Citation: Xu Laiqiang, Li Jiayang, Liu Cheng, Zou Guoqiang, Hou Hongshuai, Ji Xiaobo. Research Progress in Inorganic Solid-State Electrolytes for Sodium-Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2020, 36(5): 190501. doi: 10.3866/PKU.WHXB201905013 shu

Research Progress in Inorganic Solid-State Electrolytes for Sodium-Ion Batteries

College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China

Corresponding author: Ji Xiaobo, xji@csu.edu.cn
Received Date: 2 May 2019
Revised Date: 3 June 2019
Accepted Date: 1 July 2019
Available Online: 4 May 2019
Fund Project: The project was supported by the National Natural Science Foundation of China (51622406)the National Natural Science Foundation of China 51622406

Sodium batteries have drawn increasing attention from multiple researchers owing to the abundant reserves and low cost of sodium resources. However, traditional sodium batteries based on organic solvent electrolyte systems have safety risks. Thus, the utilization of solid electrolyte materials instead of organic electrolytes could effectively resolve safety issues and ensure the safe performance of the battery. Solid sodium-ion battery is a promising energy storage device. The sodium ion solid-state electrolytes mainly includes Na-β-Al₂O₃, Na super ionic conductor (NASICON), sulfide, polymer, and borohydride. Inorganic solid electrolytes have the advantage of ionic conductivity compared with polymer solid electrolyte. This paper summarizes the research progress on three common inorganic sodium ion solid electrolytes: Na-β-Al₂O₃, NASICON, and sulfide. Research efforts have mainly focused on increasing ionic conductivity and interface stability. Na-β-Al₂O₃ has been successfully commercialized in high-temperature Na-S and ZEBRA batteries with molten electrodes. Pure β″-Al₂O₃ is difficult to prepare owing to its low thermodynamic stability. The synthesized β″-Al₂O₃ based on traditional solid-state reaction generally contains impurities such as β-Al₂O₃ and NaAlO₂ (around the boundaries). Further improvements are required to develop favorable methods for fabricating pure β″-Al₂O₃ with high production yield, low cost, and well-controlled microstructure. NASICON, one of the most promising ionic conductors for solid sodium-ion batteries, has attracted considerable attention for its high ionic conductivity at room temperature. The general method to enhance ionic conductivity is to increase the bottleneck size by introducing proper substituents. However, the substitution of synthetic elements could result in different optimal calcination temperatures, which would lead to a change in the density of ceramic sintering. β″-Al₂O₃ and NASICON have higher ionic conductivity at room temperature but cannot achieve good performance in the field of high power densities and long-term cycling owing to the poor interface contact with electrode materials. Because the high polarizability and large ionic radius of sulfur atoms weaken the interaction between skeleton and sodium ions, sulfide solid electrolytes often provide higher ionic conductivity at room temperature than analogous oxides. At the same time, sulfide solid electrolytes can be easily pressed into a mold at room temperature. However, sulfide electrolytes have low chemical stability in air because of hydrolysis by water molecules with the generation of H₂S gas, which should be handled in inert gas atmosphere. In conclusion, this review discusses the recent progress in different aspects of ionic conductivity and interface stability.
- Solid sodium-ion battery,
- Safety,
- Inorganic sodium ion solid electrolyte,
- Ionic conductivity,
- Interface
1. [1]
  Poizot, P.; Laruelle, S.; Grugeon, S.; Dupont, L.; Tarascon, J. Nature 2000, 407, 496. doi: 10.1038/35035045 doi: 10.1038/35035045
2. [2]
  Taberna, P. L.; Mitra, S.; Poizot, P.; Simon, P.; Tarascon, J. M. Nat. Mater. 2006, 5, 567. doi: 10.1038/nmat1672 doi: 10.1038/nmat1672
3. [3]
  Nitta, N.; Wu, F.; Lee, J. T.; Yushin, G. Mater. Today 2015, 18, 252. doi: 10.1016/j.mattod.2014.10.040 doi: 10.1016/j.mattod.2014.10.040
4. [4]
  Li, M.; Lu, J.; Chen, Z.; Amine, K. Adv. Mater. 2018, 30, 1800561. doi: 10.1002/adma.201800561 doi: 10.1002/adma.201800561
5. [5]
  Schmuch, R.; Wagner, R.; Hörpel, G.; Placke, T.; Winter, M. Nat. Energy 2018, 3, 267. doi: 10.1038/s41560-018-0107-2 doi: 10.1038/s41560-018-0107-2
6. [6]
  Zubi, G.; Dufo-López, R.; Carvalho, M.; Pasaoglu, G. Renewable Sustainable Energy Rev. 2018, 89, 292. doi: 10.1016/j.rser.2018.03.002 doi: 10.1016/j.rser.2018.03.002
7. [7]
  Nayak, P. K.; Yang, L.; Brehm, W.; Adelhelm, P. Angew. Chem. Int. Ed. 2018, 57, 102. doi: 10.1002/anie.201703772 doi: 10.1002/anie.201703772
8. [8]
  Wood Ⅲ, D. L.; Li, J.; Daniel, C. J. Power Sources 2015, 275, 234. doi: 10.1016/j.jpowsour.2014.11.019 doi: 10.1016/j.jpowsour.2014.11.019
9. [9]
  Meister, P.; Jia, H.; Li, J.; Kloepsch, R.; Winter, M.; Placke, T. Chem. Mater. 2016, 28, 7203. doi: 10.1021/acs.chemmater.6b02895 doi: 10.1021/acs.chemmater.6b02895
10. [10]
  Song, W. X.; Hou, H. S.; Ji, X. B. Acta Phys. -Chim. Sin. 2017, 33, 103. doi: 10.3866/PKU.WHXB201608303
11. [11]
  Yabuuchi, N.; Kubota, K.; Dahbi, M.; Komaba, S. Chem. Rev. 2014, 114, 11636. doi: 10.1021/cr500192f doi: 10.1021/cr500192f
12. [12]
  Kundu, D.; Talaie, E.; Duffort, V.; Nazar, L. F. Angew. Chem. Int. Ed. 2015, 54, 3431. doi: 10.1002/chin.201521309 doi: 10.1002/chin.201521309
13. [13]
  Yang, Y. Q.; Chang, Z.; Li, M. X.; Wang, X. W.; Wu, Y. P. Solid State Ionics 2015, 269, 1. doi: 10.1016/j.ssi.2014.11.015 doi: 10.1016/j.ssi.2014.11.015
14. [14]
  Hu, Z.; Liu, Q.; Chou, S. L.; Dou, S. X. Adv. Mater. 2017, 29, 1700606. doi: 10.1002/adma.201700606 doi: 10.1002/adma.201700606
15. [15]
  Hou, H.; Banks, C. E.; Jing, M.; Zhang, Y.; Ji, X. B. Adv. Mater. 2015, 27, 7861. doi: 10.1002/adma.201503816 doi: 10.1002/adma.201503816
16. [16]
  David, L.; Bhandavat, R.; Singh, G. ACS Nano 2014, 8, 1759. doi: 10.1021/nn406156b doi: 10.1021/nn406156b
17. [17]
  Jin, Y.; Sun, X.; Yu, Y.; Ding, C.; Chen, C.; Guan, Y. Prog. Chem. 2014, 26, 582. doi: 10.7536/PC130914
18. [18]
  http://newsxmwb.xinmin.cn/kechuang/2019/03/25/31506485.html (accessed June 29, 2019)
19. [19]
  Huang, Y.; Zhao, L.; Li, L.; Xie, M.; Wu, F.; Chen, R. Adv. Mater. 2019, 31, 1808393. doi: 10.1002/adma.201808393 doi: 10.1002/adma.201808393
20. [20]
  Ponrouch, A.; Dedryvère, R.; Monti, D.; Demet, A. E.; Mba, J. M. A.; Croguennec, L.; Masquelier, C.; Johansson, P.; Palacín, M. R. Energy Environ. Sci. 2013, 6, 2361. doi: 10.1039/c3ee41379a doi: 10.1039/c3ee41379a
21. [21]
  Monti, D.; Jónsson, E.; Palacín, M. R.; Johansson, P. J. Power Sources 2014, 245, 630. doi: 10.1016/j.jpowsour.2013.06.153 doi: 10.1016/j.jpowsour.2013.06.153
22. [22]
  Ponrouch, A.; Marchante, E.; Courty, M.; Tarascon, J. M.; Palacin, M. R. Energy Environ. Sci. 2012, 5, 8572. doi: 10.1039/c2ee22258b doi: 10.1039/c2ee22258b
23. [23]
  Kim, J. K.; Lim, Y. J.; Kim, H.; Cho, G. B.; Kim, Y. Energy Environ. Sci. 2015, 8, 3589. doi: 10.1039/C5EE01941A doi: 10.1039/C5EE01941A
24. [24]
  Zhang, Z.; Zhang, Q.; Shi, J.; Chu, Y. S.; Yu, X.; Xu, K.; Ge, M.; Yan, H.; Li, W.; Gu, L. Adv. Energy Mater. 2017, 7, 1601196. doi: 10.1002/aenm.201601196 doi: 10.1002/aenm.201601196
25. [25]
  Ma, Q.; Hu, Y.; Li, H.; Chen, L.; Huang, X.; Zhou, Z. Acta Phys. -Chim. Sin. 2018, 34, 213. doi: 10.3866/PKU.WHXB201707172
26. [26]
  Zhang, Q.; Liang, F.; Yao, Y.; Ma, W.; Yang, B.; Dai, Y. Prog. Chem. 2019, 31, 210. doi: 10.7536/PC180434
27. [27]
  Hou, W.; Guo, X.; Shen, X.; Amine, K.; Yu, H.; Lu, J. Nano Energy 2018, 52, 279. doi: 10.1016/j.nanoen.2018.07.036 doi: 10.1016/j.nanoen.2018.07.036
28. [28]
  Gao, H.; Xin, S.; Xue, L.; Goodenough, J. B. Chemistry 2018, 4, 833. doi: 10.1016/j.chempr.2018.01.007 doi: 10.1016/j.chempr.2018.01.007
29. [29]
  Zhou, W.; Li, Y.; Xin, S.; Goodenough, J. B. ACS Cent. Sci. 2017, 3, 52. doi: 10.1021/acscentsci.6b00321 doi: 10.1021/acscentsci.6b00321
30. [30]
  Richards, W. D.; Miara, L. J.; Wang, Y.; Kim, J. C.; Ceder, G. Chem. Mater. 2015, 28, 266. doi: 10.1021/acs.chemmater.5b04082 doi: 10.1021/acs.chemmater.5b04082
31. [31]
  Wenzel, S.; Leichtweiss, T.; Weber, D. A.; Sann, J.; Zeier, W. G.; Janek, J. ACS Appl. Mater. Interfaces 2016, 8, 28216. doi: 10.1021/acsami.6b10119 doi: 10.1021/acsami.6b10119
32. [32]
  Hueso, K. B.; Armand, M.; Rojo, T. Energy Environ. Sci. 2013, 6, 734. doi: 10.1039/C3EE24086J doi: 10.1039/C3EE24086J
33. [33]
  Lu, X.; Xia, G.; Lemmon, J. P.; Yang, Z. J. Power Sources 2010, 195, 2431. doi: 10.1016/j.jpowsour.2009.11.120 doi: 10.1016/j.jpowsour.2009.11.120
34. [34]
  Chen, G.; Lu, J.; Li, L.; Chen, L.; Jiang, X. J. Alloys Compd. 2016, 673, 295. doi: 10.1016/j.jallcom.2016.03.009 doi: 10.1016/j.jallcom.2016.03.009
35. [35]
  Xu, D.; Jiang, H.; Li, Y.; Li, L.; Li, M.; Hai, O. Eur. Phys. J. Appl. Phys. 2016, 74, 10901. doi: 10901.10.1051/epjap/2016150466 doi: 10.1051/epjap/2016150466
36. [36]
  Park, J. H.; Kim, K. H.; Lim, S. K. J. Mater. Sci. 1998, 33, 5671. doi: 10.1023/A:100448880 doi: 10.1023/A:100448880
37. [37]
  Lu, X. C.; Li, G. S.; Kim, J. Y.; Meinhardt, K. D.; Sprenkle, V. L. J. Power Sources 2015, 295, 167. doi: 10.1016/j.jpowsour.2015.06.147 doi: 10.1016/j.jpowsour.2015.06.147
38. [38]
  Chen, G. Y.; Lu, J. C.; Zhou, X. H.; Chen, L. X.; Jiang, X. B. Ceram. Int. 2016, 42, 18055. doi: 10.1016/j.ceramint.2016.07.115 doi: 10.1016/j.ceramint.2016.07.115
39. [39]
  Zhu, C. F.; Hong, Y. F.; Huang, P. J. Alloys Compd. 2016, 688, 746. doi: 10.1016/j.jallcom.2016.07.264 doi: 10.1016/j.jallcom.2016.07.264
40. [40]
  Xu, D.; Jiang, H. Y.; Li, M.; Hai, O.; Zhang, Y. Ceram. Int. 2015, 41, 5355. doi: 10.1016/j.ceramint.2014.12.094 doi: 10.1016/j.ceramint.2014.12.094
41. [41]
  Wang, M. C.; Hon, M. H.; Yen, F. S. J. Cryst. Growth 1987, 84, 638. doi: 10.1016/0022-0248(87)90055-8 doi: 10.1016/0022-0248(87)90055-8
42. [42]
  Lange, F. F.; Miller, K. T. J. Am. Ceram. Soc. 1987, 12, 896. doi: 10.1111/j.1151-2916.1987.tb04913.x doi: 10.1111/j.1151-2916.1987.tb04913.x
43. [43]
  Wei, X.; Cao, Y.; Lu, L.; Yang, H.; Shen, X. J. Alloys Compd. 2011, 509, 6222. doi: 10.1016/j.jallcom.2011.03.0 doi: 10.1016/j.jallcom.2011.03.0
44. [44]
  Takahashi, T.; Kuwabara, K. J. Appl. Electrochem. 1980, 10, 291. doi:10.1007/BF00617203 doi: 10.1007/BF00617203
45. [45]
  Chi, C.; Katsui, H.; Goto, T. Ceram. Int. 2017, 43, 1278. doi: 10.1016/j.ceramint.2016.10.077 doi: 10.1016/j.ceramint.2016.10.077
46. [46]
  Yamaguchi, S.; Terabe, K.; Iguchi, Y.; Imai, A. Solid State Ionics 1987, 25, 171. doi: 10.1016/0167-2738(87)90117-2 doi: 10.1016/0167-2738(87)90117-2
47. [47]
  Pekarsky, A.; Nicholson, P. S. Mater. Res. Bull. 1980, 15, 1517. doi: 10.1016/0025-5408(80)90111-7 doi: 10.1016/0025-5408(80)90111-7
48. [48]
  Park, H. C.; Lee, Y. B.; Lee, S. G.; Lee, C. H.; Kim, J. K.; Hong, S. S.; Park, S. S. Ceram. Int. 2005, 31, 293. doi: 10.1016/j.ceramint.2004.05.019 doi: 10.1016/j.ceramint.2004.05.019
49. [49]
  Yi, E.; Temeche, E.; Laine, R. M. J. Mater. Chem. A 2018, 6, 12411. doi: 10.1039/C8TA02907E doi: 10.1039/C8TA02907E
50. [50]
  Goodenough, J.; Hong, H. P.; Kafalas, J. Mater. Res. Bull. 1976, 11, 203. doi: 10.1016/0025-5408(76)90077-5 doi: 10.1016/0025-5408(76)90077-5
51. [51]
  Chen, M.; Hua, W.; Xiao, J.; Cortie, D.; Chen, W.; Wang, E.; Hu, Z.; Gu, Q.; Wang, X.; Indris, S. Nat. Commun. 2019, 10, 1480. doi: 10.1038/s41467-019-09170-5 doi: 10.1038/s41467-019-09170-5
52. [52]
  Zhao, C.; Liu, L.; Qi, X.; Lu, Y.; Wu, F.; Zhao, J.; Yu, Y.; Hu, Y. S.; Chen, L. Adv. Energy Mater. 2018, 8, 1704012. doi: 1703012.10.1002/aenm.201703012
53. [53]
  Boilot, J.; Collin, G.; Colomban, P. Mater. Res. Bull. 1987, 22, 669. doi: 10.1016/0025-5408(87)90116-4 doi: 10.1016/0025-5408(87)90116-4
54. [54]
  Zhu, Y. S.; Li, L. L.; Li, C. Y.; Zhou, L.; Wu, Y. P. Solid State Ionics 2016, 289, 113. doi: 10.1016/j.ssi.2016.02.021 doi: 10.1016/j.ssi.2016.02.021
55. [55]
  Shao, Y.; Zhong, G.; Lu, Y.; Liu, L.; Zhao, C.; Zhang, Q.; Hu, Y. S.; Yang, Y.; Chen, L. Energy Storage Mater. 2019. doi: 10.1016/j.ensm.2019.04.009 doi: 10.1016/j.ensm.2019.04.009
56. [56]
  Imanaka, N.; Kuwabara, S.; Adachi, G. Y.; Shiokawa, J. Solid State Ionics 1987, 23, 15. doi: 10.1016/0167-2738(87)90076-2 doi: 10.1016/0167-2738(87)90076-2
57. [57]
  Agrawal, D. K. Trans. Indian Ceram. Soc. 1996, 55, 1. doi: 10.1080/0371750X.1996.10804741 doi: 10.1080/0371750X.1996.10804741
58. [58]
  Aono, H.; Sugimoto, E.; Sadaoka, Y.; Imanaka, N.; Adachi, G. Y. Solid State Ionics 1991, 47, 257. doi: 10.1016/0167-2738(91)90247-9 doi: 10.1016/0167-2738(91)90247-9
59. [59]
  Zhang, Z. Z.; Zhang, Q. H.; Shi, J. A.; Chu, Y. S.; Yu, X. Q.; Xu, K. Q.; Ge, M. Y.; Yan, H. F.; Li, W. J.; Gu, L.; et al. Adv. Energy Mater. 2016, 7, 1601196. doi: 10.1002/aenm.201601196 doi: 10.1002/aenm.201601196
60. [60]
  Deng, Y.; Eames, C.; Nguyen, L. H.; Pecher, O.; Griffith, K. J.; Courty, M.; Fleutot, B.; Chotard, J. N.; Grey, C. P.; Islam, M. S. Chem. Mater. 2018, 30, 2618. doi: 10.1021/acs.chemmater.7b05237 doi: 10.1021/acs.chemmater.7b05237
61. [61]
  Samiee, M.; Radhakrishnan, B.; Rice, Z.; Deng, Z.; Meng, Y. S.; Ong, S. P.; Luo, J. J. Power Sources 2017, 347, 229. doi: 10.1016/j.jpowsour.2017.02.04 doi: 10.1016/j.jpowsour.2017.02.04
62. [62]
  Tatsumisago, M.; Hayashi, A. Int. J. Appl. Glass Sci. 2014, 5, 226. doi: 10.1111/ijag.12084 doi: 10.1111/ijag.12084
63. [63]
  Hayashi, A.; Noi, K.; Sakuda, A.; Tatsumisago, M. Nat. Commun. 2012, 3, 856. doi: 10.1038/ncomms1843 doi: 10.1038/ncomms1843
64. [64]
  Hu, P.; Zhang, Y.; Chi, X.; Kumar Rao, K.; Hao, F.; Dong, H.; Guo, F.; Ren, Y.; Grabow, L. C.; Yao, Y. ACS Appl. Mater. Interfaces 2019, 11, 9672. doi: 10.1021/acsami.8b19984 doi: 10.1021/acsami.8b19984
65. [65]
  Yue, J.; Zhu, X.; Han, F.; Fan, X.; Wang, L.; Yang, J.; Wang, C. ACS Appl. Mater. Interfaces 2018, 10, 39645. doi: 10.1021/acsami.8b12610 doi: 10.1021/acsami.8b12610
66. [66]
  Takeuchi, S.; Suzuki, K.; Hirayama, M.; Kanno, R. J. Solid State Chem. 2018, 265, 353. doi: 10.1016/j.jssc.2018.06.023 doi: 10.1016/j.jssc.2018.06.023
67. [67]
  Dive, A.; Benmore, C.; Wilding, M.; Martin, S. W.; Beckman, S.; Banerjee, S. J. Phys. Chem. B 2018, 122, 7597. doi: 10.1021/acs.jpcb.8b04353 doi: 10.1021/acs.jpcb.8b04353
68. [68]
  Wu, E. A.; Kompella, C. S.; Zhu, Z.; Lee, J. Z.; Lee, S. C.; Chu, I. H.; Nguyen, H.; Ong, S. P.; Banerjee, A.; Meng, Y. S. ACS Appl. Mater. Interfaces 2018, 10, 10076. doi: 10.1021/acsami.7b19037 doi: 10.1021/acsami.7b19037
69. [69]
  Wan, H.; Mwizerwa, J. P.; Qi, X.; Liu, X.; Xu, X.; Li, H.; Hu, Y. S.; Yao, X. ACS Nano 2018, 12, 2809. doi: 10.1021/acsnano.8b00073 doi: 10.1021/acsnano.8b00073
70. [70]
  Chi, X.; Liang, Y.; Hao, F.; Zhang, Y.; Whiteley, J.; Dong, H.; Hu, P.; Lee, S.; Yao, Y. Angew. Chem. Int. Ed. 2018, 57, 2630. doi: 10.1002/anie.201712895 doi: 10.1002/anie.201712895
71. [71]
  Shang, S. L.; Wang, Y.; Anderson, T. J.; Liu, Z. K. Phys. Rev. Mater. 2019, 3, 015401. doi: 10.1103/PhysRevMaterials.3.015401 doi: 10.1103/PhysRevMaterials.3.015401
72. [72]
  Moon, C. K.; Lee, H. J.; Park, K. H.; Kwak, H.; Heo, J. W.; Choi, K.; Yang, H.; Kim, M. S.; Hong, S. T.; Lee, J. H. ACS Energy Lett. 2018, 3, 2504. doi: 10.1021/acsenergylett.8b01479 doi: 10.1021/acsenergylett.8b01479
73. [73]
  Huang, H.; Wu, H. H.; Wang, X.; Huang, B.; Zhang, T. Y. Phys. Chem. Chem. Phys. 2018, 20, 20525. doi: 10.1039/C8CP02383B doi: 10.1039/C8CP02383B
74. [74]
  Uematsu, M.; Yubuchi, S.; Noi, K.; Sakuda, A.; Hayashi, A.; Tatsumisago, M. Solid State Ionics 2018, 320, 33. doi: 10.1016/j.ssi.2017.12.021 doi: 10.1016/j.ssi.2017.12.021
75. [75]
  Noi, K.; Nagata, Y.; Hakari, T.; Suzuki, K.; Yubuchi, S.; Ito, Y.; Sakuda, A.; Hayashi, A.; Tatsumisago, M. ACS Appl. Mater. Interfaces 2018, 10, 19605. doi: 10.1021/acsami.8b02427 doi: 10.1021/acsami.8b02427
76. [76]
  Tang, H.; Deng, Z.; Lin, Z.; Wang, Z.; Chu, I. H.; Chen, C.; Zhu, Z.; Zheng, C.; Ong, S. P. Chem. Mater. 2017, 30, 163. doi: 10.1021/acs.chemmater.7b04096 doi: 10.1021/acs.chemmater.7b04096
77. [77]
  Zhang, D.; Cao, X.; Xu, D.; Wang, N.; Yu, C.; Hu, W.; Yan, X.; Mi, J.; Wen, B.; Wang, L. Electrochim. Acta 2018, 259, 100. doi: 10.1016/j.electacta.2017.10.173 doi: 10.1016/j.electacta.2017.10.173
78. [78]
  Tanibata, N.; Noi, K.; Hayashi, A.; Tatsumisago, M. Solid State Ionics 2018, 320, 193. doi: 10.1016/j.ssi.2018.02.042 doi: 10.1016/j.ssi.2018.02.042
79. [79]
  Jansen, M.; Henseler, U. J. Solid State Chem. 1992, 99, 110. doi: 10.1016/0022-4596(92)90295-7 doi: 10.1016/0022-4596(92)90295-7
80. [80]
  Berbano, S. S.; Seo, I.; Bischoff, C. M.; Schuller, K. E.; Martin, S. W. J. Non-Cryst. Solids 2012, 358, 93. doi: 10.1016/j.jnoncrysol.2011.08.030 doi: 10.1016/j.jnoncrysol.2011.08.030
81. [81]
  Krauskopf, T.; Culver, S. P.; Zeier, W. G. Inorg. Chem. 2018, 57, 4739. doi: 10.1021/acs.inorgchem.8b00458 doi: 10.1021/acs.inorgchem.8b00458
82. [82]
  Yu, Z.; Shang, S. L.; Seo, J. H.; Wang, D.; Luo, X.; Huang, Q.; Chen, S.; Lu, J.; Li, X.; Liu, Z. K. Adv. Mater. 2017, 29, 1605561. doi: 10.1002/adma.201605561 doi: 10.1002/adma.201605561
83. [83]
  Yu, Z.; Shang, S. L.; Wang, D.; Li, Y. C.; Yennawar, H. P.; Li, G.; Huang, H. T.; Gao, Y.; Mallouk, T. E.; Liu, Z. K. Energy Storage Mater. 2019, 17, 70. doi: 10.1016/j.ensm.2018.11.027 doi: 10.1016/j.ensm.2018.11.027
84. [84]
  Kim, S. K.; Mao, A.; Sen, S.; Kim, S. Chem. Mater. 2014, 26, 5695. doi: 10.1021/cm502542p doi: 10.1021/cm502542p
85. [85]
  Wang, H.; Chen, Y.; Hood, Z. D.; Sahu, G.; Pandian, A. S.; Keum, J. K.; An, K.; Liang, C. Angew. Chem. Int. Ed. 2016, 55, 8551. doi: 10.1002/anie.201601546 doi: 10.1002/anie.201601546
86. [86]
  Shang, S. L.; Yu, Z.; Wang, Y.; Wang, D.; Liu, Z. K. ACS Appl. Mater. Interfaces 2017, 9, 16261. doi: 10.1021/acsami.7b03606 doi: 10.1021/acsami.7b03606
87. [87]
  Kim, T. W.; Park, K. H.; Choi, Y. E.; Lee, J. Y.; Jung, Y. S. J. Mater. Chem. A 2018, 6, 840. doi: 10.1039/C7TA09242C doi: 10.1039/C7TA09242C
88. [88]
  Zhang, L.; Yang, K.; Mi, J.; Lu, L.; Zhao, L.; Wang, L.; Li, Y.; Zeng, H. Adv. Energy Mater. 2015, 5, 1501294. doi: 10.1002/aenm.201501294 doi: 10.1002/aenm.201501294
89. [89]
  Kim, J. J.; Yoon, K.; Park, I.; Kang, K. Small Methods 2017, 1, 1700219. doi: 10.1002/smtd.201700219 doi: 10.1002/smtd.201700219
90. [90]
  Tian, Y.; Sun, Y.; Hannah, D. C.; Xiao, Y.; Liu, H.; Chapman, K. W.; Bo, S. H.; Ceder, G. Joule 2019, 3, 17. doi: 10.1016/j.joule.2018.12.019 doi: 10.1016/j.joule.2018.12.019
1. [1]
  Xuechen Hu , Qiuying Xia , Fan Yue , Xinyi He , Zhenghao Mei , Jinshi Wang , Hui Xia , Xiaodong Huang . Electrochemical Characteristics of LiNbO₃ Anode Film and Its Applications in All-Solid-State Thin-Film Lithium-Ion Battery. Acta Physico-Chimica Sinica, 2024, 40(2): 2309046-0. doi: 10.3866/PKU.WHXB202309046
2. [2]
  Weiguang Zhao . 化学实验室常见安全事故应急处置的思考与建议. University Chemistry, 2025, 40(8): 291-297. doi: 10.12461/PKU.DXHX202410053
3. [3]
  Tao Xu , Wei Sun , Tianci Kong , Jie Zhou , Yitai Qian . Stable Graphite Interface for Potassium Ion Battery Achieving Ultralong Cycling Performance. Acta Physico-Chimica Sinica, 2024, 40(2): 2303021-0. doi: 10.3866/PKU.WHXB202303021
4. [4]
  Zhi Dou , Huiyu Duan , Yixi Lin , Yinghui Xia , Mingbo Zheng , Zhenming Xu . High-Throughput Screening Lithium Alloy Phases and Investigation of Ion Transport for Solid Electrolyte Interphase Layer. Acta Physico-Chimica Sinica, 2024, 40(3): 2305039-0. doi: 10.3866/PKU.WHXB202305039
5. [5]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
6. [6]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
7. [7]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 2406014-0. doi: 10.3866/PKU.WHXB202406014
8. [8]
  Zhaoxuan ZHU , Lixin WANG , Xiaoning TANG , Long LI , Yan SHI , Jiaojing SHAO . Application of poly(vinyl alcohol) conductive hydrogel electrolytes in zinc ion batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 893-902. doi: 10.11862/CJIC.20240368
9. [9]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
10. [10]
  Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . Recent Advances in Iron-based Heterostructure Anode Materials for Sodium Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(3): 2311015-0. doi: 10.3866/PKU.WHXB202311015
11. [11]
  Zilin Hu , Yaoshen Niu , Xiaohui Rong , Yongsheng Hu . Suppression of Voltage Decay through Ni³⁺ Barrier in Anionic-Redox Active Cathode for Na-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(6): 2306005-0. doi: 10.3866/PKU.WHXB202306005
12. [12]
  Da Wang , Xiaobin Yin , Jianfang Wu , Yaqiao Luo , Siqi Shi . All-Solid-State Lithium Cathode/Electrolyte Interfacial Resistance: From Space-Charge Layer Model to Characterization and Simulation. Acta Physico-Chimica Sinica, 2024, 40(7): 2307029-0. doi: 10.3866/PKU.WHXB202307029
13. [13]
  Jiandong Liu , Zhijia Zhang , Kamenskii Mikhail , Volkov Filipp , Eliseeva Svetlana , Jianmin Ma . Research Progress on Cathode Electrolyte Interphase in High-Voltage Lithium Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 2308048-0. doi: 10.3866/PKU.WHXB202308048
14. [14]
  Jiandong Liu , Xin Li , Daxiong Wu , Huaping Wang , Junda Huang , Jianmin Ma . Anion-Acceptor Electrolyte Additive Strategy for Optimizing Electrolyte Solvation Characteristics and Electrode Electrolyte Interphases for Li||NCM811 Battery. Acta Physico-Chimica Sinica, 2024, 40(6): 2306039-0. doi: 10.3866/PKU.WHXB202306039
15. [15]
  Changsheng An , Tao Liu . Decoding SEI chemistry at the lithium-metal potential. Acta Physico-Chimica Sinica, 2025, 41(9): 100101-0. doi: 10.1016/j.actphy.2025.100101
16. [16]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 2408007-0. doi: 10.3866/PKU.WHXB202408007
17. [17]
  Yameen Ahmed , Xiangxiang Feng , Yuanji Gao , Yang Ding , Caoyu Long , Mustafa Haider , Hengyue Li , Zhuan Li , Shicheng Huang , Makhsud I. Saidaminov , Junliang Yang . Interface Modification by Ionic Liquid for Efficient and Stable FAPbI₃ Perovskite Solar Cells. Acta Physico-Chimica Sinica, 2024, 40(6): 2303057-0. doi: 10.3866/PKU.WHXB202303057
18. [18]
  Qing Xue , Shengyi Li , Yanan Zhao , Peng Sheng , Li Xu , Zhengxi Li , Bo Zhang , Hui Li , Bo Wang , Libin Yang , Yuliang Cao , Zhongxue Chen . Novel Alkaline Sodium-Ion Battery Capacitor Based on Active Carbon||Na_0.44MnO₂ towards Low Cost, High-Rate Capability and Long-Term Lifespan. Acta Physico-Chimica Sinica, 2024, 40(2): 2303041-0. doi: 10.3866/PKU.WHXB202303041
19. [19]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5−xMn_0.5V_1.5−xZr_x (PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-0. doi: 10.3866/PKU.WHXB202407023
20. [20]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . Sulfide Solid Electrolyte Synthesized by Liquid Phase Approach and Application in All-Solid-State Lithium Batteries. Acta Physico-Chimica Sinica, 2025, 41(1): 100004-0. doi: 10.3866/PKU.WHXB202309019

Get Citation

PDF

XML

Metrics

PDF Downloads(54)
Abstract views(1457)
HTML views(294)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142