Citation: Xinrun Yu, Jun Ma, Chunbo Mou, Guanglei Cui. Percolation Structure Design of Organic-inorganic Composite Electrolyte with High Lithium-Ion Conductivity[J]. Acta Physico-Chimica Sinica, ;2022, 38(3): 191206. doi: 10.3866/PKU.WHXB201912061 shu

Percolation Structure Design of Organic-inorganic Composite Electrolyte with High Lithium-Ion Conductivity

Xinrun Yu ^{1, 2} ,
Jun Ma ^2,, ,
Chunbo Mou ¹ ,
Guanglei Cui ^2,,

1.
College of Materials Science and Engineering, Qingdao University, Qingdao 266071, Shandong Province, China
2.
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao Industrial Energy Storage Technology Institute, Qingdao 266101, Shandong Province, China

Corresponding author: Jun Ma, majun@qibebt.ac.cn Guanglei Cui, cuigl@qibebt.ac.cn
Received Date: 25 December 2019
Revised Date: 14 January 2020
Accepted Date: 15 January 2020
Available Online: 10 March 2020
Fund Project: the National Natural Science Foundation of China 51625204

With the increasing demand for safe high energy density energy storage systems, solid-state lithium metal batteries have attracted extensive attention. The solid electrolyte, which is expected to replace the traditional liquid organic electrolyte core in solid-state lithium metal batteries because of its excellent mechanical properties and non-flammability. Lithium-ion solid-state electrolytes can be categorized into two broad types: inorganic electrolytes and polymer electrolytes. Inorganic solid electrolytes have the advantages of high room-temperature ionic conductivity, wide electrochemical window, and high mechanical strength. However, their high brittleness, high solid-solid interface contact resistance, complex preparation process, and high cost make future development and practical applications challenging. In contrast to inorganic electrolytes, polymer electrolytes are easy to process and exhibit better flexibility and easy formation of a good, stable interface with lithium metal. However, solid polymer electrolytes still exhibit insufficient ionic conductivity at room temperatures compared with polymer solid electrolytes. Therefore, neither the inorganic electrolytes nor the polymer electrolytes alone can meet the requirements of high-performance solid-state lithium metal batteries. Recently, dispersing ceramic fillers (especially fast lithium-ion conductors) in a polymer matrix to integrate with composite polymer electrolytes has been developed as an effective strategy for enhancing room-temperature ionic conductivity, mechanical properties, and thermal stability of solid polymer electrolytes. Inorganic fillers do not only reduce the polymer matrix crystallization but also improve the lithium-ion conductivity by promoting the dissociation of lithium salts. The Lewis acid-base groups and oxygen vacancy at the surface of inorganic fillers can increase the migration number of lithium ions. Nevertheless, the effect of the percolation structure of inorganic fillers on the conductivity of organic-inorganic composite electrolytes should be discussed. It is believed that the organic-inorganic interface is the main reason for the significantly enhanced lithium-ion conductivity of composite electrolytes based on the percolation theory. In this paper, from the perspective of percolation structure design, we summarize the progress on high lithium-ion conductive organic-inorganic composite electrolytes with different dimensional-structured inorganic fillers. From one-dimensional filler to three-dimensional filler, the ionic conductivity of a composite electrolyte can be significantly influenced by the rational design and optimization of the percolation structure and orientation of the inorganic filler. Vertically aligned inorganic fillers provide optimal ion transport pathways in the polymer matrix, significantly improving the lithium-ion conductivity of the composite electrolytes. Furthermore, the advantages and disadvantages of the different percolation structures are compared and discussed objectively. Finally, future development trends of organic-inorganic composite electrolytes are discussed.
- Inorganic nano-filler,
- Polymer electrolyte,
- Composite electrolyte,
- High lithium-ion conductivity
1. [1]
  Cheng, F.; Liang, J.; Tao, Z.; Chen, J. Adv. Mater. 2011, 23, 1695. doi: 10.1002/adma.201003587 doi: 10.1002/adma.201003587
2. [2]
  Tarascon, J. M.; Armand, M. Nature 2001, 414, 359. doi: 10.1038/35104644 doi: 10.1038/35104644
3. [3]
  Lin, D.; Liu, Y.; Cui, Y. Nat. Nanotechnol. 2017, 12, 194. doi: 10.1038/nnano.2017.16 doi: 10.1038/nnano.2017.16
4. [4]
  Liu, B.; Zhang, J. G.; Xu, W. Joule 2018, 2, 833. doi: 10.1016/j.joule.2018.03.008 doi: 10.1016/j.joule.2018.03.008
5. [5]
  Fan, L.; Wei, S.; Li, S.; Li, Q.; Lu, Y. Adv. Energy Mater. 2018, 8, 1702657. doi: 10.1002/aenm.201702657 doi: 10.1002/aenm.201702657
6. [6]
  Chen, S.; Wen, K.; Fan, J.; Bando, Y.; Golberg, D. J. Mater. Chem. A 2018, 6, 11631. doi: 10.1039/c8ta03358g doi: 10.1039/c8ta03358g
7. [7]
  Nowak, S.; Winter, M. J. Electrochem. Soc. 2015, 162 (14), A2500. doi: 10.1149/2.0121514jes doi: 10.1149/2.0121514jes
8. [8]
  Schroeder, D. J.; Hubaud, A. A.; Vaughey, J. T. Mater. Res. Bull. 2014, 49, 614. doi: 10.1016/j.materresbull.2013.10.006 doi: 10.1016/j.materresbull.2013.10.006
9. [9]
  Cui, W. Y.; An, M. Z.; Yang, P. X. Acta Phys. -Chim. Sin. 2010, 26 (5), 1233. doi: 10.3866/PKU.WHXB20100530
10. [10]
  Chen, R.; Qu, W.; Guo, X.; Li, L.; Wu, F. Mater. Horiz. 2016, 3, 487. doi: 10.1039/c6mh00218h doi: 10.1039/c6mh00218h
11. [11]
  Hu, Y. S. Nat. Energy 2016, 1, 16042. doi: 10.1038/nenergy.2016.42 doi: 10.1038/nenergy.2016.42
12. [12]
  Janek, J.; Zeier, W. G. Nat. Energy 2016, 1, 16141. doi: 10.1038/nenergy.2016.141 doi: 10.1038/nenergy.2016.141
13. [13]
  Zhou, D.; Shanmukaraj, D.; Tkacheva, A.; Armand, M.; Wang, G. Chemistry 2019, 5, 2326. doi: 10.1016/j.chempr.2019.05.009 doi: 10.1016/j.chempr.2019.05.009
14. [14]
  Cheng, X. B.; Zhao, C. Z.; Yao, Y. X.; Liu, H.; Zhang, Q. Chemistry 2019, 5, 74. doi: 10.1016/j.chempr.2018.12.002 doi: 10.1016/j.chempr.2018.12.002
15. [15]
  Zhu, Y.; He, X.; Mo, Y. ACS Appl. Mater. Interfaces 2015, 7, 23685. doi: 10.1021/acsami.5b07517 doi: 10.1021/acsami.5b07517
16. [16]
  Bachman, J. C.; Muy, S.; Grimaud, A.; Chang, H. H.; Pour, N.; Lux, S. F.; Paschos, O.; Maglia, F.; Lupart, S.; Lamp, P.; et al. Chem. Rev. 2016, 116, 140. doi: 10.1021/acs.chemrev.5b00563 doi: 10.1021/acs.chemrev.5b00563
17. [17]
  Chinnam, P. R.; Wunder, S. L. ACS Energy Lett. 2016, 2, 134. doi: 10.1021/acsenergylett.6b00609 doi: 10.1021/acsenergylett.6b00609
18. [18]
  Han, F.; Zhu, Y.; He, X.; Mo, Y.; Wang, C. Adv. Energy Mater. 2016, 6(8), 1501590. doi: 10.1002/aenm.201501590 doi: 10.1002/aenm.201501590
19. [19]
  Yao, X.; Huang, B.; Yin, J.; Peng, G.; Huang, Z.; Gao, C.; Liu, D.; Xu, X. Chin. Phys. B 2016, 25, 018802. doi: 10.1088/1674-1056/25/1/018802 doi: 10.1088/1674-1056/25/1/018802
20. [20]
  Hu, P.; Chai, J.; Duan, Y.; Liu, Z.; Cui, G.; Chen, L. J. Mater. Chem. A 2016, 4, 10070. doi: 10.1039/c6ta02907h doi: 10.1039/c6ta02907h
21. [21]
  Zhang, X.; Wang, S.; Xue, C.; Xin, C.; Lin, Y.; Shen, Y.; Li, L.; Nan, C. W. Adv. Mater. 2019, 31, e1806082. doi: 10.1002/adma.201806082 doi: 10.1002/adma.201806082
22. [22]
  Zhang, W.; Nie, J.; Li, F.; Wang, Z. L.; Sun, C. Nano Energy 2018, 45, 413. doi: 10.1016/j.nanoen.2018.01.028 doi: 10.1016/j.nanoen.2018.01.028
23. [23]
  Fei, H. F.; Liu, Y. P.; Wei, C. L.; Zhang, Y. C.; Feng, J. K.; Chen, C. Z.; Yu, H. J. Acta Phys. -Chim. Sin. 2020, 36 (5), 1905015. doi: 10.3866/PKU.WHXB201905015
24. [24]
  Quartarone, E.; Mustarelli, P. Chem. Soc. Rev. 2011, 40, 2525. doi: 10.1039/c0cs00081g doi: 10.1039/c0cs00081g
25. [25]
  Zhou, Q.; Ma, J.; Dong, S.; Li, X.; Cui, G. Adv. Mater. 2019, 31(50), 1902029. doi: 10.1002/adma.201902029 doi: 10.1002/adma.201902029
26. [26]
  Hu, T. S.; Hong, P. K.; Saikia, D.; Kao, H. M.; Chen, M. C. Ionics 2014, 20, 1561. doi: 10.1007/s11581-014-1107-2 doi: 10.1007/s11581-014-1107-2
27. [27]
  Masoud, E. M.; El-Bellihi, A. A.; Bayoumy, W. A.; Mousa, M. A. J. Alloy. Compd. 2013, 575, 223. doi: 10.1016/j.jallcom.2013.04.054 doi: 10.1016/j.jallcom.2013.04.054
28. [28]
  Zhang, X.; Liu, T.; Zhang, S.; Huang, X.; Xu, B.; Lin, Y.; Xu, B.; Li, L.; Nan, C. W.; Shen, Y. J. Am. Chem. Soc. 2017, 139, 13779. doi: 10.1021/jacs.7b06364 doi: 10.1021/jacs.7b06364
29. [29]
  Zheng, J.; Tang, M.; Hu, Y. Y. Angew. Chem. Int. Ed. 2016, 55, 12538. doi: 10.1002/anie.201607539 doi: 10.1002/anie.201607539
30. [30]
  Zhao, Y.; Wu, C.; Peng, G.; Chen, X.; Yao, X.; Bai, Y.; Wu, F.; Chen, S.; Xu, X. J. Power Sources 2016, 301, 47. doi: 10.1016/j.jpowsour.2015.09.111 doi: 10.1016/j.jpowsour.2015.09.111
31. [31]
  Dieterich, W.; Dürr, O.; Pendzig, P.; Bunde, A.; Nitzan, A. Phys. A 1999, 266, 229. doi: 10.1016/S0378-4371(98)00597-4 doi: 10.1016/S0378-4371(98)00597-4
32. [32]
  Li, Z.; Huang, H.; Zhu, J.; Wu, J.; Yang, H.; Wei, L.; Guo, X. ACS Appl. Mater. Interfaces 2018, 11 (1), 784. doi: 10.1021/acsami.8b17279 doi: 10.1021/acsami.8b17279
33. [33]
  Kitajima, S.; Kitaura, H.; Im, D.; Hwang, Y.; Ishida, M.; Zhou, H. Solid State Ionics 2018, 316, 29. doi: 10.1016/j.ssi.2017.12.018 doi: 10.1016/j.ssi.2017.12.018
34. [34]
  Chen, L.; Li, Y.; Li, S. P.; Fan, L. Z.; Nan, C. W.; Goodenough, J. B. Nano Energy 2018, 46, 176. doi: 10.1016/j.nanoen.2017.12.037 doi: 10.1016/j.nanoen.2017.12.037
35. [35]
  Liu, X.; Peng, S.; Gao, S.; Cao, Y.; You, Q.; Zhou, L.; Jin, Y.; Liu, Z.; Liu, J. ACS Appl. Mater. Interfaces 2018, 10, 15691. doi: 10.1021/acsami.8b01631 doi: 10.1021/acsami.8b01631
36. [36]
  Zhai, H.; Xu, P.; Ning, M.; Cheng, Q.; Mandal, J.; Yang, Y. Nano Lett. 2017, 17, 3182. doi: 10.1021/acs.nanolett.7b00715 doi: 10.1021/acs.nanolett.7b00715
37. [37]
  Liu, W.; Liu, N.; Sun, J.; Hsu, P. C.; Li, Y.; Lee, H. W.; Cui, Y. Nano Lett. 2015, 15, 2740. doi: 10.1021/acs.nanolett.5b00600 doi: 10.1021/acs.nanolett.5b00600
38. [38]
  Zhu, P.; Yan, C.; Dirican, M.; Zhu, J.; Zang, J.; Selvan, R. K.; Chung, C. C.; Jia, H.; Li, Y.; Kiyak, Y.; et al. J. Mater. Chem. A 2018, 6, 4279. doi: 10.1039/c7ta10517g doi: 10.1039/c7ta10517g
39. [39]
  Liu, W.; Lee, S. W.; Lin, D.; Shi, F.; Wang, S.; Sendek, A. D.; Cui, Y. Nat. Energy 2017, 2, 17035. doi: 10.1038/nenergy.2017.35 doi: 10.1038/nenergy.2017.35
40. [40]
  Tang, W.; Tang, S.; Zhang, C.; Ma, Q.; Xiang, Q.; Yang, Y. W.; Luo, J. Adv. Energy Mater. 2018, 8, 1800866. doi: 10.1002/aenm.201800866 doi: 10.1002/aenm.201800866
41. [41]
  Tang, W.; Tang, S.; Guan, X.; Zhang, X.; Xiang, Q.; Luo, J. Adv. Funct. Mater. 2019, 29, 1900648. doi: 10.1002/adfm.201900648 doi: 10.1002/adfm.201900648
42. [42]
  Jia, W.; Li, Z.; Wu, Z.; Wang, L.; Wu, B.; Wang, Y.; Cao, Y.; Li, J. Solid State Ionics 2018, 315, 7. doi: 10.1016/j.ssi.2017.11.026 doi: 10.1016/j.ssi.2017.11.026
43. [43]
  Kammoun, M.; Berg, S.; Ardebili, H. Nanoscale 2015, 7, 17516. doi: 10.1039/c5nr04339e doi: 10.1039/c5nr04339e
44. [44]
  Cheng, S.; Smith, D. M.; Li, C. Y. Macromolecule 2015, 48, 4503. doi: 10.1021/acs.macromol.5b00972 doi: 10.1021/acs.macromol.5b00972
45. [45]
  Yuan, M.; Erdman, J.; Tang, C.; Ardebili, H. RSC Adv. 2014, 4, 59637. doi: 10.1039/c4ra07919a doi: 10.1039/c4ra07919a
46. [46]
  Li, A.; Liao, X.; Zhang, H.; Shi, L.; Wang, P.; Cheng, Q.; Borovilas, J.; Li, Z.; Huang, W.; Fu, Z.; et al. Adv. Mater. 2019, 32, 1905517. doi: 10.1002/adma.201905517 doi: 10.1002/adma.201905517
47. [47]
  Zekoll, S.; Marriner-Edwards, C.; Hekselman, A. K. O.; Kasemchainan, J.; Kuss, C.; Armstrong, D. E. J.; Cai, D.; Wallace, R. J.; Richter, F. H.; Thijssen, J. H. J.; et al. Energy Environ. Sci. 2018, 11, 185. doi: 10.1039/c7ee02723k doi: 10.1039/c7ee02723k
48. [48]
  Xie, H.; Yang, C.; Fu, K.; Yao, Y.; Jiang, F.; Hitz, E.; Liu, B.; Wang, S.; Hu, L. Adv. Energy Mater. 2018, 8, 1703474. doi: 10.1002/aenm.201703474 doi: 10.1002/aenm.201703474
49. [49]
  Bae, J.; Li, Y.; Zhang, J.; Zhou, X.; Zhao, F.; Shi, Y.; Goodenough, J. B.; Yu, G. Angew. Chem. Int. Ed. 2018, 57, 2096. doi: 10.1002/anie.201710841 doi: 10.1002/anie.201710841
50. [50]
  Zhou, Q.; Zhang, J.; Cui, G. Macromol. Mater. Eng. 2018, 303, 1800337. doi: 10.1002/mame.201800337 doi: 10.1002/mame.201800337
51. [51]
  Duan, H.; Fan, M.; Chen, W. P.; Li, J. Y.; Wang, P. F.; Wang, W. P.; Shi, J. L.; Yin, Y. X.; Wan, L. J.; Guo, Y. G. Adv. Mater. 2019, 31, e1807789. doi: 10.1002/adma.201807789 doi: 10.1002/adma.201807789
52. [52]
  Zhou, W.; Wang, Z.; Pu, Y.; Li, Y.; Xin, S.; Li, X.; Chen, J.; Goodenough, J. B. Adv. Mater. 2018, 31, 1805574. doi: 10.1002/adma.201805574 doi: 10.1002/adma.201805574
1. [1]
  Hanmei Lü , Xin Chen , Qifu Sun , Ning Zhao , Xiangxin Guo . Uniform Garnet Nanoparticle Dispersion in Composite Polymer Electrolytes. Acta Physico-Chimica Sinica, 2024, 40(3): 2305016-0. doi: 10.3866/PKU.WHXB202305016
2. [2]
  Ke Qiu , Fengmei Wang , Mochou Liao , Kerun Zhu , Jiawei Chen , Wei Zhang , Yongyao Xia , Xiaoli Dong , Fei Wang . A Fumed SiO₂-based Composite Hydrogel Polymer Electrolyte for Near-Neutral Zinc-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(3): 2304036-0. doi: 10.3866/PKU.WHXB202304036
3. [3]
  Zhaoxuan ZHU , Lixin WANG , Xiaoning TANG , Long LI , Yan SHI , Jiaojing SHAO . Application of poly(vinyl alcohol) conductive hydrogel electrolytes in zinc ion batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 893-902. doi: 10.11862/CJIC.20240368
4. [4]
  Zhi Dou , Huiyu Duan , Yixi Lin , Yinghui Xia , Mingbo Zheng , Zhenming Xu . High-Throughput Screening Lithium Alloy Phases and Investigation of Ion Transport for Solid Electrolyte Interphase Layer. Acta Physico-Chimica Sinica, 2024, 40(3): 2305039-0. doi: 10.3866/PKU.WHXB202305039
5. [5]
  Yu Peng , Jiawei Chen , Yue Yin , Yongjie Cao , Mochou Liao , Congxiao Wang , Xiaoli Dong , Yongyao Xia . Tailored cathode electrolyte interphase via ethylene carbonate-free electrolytes enabling stable and wide-temperature operation of high-voltage LiCoO₂. Acta Physico-Chimica Sinica, 2025, 41(8): 100087-0. doi: 10.1016/j.actphy.2025.100087
6. [6]
  Tao Jiang , Yuting Wang , Lüjin Gao , Yi Zou , Bowen Zhu , Li Chen , Xianzeng Li . Experimental Design for the Preparation of Composite Solid Electrolytes for Application in All-Solid-State Batteries: Exploration of Comprehensive Chemistry Laboratory Teaching. University Chemistry, 2024, 39(2): 371-378. doi: 10.3866/PKU.DXHX202308057
7. [7]
  Xinran Zhang , Siqi Liu , Yichi Chen , Qingli Zou , Qinghong Xu , Yaqin Huang . From Protein to Energy Storage Materials: Edible Gelatin Jelly Electrolyte. University Chemistry, 2025, 40(7): 255-266. doi: 10.12461/PKU.DXHX202408104
8. [8]
  Jiandong Liu , Zhijia Zhang , Kamenskii Mikhail , Volkov Filipp , Eliseeva Svetlana , Jianmin Ma . Research Progress on Cathode Electrolyte Interphase in High-Voltage Lithium Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 2308048-0. doi: 10.3866/PKU.WHXB202308048
9. [9]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . Sulfide Solid Electrolyte Synthesized by Liquid Phase Approach and Application in All-Solid-State Lithium Batteries. Acta Physico-Chimica Sinica, 2025, 41(1): 100004-0. doi: 10.3866/PKU.WHXB202309019
10. [10]
  Changsheng An , Tao Liu . Decoding SEI chemistry at the lithium-metal potential. Acta Physico-Chimica Sinica, 2025, 41(9): 100101-0. doi: 10.1016/j.actphy.2025.100101
11. [11]
  Da Wang , Xiaobin Yin , Jianfang Wu , Yaqiao Luo , Siqi Shi . All-Solid-State Lithium Cathode/Electrolyte Interfacial Resistance: From Space-Charge Layer Model to Characterization and Simulation. Acta Physico-Chimica Sinica, 2024, 40(7): 2307029-0. doi: 10.3866/PKU.WHXB202307029
12. [12]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 2408007-0. doi: 10.3866/PKU.WHXB202408007
13. [13]
  Yajie Li , Bin Chen , Yiping Wang , Hui Xing , Wei Zhao , Geng Zhang , Siqi Shi . Inhibiting Dendrite Growth by Customizing Electrolyte or Separator to Achieve Anisotropic Lithium-Ion Transport: A Phase-Field Study. Acta Physico-Chimica Sinica, 2024, 40(3): 2305053-0. doi: 10.3866/PKU.WHXB202305053
14. [14]
  Fanpeng Meng , Fei Zhao , Jingkai Lin , Jinsheng Zhao , Huayang Zhang , Shaobin Wang . Optimizing interfacial electric fields in carbon nitride nanosheet/spherical conjugated polymer S-scheme heterojunction for hydrogen evolution. Acta Physico-Chimica Sinica, 2025, 41(8): 100095-0. doi: 10.1016/j.actphy.2025.100095
15. [15]
  Xianyong Lu , Tao Hu . Developing an Innovative Inorganic Chemistry Teaching Model Based on Aerospace Specialty Characteristics. University Chemistry, 2025, 40(7): 127-131. doi: 10.12461/PKU.DXHX202409037
16. [16]
  Kai PENG , Xinyi ZHAO , Zixi CHEN , Xuhai ZHANG , Yuqiao ZENG , Jianqing JIANG . Progress in the application of high-entropy alloys and high-entropy ceramics in water electrolysis. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1257-1275. doi: 10.11862/CJIC.20240454
17. [17]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
18. [18]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-0. doi: 10.3866/PKU.WHXB202311030
19. [19]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
20. [20]
  Xin Feng , Kexin Guo , Chunguang Jia , Bowen Liu , Suqin Ci , Junxiang Chen , Zhenhai Wen . Hydrogen Generation Coupling with High-Selectivity Electrocatalytic Glycerol Valorization into Formate in an Acid-Alkali Dual-Electrolyte Flow Electrolyzer. Acta Physico-Chimica Sinica, 2024, 40(5): 2303050-0. doi: 10.3866/PKU.WHXB202303050

Get Citation

PDF

XML

Metrics

PDF Downloads(34)
Abstract views(1035)
HTML views(186)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142