Citation: Xu henmin, Bian Zhenfeng. Photocatalytic Methane Conversion[J]. Acta Physico-Chimica Sinica, ;2020, 36(3): 190701. doi: 10.3866/PKU.WHXB201907013 shu

Photocatalytic Methane Conversion

Xu henmin ,
Bian Zhenfeng ^,

Laboratory of Resource Chemistry, Ministry of Education, Shanghai Normal University, Shanghai 200234, P. R. China

Corresponding author: Bian Zhenfeng, bianzhenfeng@shnu.edu.cn
Received Date: 1 July 2019
Revised Date: 13 August 2019
Accepted Date: 29 August 2019
Available Online: 2 March 2019
Fund Project: the National Natural Science Foundation of China 21761142011Shanghai Government, China 19160712900the National Natural Science Foundation of China 51572174The project was supported by the National Natural Science Foundation of China (21876114, 21761142011, 51572174), Shanghai Government, China (19160712900), International Joint Laboratory on Resource Chemistry, China (IJLRC), and the Program for Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning, Chinathe National Natural Science Foundation of China 21876114

Methane is a promising energy source with vast reserves, and is considered one of the promising alternatives to nonrenewable petroleum resources because it can be converted into valuable hydrocarbon feedstocks and hydrogen through appropriate reactions. Recently, the conversion of CH₄ into other high-value-added products has received increasing attention because of their sustainability for energy and the environment. However, methane has a tetrahedral geometry with four equivalent C―H bonds due to the sp³ hybridization of the central carbon atom, with a C―H bond length of 0.1087 nm and an H-C―H bond angle of 109.5°. The absence of a dipole moment and the small polarizability (2.84 × 10⁻⁴⁰ C²·m²·J⁻¹) imply that methane requires a high local electric field for polarization and for nucleophilic or electrophilic attack. Nevertheless, it is believed that an effective method to activate CH₄ would be available, so that not only methanol, formaldehyde, and ethylene but also other industrially valuable raw materials can be obtained. On the other hand, the conversion of this combustible gas into the corresponding liquid fossil fuel proceeds via secondary chemical conversion, and it can greatly reduce transportation costs. From the economic viewpoint, this can still provide considerable benefits. Homogeneous catalysts have been reported to catalyze methane, but most of them operate at high pressures (2–7 MPa), or in strongly acidic media and at high temperatures (up to 500 K). Heterogeneous catalysts reported in the literature are also active only at high temperatures. Therefore, finding an efficient method to active methane has become a hot research topic. Photocatalysis technology is recognized as the optimal solution for the conversion of CH₄ since solar energy is by far the largest exploitable resource of energy. In the past years, much effort has been undertaken for the conversion of CH₄ under light at low temperature. In this regard, several photocatalysts, including silica-alumina-titania, silica-supported oxides, and ceria- and zeolite-based materials, have been developed. In photocatalytic methane conversion, the C―H bond can be selectively activated by adjusting the wavelength and intensity of the incident light and the oxidation capacity of the photocatalysts, thereby avoiding the formation of byproducts. This review summarizes a series of photocatalytic direct methane conversion systems developed in recent years, including methane oxidation and coupling processes. The effects of the catalyst composition and structure, oxidant, and electron transfer on the activation of the C―H bond of methane are detailed. Finally, future perspectives and challenges for the photocatalytic conversion of methane are discussed.
- Photocatalysis,
- Methane conversion,
- Oxidation to methanol,
- Anaerobic coupling,
- Oxidative coupling
1. [1]
  Xiao, G.; Guan, F.; Gang, L.; Hao, M.; Hong, F.; Liang, Y.; Chao, M.; Xing, W.; De, D.; Ming, W.; et al. Science 2014, 334, 616. doi: 10.1126/science.1253150 doi: 10.1126/science.1253150
2. [2]
  Golisz, S. R.; Brent, G. T.; Goddard, W. A.; Groves, J. T.; Periana, R. A. Catal. Lett. 2010, 141, 213. doi: 10.1007/s10562-010-0499-5 doi: 10.1007/s10562-010-0499-5
3. [3]
  Patrick, G.; Michel, P. Appl. Catal. B: Environ. 2002, 39, 1. doi: 10.1016/S0926-3373(02)00076-0 doi: 10.1016/S0926-3373(02)00076-0
4. [4]
  Cullis, C. F.; Willatt, B. M. J. Cat. 1983, 83, 267. doi: 10.1016/0021-9517(83)90054-4 doi: 10.1016/0021-9517(83)90054-4
5. [5]
  Andrey, J. Z.; Jackie, Y. Y. Nature 2000, 43, 6765. doi: 10.1038/47450 doi: 10.1038/47450
6. [6]
  Tao, F. F.; Shan, J. J.; Nguyen, L.; Wang, Z.; Zhang, S.; Zhang, L.; Wu, Z.; Huang, W.; Zeng, S.; Hu, P. Nat. Commun. 2015, 6, 7798. doi: 10.1038/ncomms8798 doi: 10.1038/ncomms8798
7. [7]
  Wang, H.; Chen, C.; Zhang, Y.; Peng, L.; Ma, S.; Yang, T.; Guo, H.; Zhang, Z.; Su, D. S.; Zhang, J. Nat. Commun. 2015, 6, 7181. doi: 10.1038/ncomms8181 doi: 10.1038/ncomms8181
8. [8]
  Cargnello, M.; Delgado, J. J.; Hernandez, J. C. Bakhmutsky, K.; Montini, T.; Calvino, J. J.; Gorte, R. J.; Fornasiero, P. Science 2012, 337, 713. doi: 10.1126/science.1222887 doi: 10.1126/science.1222887
9. [9]
  Narsimhan, K.; Iyoki, K.; Dinh, K.; Roman, L. Y. ACS Cent. Sci. 2016, 2, 424. doi: 10.1021/acscentsci.6b00139 doi: 10.1021/acscentsci.6b00139
10. [10]
  Baek, J.; Rung, B.; Pei, X.; Park, M.; Fakra, S. C.; Liu, Y. S.; Matheu, R.; Alshmimri, S. A.; Alshehri, S; Trickett, C. A.; et al. J. Am. Chem. Soc. 2018, 140, 18208. doi: 10.1021/jacs.8b11525 doi: 10.1021/jacs.8b11525
11. [11]
  Chen, X.; Li, Y.; Pan, X.; Cortie, D.; Huang, X.; Yi, Z. Nat. Commun. 2016, 7, 12273. doi: 10.1038/ncomms12273 doi: 10.1038/ncomms12273
12. [12]
  Shan, J.; Li, M.; Allard, L. F.; Lee, S.; Flytzani, S. M. Nature 2017, 551, 605. doi: 10.1038/nature24640 doi: 10.1038/nature24640
13. [13]
  Sh, Q. W.; Xian, T.; Ju, C. H.; Wang, L.; Zhang, J. L. J. Am. Chem. Soc. 2019, 141, 6592. doi: 10.1021/jacs.8b13858 doi: 10.1021/jacs.8b13858
14. [14]
  Ji, X.; Jin, R.; Li, A.; Bi, Y.; Ruan, Q.; Deng, Y.; Zhang, Y.; Yao, S.; Sankar, G.; Ma, D.; Tang, J. Nat. Catal. 2018, 1, 889. doi: 10.1038/s41929-018-0170-x doi: 10.1038/s41929-018-0170-x
15. [15]
  Hansan, L.; Chao, S.; Lei, Z.; Jiu, Z.; Hai, W.; Wilkinson, D. P. J. Power Sources 2006, 155, 95. doi: 10.1016/j.jpowsour.2006.01.030 doi: 10.1016/j.jpowsour.2006.01.030
16. [16]
  Nishth, A.; Simon, J. F.; Rebecca, U. M.; Sultan, M. A.; Nikolaos, D.; Qian, H.; David, J. M.; Robert, L. J.; David, J. W.; Stuart, H. T.; et al. Science 2017, 358, 223. doi: 10.1126/science doi: 10.1126/science
17. [17]
  Newton, M. A.; Knorpp, A. J.; Pinar, A. B.; Sushkevich, V. L.; Palagin, D.; Bokhoven, J. A. J. Am. Chem. Soc. 2018, 140, 10090. doi: 10.1021/jacs.8b05139 doi: 10.1021/jacs.8b05139
18. [18]
  Vanelderen, P.; Snyder, B. E.; Tsai, M. L.; Hadt, R. G.; Van, J.; Coussens, O.; Schoonheydt, R. A.; Sels, B. F.; Solomon, E. I. J. Am. Chem. Soc. 2015, 137, 6383. doi: 10.1021/jacs.5b02817 doi: 10.1021/jacs.5b02817
19. [19]
  Snyder, B. E.; Vanelderen, P.; Bols, M. L.; Hallaert, S. D.; Bottger, L. H.; Ungur, L.; Pierloot, K.; Schoonheydt, R. A.; Sels, B. F.; Solomon, E. I. Nature 2016, 536, 317. doi: 10.1038/nature19059 doi: 10.1038/nature19059
20. [20]
  Michael, M.; Thomas, S.; Wolf, A. H. Angew. Chem. Int. Ed. 2002, 41, 1475. doi: 10.1002/1521-3773 doi: 10.1002/1521-3773
21. [21]
  Vitaly, L. S.; Dennis, P.; Marco, R.; Jeroen, A. B. Science 2017, 356, 523. doi: 10.1126/science.aam9035 doi: 10.1126/science.aam9035
22. [22]
  Huang, W.; Zhang, S.; Tang, Y.; Li, Y.; Nguyen, L.; Li, Y.; Shan, J.; Xiao, D.; Gagne, R.; Anatoly, I. F.; et al. Angew. Chem. Int. Ed. 2016, 55, 13441. doi: 10.1002/anie.201604708 doi: 10.1002/anie.201604708
23. [23]
  Zimmermann, T.; Soorholtz, M.; Bilke, M.; Schuth, F. J. Am. Chem. Soc. 2016, 138, 12395. doi: 10.1021/jacs.6b05167 doi: 10.1021/jacs.6b05167
24. [24]
  Rahim, M. H.; Armstrong, R. D.; Hammond, C.; Dimitratos, N.; Freakley, S. J.; Forde, M. M.; Morgan, D. J.; Lalev, G.; Jenkins, R. L.; Lopez, J. A.; et al. Catal. Sci. Technol. 2016, 6, 3410. doi: 10.1039/c5cy01586c doi: 10.1039/c5cy01586c
25. [25]
  Liu, C.; Mou, C. Y.; Yu, S. F.; Chan, S. I. Energy Environ. Sci. 2016, 9, 1361. doi: 10.1039/c5ee03372a doi: 10.1039/c5ee03372a
26. [26]
  Grundner, S.; Markovits, M. A.; Li, G.; Tromp, M.; Pidko, E. A.; Hensen, E. J.; Jentys, A.; Sanchez, M.; Lercher, J. A. Nat. Commun. 2015, 6, 7546. doi: 10.1038/ncomms8546 doi: 10.1038/ncomms8546
27. [27]
  Kaliaguine, S. L.; Shelomov. B. N.; Kazansky. V. B. J. Catal. 1978, 55, 384. doi: 10.1016/0021-9517(78)90225-7 doi: 10.1016/0021-9517(78)90225-7
28. [28]
  Heactor, H. L.; Agustõan, M. Catal. Lett. 2002, 83, 37. doi: 10.1023/A:1020649313699 doi: 10.1023/A:1020649313699
29. [29]
  Hu, Y.; Nagai, Y.; Rahmawaty, D.; Wei, C.; Anpo, M. Catal. Lett. 2008, 124, 80. doi: 10.1007/s10562-008-9491-8: doi: 10.1007/s10562-008-9491-8:
30. [30]
  Richard, P. N.; Charles, E. T.; Joseph, R. D. Catal. Today 1997, 33, 167. doi: 10.1016/S0920-5861(96)00155-1 doi: 10.1016/S0920-5861(96)00155-1
31. [31]
  Villa, K.; Murcia, L. S.; Remon, M. J.; Andreu, T. Appl. Catal. B: Environ. 2016, 187, 30. doi: 10.1016/j.apcatb.2016.01.032 doi: 10.1016/j.apcatb.2016.01.032
32. [32]
  Xuan, L.; Chen, G.; Liang, Y.; Zhen, J.; Jin, L. Adv. Funct. Mater. 2010, 20, 2815. doi: 10.1002/adfm.201000792 doi: 10.1002/adfm.201000792
33. [33]
  Chen, Y.; Zeng, D.; Zhang, K.; Lu, A.; Wang, L.; Peng, D. L. Nanoscale 2014, 6, 874. doi: 10.1039/c3nr04558g doi: 10.1039/c3nr04558g
34. [34]
  Li, G.; Tang, Z. Nanoscale 2014, 6, 3995. doi: 10.1039/c3nr06787d doi: 10.1039/c3nr06787d
35. [35]
  Reza, G. M.; Dinh, C. T.; Beland, F.; Do, T. O. Nanoscale 2015, 7, 8187. doi: 10.1039/c4nr07224c doi: 10.1039/c4nr07224c
36. [36]
  Amiri, O.; Salavati, N. M.; Mir, N.; Beshkar, F.; Saadat, M.; Ansari, F. Renewable Energy 2018, 125, 590. doi: 10.1016/j.renene.2018.03.003 doi: 10.1016/j.renene.2018.03.003
37. [37]
  Qing, Q.; Hong, Y.; Zheng, J.; Gong, L.; Ying, B. RSC Adv. 2014, 4, 59114. doi: 10.1039/c4ra09355k doi: 10.1039/c4ra09355k
38. [38]
  Na, T.; Zhi, Z.; Shi, S.; Yong, D.; Zhong, W. Science 2007, 316, 732. doi: 10.1126/science.1140484 doi: 10.1126/science.1140484
39. [39]
  Hameed, A.; Ismail, I. M.; Aslam, M.; Gondal, M. A. Appl. Catal. A: Gen. 2014, 470, 327. doi: 10.1016/j.apcata.2013.10.045 doi: 10.1016/j.apcata.2013.10.045
40. [40]
  Xiao, J. D.; Han, L.; Luo, J.; Yu, S. H.; Jiang, H. L. Angew. Chem. Int. Ed. 2018, 57, 1103. doi: 10.1002/anie.201711725 doi: 10.1002/anie.201711725
41. [41]
  Wang, Y.; Suzuki, H.; Xie, J.; Tomita, O.; Martin, D. J.; Higashi, M.; Kong, D.; Abe, R.; Tang, J. Chem. Rev. 2018, 118, 5201. doi: 10.1021/acs.chemrev.7b00286 doi: 10.1021/acs.chemrev.7b00286
42. [42]
  Guo, L.; Yang, Z.; Marcus, K.; Li, Z.; Luo, B.; Zhou, L.; Wang, X.; Du, Y.; Yang, Y. J. Am. Chem. Soc. 2018, 11, 106. doi: 10.1039/c7ee02464a: doi: 10.1039/c7ee02464a:
43. [43]
  Qian, C.; Long, C.; Juan, Q.; Ying, T.; Yi, L.; Chao, X.; Jin, N.; Wen, L. Chin. Chem. Lett. 2019, 06, 1214. doi: 10.1016/j.cclet.2019.03.002 doi: 10.1016/j.cclet.2019.03.002
44. [44]
  Murcia, L. S.; Bacariza, M. C.; Villa, K.; Lopes, J. M.; Morante, J. R.; Andreu, T. ACS Catal. 2017, 7, 2878. doi: 10.1021/acscatal.6b03535 doi: 10.1021/acscatal.6b03535
45. [45]
  Villa, K.; S, M. L.; Andreu, T.; Remon, M. J. Appl. Catal. B: Environ. 2015, 163, 150. doi: 10.1016/j.apcatb.2014.07.055 doi: 10.1016/j.apcatb.2014.07.055
46. [46]
  Xu, Z. M.; Zheng, Ru.; Chen, Y.; Zhu, J.; Bian Z. F. Chin. J. Catal. 2019, 40, 631. doi: S1872-2067(19)63309-7
47. [47]
  Shi, F.; Tse, M. K.; Pohl, M. M.; Bruckner, A.; Zhang, S.; Beller, M. Angew. Chem. Int. Ed. 2007, 46, 8866. doi: 10.1002/anie.200703418 doi: 10.1002/anie.200703418
48. [48]
  Wang, T.; Yang, G.; Liu, J.; Yang, B.; Ding, S.; Yan, Z.; Xiao, T. Appl. Surf. Sci. 2014, 311, 314. doi: 10.1016/j.apsusc.2014.05.060 doi: 10.1016/j.apsusc.2014.05.060
49. [49]
  Eunsung, K.; Scott, G. H. Environ. Sci. Technol. 2009, 43, 1493. doi: 10.1021/es802360f doi: 10.1021/es802360f
50. [50]
  Qian, X.; Ren, M.; Zhu, Y.; Yue, D.; Han, Y.; Jia, J.; Zhao, Y. Environ. Sci. Technol. 2017, 51, 3993. doi: 10.1021/acs.est.6b06429 doi: 10.1021/acs.est.6b06429
51. [51]
  Hems, R. F.; Hsieh, J. S.; Slodki, M. A.; Zhou, S.; Abbatt, J. P. Environ. Sci. Technol. Lett. 2017, 4, 439. doi: 10.1021/acs.estlett.7b00381 doi: 10.1021/acs.estlett.7b00381
52. [52]
  Jian, Z.; Jie, R.; Yuning, H.; Zhen, F. B.; He, L. J. Phys. Chem. C 2007, 111, 18965. doi: 10.1021/jp0751108 doi: 10.1021/jp0751108
53. [53]
  Yue, Z.; Yang, S.; Ying, W.; Ji, B.; Mcpherson, G. L.; John, V. T. RSC Adv. 2017, 7, 39049. doi: 10.1039/c7ra06621j doi: 10.1039/c7ra06621j
54. [54]
  Isaac, B.; Maxime, S. Angew. Chem. Int. Ed. 2016, 55, 12873. doi: 10.1002/anie.201607216 doi: 10.1002/anie.201607216
55. [55]
  Spannring, P.; Yazerski, V.; Bruijnincx, P. C. A.; Weckhuysen, B. M.; Klein, R. J. M. Chem. Eur. J. 2013, 19, 15012. doi: 10.1002/chem.201301371 doi: 10.1002/chem.201301371
56. [56]
  Eric, M. F. Science 2012, 6105, 340. doi: 10.1126/science.1226840 doi: 10.1126/science.1226840
57. [57]
  Vasant, R. C.; Anil, K. K.; Tushar, V. C. Science 1997, 275, 1286. doi: 10.1126/science.275.5304.1286 doi: 10.1126/science.275.5304.1286
58. [58]
  Shimura, K.; Yoshida, H. Catal. Surv. Asia 2014, 18, 24. doi: 10.1007/s10563-014-9165-z doi: 10.1007/s10563-014-9165-z
59. [59]
  Yuliati, L.; Itoh, H.; Yoshida, H. Chem. Phy. Lett. 2008, 452, 178. doi: 10.1016/j.cplett.2007.12.051 doi: 10.1016/j.cplett.2007.12.051
60. [60]
  Yuko, K.; Yoshida, H.; Tadashi, H. Chem. Commun. 1998, 21, 2389. doi: 10.1039/A806825I doi: 10.1039/A806825I
61. [61]
  Yuliati, L.; Tsubota, M.; Satsuma, A.; Itoh, H.; Yoshida H. J. Catal. 2006, 238, 214. doi: 10.1016/j.jcat.2005.12.002 doi: 10.1016/j.jcat.2005.12.002
62. [62]
  Yoshida, H.; Matsushita, N.; Kato, Y.; Hattori, T. J. Phys. Chem. B 2003, 107, 8355. doi: 10.1021/jp034458 doi: 10.1021/jp034458
63. [63]
  Yuko, K.; Hisao, Y.; Atsushi, S.; Tadashi, H. Microporous Mesoporous Mat. 2002, 51, 223. doi: 10.1016/s1387-1811(02)00268-8 doi: 10.1016/s1387-1811(02)00268-8
64. [64]
  Li, L.; Li, G. D.; Yan, C.; Mu, X. Y.; Pan, X. L.; Zou, X. X.; Wang, K. X.; Chen, J. S. Angew. Chem. Int. Ed. 2011, 50, 8299. doi: 10.1002/anie.201102320 doi: 10.1002/anie.201102320
65. [65]
  Li, L.; Cai, Y. Y.; Li, G. D.; Mu, X. Y.; Wang, K. X.; Chen, J. S. Angew. Chem. Int. Ed. 2012, 51, 4702. doi: 10.1002/anie.201200045 doi: 10.1002/anie.201200045
66. [66]
  Wei, H.; Shou, F.; Qun, L.; Yong, H. Science 1997, 277, 1287. doi: 10.1126/science.277.5330.1287 doi: 10.1126/science.277.5330.1287
67. [67]
  Schafer, S.; Wyrzgol, S. A.; Caterino, R.; Jentys, A.; Schoell, S. J.; Haver, M.; Knop, A.; Lercher, J. A.; Sharp, I. D.; Stut, M. J. Am. Chem. Soc. 2012, 134, 12528. doi: 10.1021/ja3020132 doi: 10.1021/ja3020132
68. [68]
  Li, L.; Fan, S.; Mu, X.; Mi, Z.; Li, C. J. Am. Chem. Soc. 2014, 136, 7793. doi: 10.1021/ja5004119 doi: 10.1021/ja5004119
69. [69]
  Yu, L.; Shao, Y.; Li, D. Appl. Catal. B: Environ. 2017, 204, 216. doi: 10.1016/j.apcatb.2016.11.039 doi: 10.1016/j.apcatb.2016.11.039
70. [70]
  Chen, Y.; Zhao, H.; Liu, B.; Yang, H. Appl. Catal. B: Environ. 2015, 163, 189. doi: 10.1016/j.apcatb.2014.07.044 doi: 10.1016/j.apcatb.2014.07.044
71. [71]
  Zhang, B.; Wang, Z.; Huang, B.; Zhang, X.; Qin, X.; Li, H.; Dai, Y.; Li, Y. Chem. Mater. 2016, 28, 6613. doi: 10.1021/acs.chemmater.6b02639 doi: 10.1021/acs.chemmater.6b02639
72. [72]
  Meng, L.; Chen, Z.; Ma, Z.; He, S.; Hou, Y.; Li, H.; Yuan, R.; Huang, X.; Wang, X.; Long, J. J. Am. Chem. Soc. 2018, 11, 294. doi: 10.1039/c7ee02951a doi: 10.1039/c7ee02951a
73. [73]
  Zhou, Y.; Zhang, L.; Wang, W. Nat. Commun. 2019, 10, 506. doi: 10.1038/s41467-019-08454-0 doi: 10.1038/s41467-019-08454-0
1. [1]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-Based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-0. doi: 10.3866/PKU.WHXB202406029
2. [2]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-0. doi: 10.1016/j.actphy.2025.100067
3. [3]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
4. [4]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
5. [5]
  Jingping Li , Suding Yan , Jiaxi Wu , Qiang Cheng , Kai Wang . Improving hydrogen peroxide photosynthesis over inorganic/organic S-scheme photocatalyst with LiFePO₄. Acta Physico-Chimica Sinica, 2025, 41(9): 100104-0. doi: 10.1016/j.actphy.2025.100104
6. [6]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . Architecting Inorganic/Organic S-Scheme Heterojunction of Bi₄Ti₃O₁₂ Coupling with g-C₃N₄ for Photocatalytic H₂O₂ Production from Pure Water. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-0. doi: 10.3866/PKU.WHXB202403009
7. [7]
  Yanhui Guo , Li Wei , Zhonglin Wen , Chaorong Qi , Huanfeng Jiang . Recent Progress on Conversion of Carbon Dioxide into Carbamates. Acta Physico-Chimica Sinica, 2024, 40(4): 2307004-0. doi: 10.3866/PKU.WHXB202307004
8. [8]
  Yuanqing Wang , Yusong Pan , Hongwu Zhu , Yanlei Xiang , Rong Han , Run Huang , Chao Du , Chengling Pan . Enhanced Catalytic Activity of Bi₂WO₆ for Organic Pollutants Degradation under the Synergism between Advanced Oxidative Processes and Visible Light Irradiation. Acta Physico-Chimica Sinica, 2024, 40(4): 2304050-0. doi: 10.3866/PKU.WHXB202304050
9. [9]
  Yifan ZHAO , Qiyun MAO , Meijing GUO , Guoying ZHANG , Tongliang HU . Z-scheme bismuth-based multi-site heterojunction: Synthesis and hydrogen production from photocatalytic hydrogen production. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1318-1330. doi: 10.11862/CJIC.20250001
10. [10]
  Jiajie Cai , Chang Cheng , Bowen Liu , Jianjun Zhang , Chuanjia Jiang , Bei Cheng . CdS/DBTSO-BDTO S-scheme photocatalyst for H₂ production and its charge transfer dynamics. Acta Physico-Chimica Sinica, 2025, 41(8): 100084-0. doi: 10.1016/j.actphy.2025.100084
11. [11]
  Yadan Luo , Hao Zheng , Xin Li , Fengmin Li , Hua Tang , Xilin She . Modulating reactive oxygen species in O, S co-doped C₃N₄ to enhance photocatalytic degradation of microplastics. Acta Physico-Chimica Sinica, 2025, 41(6): 100052-0. doi: 10.1016/j.actphy.2025.100052
12. [12]
  Hui Wang , Abdelkader Labidi , Menghan Ren , Feroz Shaik , Chuanyi Wang . Recent Progress of Microstructure-Regulated g-C₃N₄ in Photocatalytic NO Conversion: The Pivotal Roles of Adsorption/Activation Sites. Acta Physico-Chimica Sinica, 2025, 41(5): 100039-0. doi: 10.1016/j.actphy.2024.100039
13. [13]
  Meihong Luo , Hongyu Wang . Teaching Reform of Benzoin Oxidation Experiment in the Context of Green Pharmaceutical Chemistry. University Chemistry, 2025, 40(5): 376-382. doi: 10.12461/PKU.DXHX202411055
14. [14]
  Fengying Zhang , Yanglin Mei , Yuman Jiang , Shenshen Zheng , Kaibo Zheng , Ying Zhou . Research progress of transient absorption spectroscopy in solar energy conversion and utilization. Acta Physico-Chimica Sinica, 2025, 41(9): 100118-0. doi: 10.1016/j.actphy.2025.100118
15. [15]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
16. [16]
  Xia ZHANG , Yushi BAI , Xi CHANG , Han ZHANG , Haoyu ZHANG , Liman PENG , Shushu HUANG . Preparation and photocatalytic degradation performance of rhodamine B of BiOCl/polyaniline. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 913-922. doi: 10.11862/CJIC.20240255
17. [17]
  Haitao Wang , Lianglang Yu , Jizhou Jiang , Arramel , Jing Zou . S-Doping of the N-Sites of g-C₃N₄ to Enhance Photocatalytic H₂ Evolution Activity. Acta Physico-Chimica Sinica, 2024, 40(5): 2305047-0. doi: 10.3866/PKU.WHXB202305047
18. [18]
  Jiajia Wang , Sibo Huang , Xijing Gao , Chaoxun Liu , Haibo Zhang . 光催化硝酸根还原产氨的综合实验设计. University Chemistry, 2025, 40(8): 241-248. doi: 10.12461/PKU.DXHX202410050
19. [19]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-0. doi: 10.3866/PKU.WHXB202312014
20. [20]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-0. doi: 10.3866/PKU.WHXB202408005

Get Citation

PDF

XML

Metrics

PDF Downloads(8)
Abstract views(830)
HTML views(119)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142