Citation: NIU Xiao-Ye, DU Xiao-Qin, WANG Qin-Chao, WU Xiao-Jing, ZHANG Xin, ZHOU Yong-Ning. AlN-Fe Nanocomposite Thin Film:A New Anode Material for Lithium-Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2017, 33(12): 2517-2522. doi: 10.3866/PKU.WHXB201706162 shu

AlN-Fe Nanocomposite Thin Film:A New Anode Material for Lithium-Ion Batteries

Department of Materials Science, Fudan University, Shanghai 200433, P. R. China

Received Date: 15 May 2017
Revised Date: 12 June 2017

Fund Project: The project was supported by the National Natural Science Foundation of China (51502039).

AlN-Fe nanocomposite thin films with different AlN-Fe ratio were prepared by pulsed laser deposition (PLD).They were investigated as new anode materials for lithium ion batteries for the first time.The AlN-Fe nanocomposite films with an AlN/Fe ratio of 2:1 show the best electrochemical performance.They exhibit a specific capacity of 510 mA·g^-1 after 100 cycles at a rate of 500 mA·g^-1.Further,the study of the electrochemical reaction mechanism of the AlN-Fe nanocomposite thin films with lithium reveals that AlN decomposes during the discharge process to form the LiAl alloy and Li₃N.During recharge,a part of Li₃N reacts with Fe to form Fe₃N,and the rest reacts with Al to form AlN.In subsequent cycles,all of Fe₃N,AlN,and Al react with Li reversibly,contributing to the reversible charge-discharge processes and to the superior electrochemical performance of AlN-Fe nanocomposite thin films.Thus,this study provides a new perspective to design advanced electrode materials for lithium-ion batteries.
- Lithium-ion battery,
- Anode material,
- Aluminium nitride,
- Thin film,
- Pulsed laser Deposition
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