Home

Citation: Zheng Hu. Regulating the Electronic State of Single Metal Sites in Ultrathin Conjugated Microporous Polymer Nanosheets for Catalyzing CO₂ Cycloaddition with High Efficiency[J]. Acta Physico-Chimica Sinica, ;2023, 39(1): 201202. doi: 10.3866/PKU.WHXB202012021 shu

Regulating the Electronic State of Single Metal Sites in Ultrathin Conjugated Microporous Polymer Nanosheets for Catalyzing CO₂ Cycloaddition with High Efficiency

Zheng Hu

School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

Author Bio: Zheng Hu, Email: zhenghu@nju.edu.cn
Available Online: 21 December 2020

1. [1]
  Han, Y.; Wang, Y. G.; Chen, W.; Xu, R.; Zheng, L. R.; Zhang, J.; Luo, J.; Shen, R. A.; Zhu, Y.; Cheong, W. C.; et al. J. Am. Chem. Soc. 2017, 139, 17269. doi: 10.1021/jacs.7b10194 doi: 10.1021/jacs.7b10194
2. [2]
  Deng, D.; Chen, X.; Yu, L.; Wu, X.; Liu, Q.; Liu, Y.; Yang, H.; Tian, H.; Hu, Y.; Du, P.; et al. Sci. Adv. 2015, 1, e1500462. doi: 10.1126/sciadv.1500462 doi: 10.1126/sciadv.1500462
3. [3]
  Zhu, Y. Q.; Sun, W. M.; Luo, J.; Chen, W. X.; Cao, T.; Zheng, L. R.; Dong, J. C.; Zhang, J.; Zhang, M. L.; Han, Y. H.; et al. Nat. Commun. 2018, 9, 3861. doi: 10.1038/s41467-018-06296-w doi: 10.1038/s41467-018-06296-w
4. [4]
  Li, B. B.; Ju, Z. F.; Zhou, M.; Su, K. Z.; Yuan, D. Q. Angew. Chem. Int. Ed. 2019, 58, 7687. doi: 10.1002/anie.201902171 doi: 10.1002/anie.201902171
5. [5]
  Zhang, Z. Q.; Chen, Y. G.; Zhou, L. Q.; Chen, C.; Han, Z.; Zhang, B. S.; Wu, Q.; Yang, L. J.; Du, L. Y.; Bu, Y. F. et al. Nat. Commun. 2019, 10, 1657. doi: 10.1038/s41467-019-09596-x doi: 10.1038/s41467-019-09596-x
6. [6]
  Wu, P. Y.; Li, Y.; Zheng, J. J.; Hosono, N.; Otake, K.; Wang, J.; Liu, Y. H.; Xia, L. L.; Jiang, M.; Sakaki, S.; et al. Nat. Commun. 2019, 10, 4362. doi: 10.1038/s41467-019-12414-z doi: 10.1038/s41467-019-12414-z
7. [7]
  Liu, Q.; Wu, L. P.; Jackstell, R.; Beller M. Nat. Commun. 2015, 6, 5933. doi: 10.1038/ncomms6933 doi: 10.1038/ncomms6933
8. [8]
  Xie, Y.; Wang, T. T.; Liu, X. H.; Zou, K.; Deng, W. Nat. Commun. 2013, 4, 1960. doi: 10.1038/ncomms2960 doi: 10.1038/ncomms2960
9. [9]
  Zhou, Z.; He, C.; Xiu, J. H.; Yang, L.; Duan C. Y. J. Am. Chem. Soc. 2015, 137, 15066. doi: 10.1021/jacs.5b07925 doi: 10.1021/jacs.5b07925
10. [10]
  Li, P. Z.; Wang, X. J.; Liu, J.; Lim, J. S.; Zou, R.; Zhao, Y. J. Am. Chem. Soc. 2016, 138, 2142. doi: 10.1021/jacs.5b13335 doi: 10.1021/jacs.5b13335
11. [11]
  Zhang, X. F.; Liu, H. T.; An, P. F.; Shi, Y. N.; Han, J. Y.; Yang, Z. J. Long, C.; Guo, J.; Zhao, S. L.; Zhao, K.; et al. Sci. Adv. 2020, 6, eaaz4824. doi: 10.1126/sciadv.aaz4824 doi: 10.1126/sciadv.aaz4824
1. [1]
  Jianan Hong , Chenyu Xu , Yan Liu , Changqi Li , Menglin Wang , Yanwei Zhang . Decoding the interfacial competition between hydrogen evolution and CO₂ reduction via edge-active-site modulation in photothermal catalysis. Acta Physico-Chimica Sinica, 2025, 41(9): 100099-0. doi: 10.1016/j.actphy.2025.100099
2. [2]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
3. [3]
  Bizhu Shao , Huijun Dong , Yunnan Gong , Jianhua Mei , Fengshi Cai , Jinbiao Liu , Dichang Zhong , Tongbu Lu . Metal-Organic Framework-Derived Nickel Nanoparticles for Efficient CO₂ Electroreduction in Wide Potential Windows. Acta Physico-Chimica Sinica, 2024, 40(4): 2305026-0. doi: 10.3866/PKU.WHXB202305026
4. [4]
  Qiang Zhang , Yuanbiao Huang , Rong Cao . Imidazolium-Based Materials for CO₂ Electroreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306040-0. doi: 10.3866/PKU.WHXB202306040
5. [5]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-Based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-0. doi: 10.3866/PKU.WHXB202406029
6. [6]
  Yan Kong , Wei Wei , Lekai Xu , Chen Chen . Electrochemical Synthesis of Organonitrogen Compounds from N-integrated CO₂ Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2307049-0. doi: 10.3866/PKU.WHXB202307049
7. [7]
  Hui-Ying Chen , Hao-Lin Zhu , Pei-Qin Liao , Xiao-Ming Chen . Integration of Ru(Ⅱ)-Bipyridyl and Zinc(Ⅱ)-Porphyrin Moieties in a Metal-Organic Framework for Efficient Overall CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306046-0. doi: 10.3866/PKU.WHXB202306046
8. [8]
  Yanhui Guo , Li Wei , Zhonglin Wen , Chaorong Qi , Huanfeng Jiang . Recent Progress on Conversion of Carbon Dioxide into Carbamates. Acta Physico-Chimica Sinica, 2024, 40(4): 2307004-0. doi: 10.3866/PKU.WHXB202307004
9. [9]
  Xiaofei Liu , He Wang , Li Tao , Weimin Ren , Xiaobing Lu , Wenzhen Zhang . Electrocarboxylation of Benzylic Phosphates and Phosphinates with Carbon Dioxide. Acta Physico-Chimica Sinica, 2024, 40(9): 2307008-0. doi: 10.3866/PKU.WHXB202307008
10. [10]
  Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO₂ capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213
11. [11]
  Wei HE , Jing XI , Tianpei HE , Na CHEN , Quan YUAN . Application of solar-driven inorganic semiconductor-microbe hybrids in carbon dioxide fixation and biomanufacturing. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 35-44. doi: 10.11862/CJIC.20240364
12. [12]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
13. [13]
  Hailang JIA , Pengcheng JI , Hongcheng LI . Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1632-1640. doi: 10.11862/CJIC.20240398
14. [14]
  Runhua Chen , Qiong Wu , Jingchen Luo , Xiaolong Zu , Shan Zhu , Yongfu Sun . Defective Ultrathin Two-Dimensional Materials for Photo-/Electrocatalytic CO₂ Reduction: Fundamentals and Perspectives. Acta Physico-Chimica Sinica, 2025, 41(3): 2308052-0. doi: 10.3866/PKU.WHXB202308052
15. [15]
  Ruolin CHENG , Yue WANG , Xiyao NIU , Huagen LIANG , Ling LIU , Shijian LU . Efficient photothermal catalytic CO₂ cycloaddition over W₁₈O₄₉/rGO composites. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1276-1284. doi: 10.11862/CJIC.20240424
16. [16]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
17. [17]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . Remarkable Photocatalytic H₂O₂ Production Efficiency over Ultrathin g-C₃N₄ Nanosheet with Large Surface Area and Enhanced Crystallinity by Two-Step Calcination. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-0. doi: 10.3866/PKU.WHXB202406019
18. [18]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
19. [19]
  Qing Li , Guangxun Zhang , Yuxia Xu , Yangyang Sun , Huan Pang . P-Regulated Hierarchical Structure Ni₂P Assemblies toward Efficient Electrochemical Urea Oxidation. Acta Physico-Chimica Sinica, 2024, 40(9): 2308045-0. doi: 10.3866/PKU.WHXB202308045
20. [20]
  Hui Wang , Abdelkader Labidi , Menghan Ren , Feroz Shaik , Chuanyi Wang . Recent Progress of Microstructure-Regulated g-C₃N₄ in Photocatalytic NO Conversion: The Pivotal Roles of Adsorption/Activation Sites. Acta Physico-Chimica Sinica, 2025, 41(5): 100039-0. doi: 10.1016/j.actphy.2024.100039

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(493)
HTML views(54)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return

Regulating the Electronic State of Single Metal Sites in Ultrathin Conjugated Microporous Polymer Nanosheets for Catalyzing CO2 Cycloaddition with High Efficiency

Metrics

通讯作者: 陈斌, bchen63@163.com

Regulating the Electronic State of Single Metal Sites in Ultrathin Conjugated Microporous Polymer Nanosheets for Catalyzing CO₂ Cycloaddition with High Efficiency