Citation: YU Kang, TIAN Cuicui, LI Xia, LIAO Xuepin, SHI Bi. Synthesis, Characterization, and Antibacterial Activity of Rare Earth-Catechin Complexes[J]. Acta Physico-Chimica Sinica, ;2018, 34(5): 543-550. doi: 10.3866/PKU.WHXB201709291 shu

Synthesis, Characterization, and Antibacterial Activity of Rare Earth-Catechin Complexes

YU Kang ¹ ,
TIAN Cuicui ¹ ,
LI Xia ¹ ,
LIAO Xuepin ^1,2,3,, ,
SHI Bi ^1,2,3

1.
Department of Biomass and Leather Engineering, Sichuan University, Chengdu 610065, P. R. China
2.
Key Laboratory of Leather Chemistry and Engineering of Ministry of Education, Sichuan University, Chengdu 610065, P. R. China
3.
National Engineering Laboratory for Clean Technology of Leather Manufacture, Sichuan University, Chengdu 610065, P. R. China

Corresponding author: LIAO Xuepin, xpliao@scu.edu.cn
Received Date: 31 July 2017
Revised Date: 26 September 2017
Accepted Date: 27 September 2017
Available Online: 29 May 2017
Fund Project: the National Technology Improvement and Industrialization Project of Fundamental Materials, China 2017YFB0308500The project was supported by the National Technology Improvement and Industrialization Project of Fundamental Materials, China (2017YFB0308500)

Three kinds of novel coordination compounds [Re³⁺-C] (Re = La, Gd, Er; C = Catechin) were synthesized by the liquid-phase method, and characterized by Fourier transform infrared (FT-IR) spectroscopy, ultraviolet-visible (UV) spectrophotometry, X-ray photoelectron spectroscopy (XPS), and coordination number determination. The results indicated that the coordination number of the complexes is 8. Moreover, the antibacterial activities of Re³⁺-C against Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, and Salmonella were evaluated by the Oxford cup, minimum inhibition concentration (MIC), and minimum bactericidal concentration (MBC) approaches. Compared with Re³⁺ and C, the as-prepared complexes exhibited excellent antimicrobial activity toward the four strains. The MIC of Gd³⁺-C to these food-borne bacteria was 1.550, 0.0968, 0.775, and 1.550 μmol·mL⁻¹, respectively, while the corresponding MBC values were 3.100, 0.194, 1.550, and 1.550 μmol·mL⁻¹. It is clear that the Gd³⁺-C complex showed the best antibacterial and germicidal activity against S. aureus.
- Catechin,
- Rare earth,
- Complex,
- Food-borne bacteria,
- Antibacterial activity
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