; Zhang, B. N.; He, M.; Huang, X.; Wu, G. J.; Yin, G. Q.; Cui, Y. D. J. Mater. Sci. 2020, 55 (17), 7337. doi: 10.1007/s10853-020-04514-9 doi: 10.1007/s10853-020-04514-9
25. [25]
  Yang, G. Q.; Zhao, L. Y.; Shen, C. F.; Mao, Z. P.; Xu, H.; Feng, X. L.; Wang, B. J.; Sui, X. F. Sol. Energy Mater. Sol. Cells 2020, 209, 110441. doi: 10.1016/j.solmat.2020.110441 doi: 10.1016/j.solmat.2020.110441
26. [26]
  Mu, B. Y.; Li, M. Sol. Energy Mater. Sol. Cells 2019, 191, 466. doi: 10.1016/j.solmat.2018.11.025 doi: 10.1016/j.solmat.2018.11.025
27. [27]
  Jiang, L. L.; Fan, Z. J. Nanoscale 2014, 6 (4), 1922. doi: 10.1039/c3nr04555b doi: 10.1039/c3nr04555b
28. [28]
  Wang, P.; Chong, H. D.; Zhang, J. J.; Lu, H. B. ACS Appl. Mater. Interfaces 2017, 9 (26), 22006. doi: 10.1021/acsami.7b07328 doi: 10.1021/acsami.7b07328
29. [29]
  Woltornist, S. J.; Varghese, D.; Massucci, D.; Cao, Z.; Dobrynin, A. V.; Adamson, D. H. Adv. Mater. 2017, 1604947. doi: 10.1002/adma.201604947 doi: 10.1002/adma.201604947
30. [30]
  Zhong, Y. J.; Zhou, M.; Huang, F. Q.; Lin, T. Q.; Wan, D. Y. Sol. Energy Mater. Sol. Cells 2013, 113, 195. doi: 10.1016/j.solmat.2013.01.046 doi: 10.1016/j.solmat.2013.01.046
31. [31]
  Yang, J.; Zhang, E. W.; Li, X. F.; Zhang, Y. T.; Qu, J.; Yu, Z. Z. Carbon 2016, 98, 50. doi: 10.1016/j.carbon.2015.10.082 doi: 10.1016/j.carbon.2015.10.082
32. [32]
  Zhou, Y.; Li, C. H.; Wu, H.; Guo, S. Y. Colloids Surf. A 2020, 597, 124780. doi: 10.1016/j.colsurfa.2020.124780 doi: 10.1016/j.colsurfa.2020.124780
33. [33]
  Zhu, X. Y.; Yang, C.; Wu, P. W.; Ma, Z. Q.; Shang, Y. Y.; Bai, G. Z.; Liu, X. Y.; Chang, G.; Li, N.; Dai, J. J; et al. Nanoscale 2020, 12 (8), 4882. doi: 10.1039/c9nr07861d doi: 10.1039/c9nr07861d
34. [34]
  Qiu, L.; Liu, J. Z.; Chang, S. L.; Wu, Y. Z.; Li, D. Nat. Commun. 2012, 3, 1241. doi: 10.1038/ncomms2251 doi: 10.1038/ncomms2251
35. [35]
  Kashyap, S.; Kabra, S.; Kandasubramanian, B. J. Mater. Sci. 2020, 55 (10), 4127. doi: 10.1007/s10853-019-04325-7 doi: 10.1007/s10853-019-04325-7
36. [36]
  Yan, F.; Liu, L.; Li, M.; Zhang, M. J.; Shang, L.; Xiao, L. H.; Ao, Y. H. Compos. Part A 2019, 125, 105530. doi: 10.1016/j.compositesa.2019.105530 doi: 10.1016/j.compositesa.2019.105530
37. [37]
  Lu, L.; Shen, Y. F.; Chen, X. H.; Qian, L. H.; Lu, K. Science 2004, 304 (5669), 422. doi: 10.1126/science.1092905 doi: 10.1126/science.1092905
38. [38]
  Chen, C. M.; Zhang, Q.; Yang, M. G.; Huang, C. H.; Yang, Y. G.; Wang, M. Z. Carbon 2012, 50 (10), 3572. doi: 10.1016/j.carbon.2012.03.029 doi: 10.1016/j.carbon.2012.03.029
39. [39]
  Hu, H.; Zhao, Z. B.; Wan, W. B.; Gogotsi, Y.; Qiu, J. S. Adv. Mater. 2013, 25 (15), 2219. doi: 10.1002/adma.201204530 doi: 10.1002/adma.201204530
40. [40]
  Yang, J.; Qi, G. Q.; Bao, R. Y.; Yi, K. Y.; Li, M. L.; Peng, L.; Cai, Z.; Yang, M. B.; Wei, D. C.; Yang, W. Energy Storage Mater. 2018, 13, 88. doi: 10.1016/j.ensm.2017.12.028 doi: 10.1016/j.ensm.2017.12.028
41. [41]
  Zhao, J. L.; Luo, W. J.; Kim, J. K.; Yang, J. L. ACS Appl. Energy Mater. 2019, 2 (5), 3657. doi: 10.1021/acsaem.9b00374 doi: 10.1021/acsaem.9b00374
42. [42]
  Tian, B. Q.; Yang, W. B.; Luo, L. J.; Wang, J.; Zhang, K.; Fan, J. H.; Wu, J. Y.; Xing, T. Sol. Energy 2016, 127, 48. doi: 10.1016/j.solener.2016.01.011 doi: 10.1016/j.solener.2016.01.011
43. [43]
  Biener, J.; Stadermann, M.; Suss, M.; Worsley, M. A.; Biener, M. M.; Rose, K. A.; Baumann, T. F. Energy Environ. Sci. 2011, 4 (3), 656. doi: 10.1039/c0ee00627k doi: 10.1039/c0ee00627k
44. [44]
  Xu, Y.; Fleischer, A. S.; Feng, G. Carbon 2017, 114, 334. doi: 10.1016/j.carbon.2016.11.069 doi: 10.1016/j.carbon.2016.11.069
45. [45]
  Padmajan Sasikala, S.; Poulin, P.; Aymonier, C. Adv. Mater. 2016, 28 (14), 2663. doi: 10.1002/adma.201504436 doi: 10.1002/adma.201504436
46. [46]
  Balandin, A. A. Nat. Mater. 2011, 10 (8), 569. doi: 10.1038/nmat3064 doi: 10.1038/nmat3064
47. [47]
  Zhang, X.; Wan, D. Q.; Peng, K.; Zhang, W. J. Mater. Eng. Perform. 2019, 28 (8), 5165. doi: 10.1007/s11665-019-04212-x doi: 10.1007/s11665-019-04212-x
48. [48]
  Gao, W. W.; Zhao, N. F.; Yao, W. Q.; Xu, Z.; Bai, H.; Gao, C. RSC Adv. 2017, 7 (53), 33600. doi: 10.1039/c7ra05557a doi: 10.1039/c7ra05557a
49. [49]
  Almajali, M.; Lafdi, K.; Prodhomme, P. H.; Ochoa, O. Carbon 2010, 48 (5), 1604. doi: 10.1016/j.carbon.2009.12.060 doi: 10.1016/j.carbon.2009.12.060
50. [50]
  Cao, A. Y.; Dickrell, P. L.; Sawyer, W. G.; Ghasemi-Nejhad, M. N.; Ajayan, P. M. Science 2005, 310 (5752), 1307. doi: 10.1126/science.1118957 doi: 10.1126/science.1118957
51. [51]
  Zhang, Q. Q.; Lin, D.; Deng, B. W.; Xu, X.; Nian, Q.; Jin, S. Y.; Leedy, K. D.; Li, H.; Cheng, G. J. Adv. Mater. 2017, 29 (28), 69469. doi: 10.1002/adma.201605506 doi: 10.1002/adma.201605506
52. [52]
  Park, J. H.; Lee, J. H.; Soon, A. Phys. Chem. Chem. Phys. 2016, 18 (31), 21893. doi: 10.1039/c6cp03249d doi: 10.1039/c6cp03249d
53. [53]
  He, L. J.; Mo, S. P.; Lin, P. C.; Jia, L.; Chen, Y.; Cheng, Z. D. Appl. Energy 2020, 268. 115020. doi: 10.1016/j.apenergy.2020.115020 doi: 10.1016/j.apenergy.2020.115020
54. [54]
  Liang, K.; Shi, L.; Zhang, J. Y.; Cheng, J.; Wang, X. D. Thermochim. Acta 2018, 664, 1. doi: 10.1016/j.tca.2018.04.002 doi: 10.1016/j.tca.2018.04.002
55. [55]
  Shen, J.; Zhang, P.; Song, L. X.; Li, J. P.; Ji, B. Q.; Li, J. J.; Chen, L. Compos. Part B 2019, 179, 107545. doi: 10.1016/j.compositesb.2019.107545 doi: 10.1016/j.compositesb.2019.107545
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