Citation: PENG Bo, XU Yao-Lin, MULDER Fokko M.. Improving the Performance of Si-Based Li-Ion Battery Anodes by Utilizing Phosphorene Encapsulation[J]. Acta Physico-Chimica Sinica, ;2017, 33(11): 2127-2132. doi: 10.3866/PKU.WHXB201705244 shu

Improving the Performance of Si-Based Li-Ion Battery Anodes by Utilizing Phosphorene Encapsulation

1.
Department of Physics, Renmin University of China, Beijing 100872, China;
2.
Materials for Energy Conversion and Storage(MECS), Department of Chemical Engineering, Faculty of Applied Science, Delft University of Technology, Delft 2629 HZ, The Netherlands

Received Date: 14 April 2017
Revised Date: 17 May 2017

Fund Project: This project was supported by Chinese Scholarship Council (CSC) and the "A green Deal in Energy Materials" (ADEM) program.

Si-based anode materials in Li-ion batteries (LIBs) suffer from severe volume expansion/contraction during repetitive discharge/charge, which results in the pulverization of active materials, continuous growth of solid electrolyte interface (SEI) layers, loss of electrical conduction, and, eventually, battery failure. Herein, we present unprecedented low-content phosphorene (single-layer black phosphorus) encapsulation of silicon particles as an effective method for improving the electrochemical performance of Si-based LIB anodes. The incorporation of low phosphorene amounts (1%, mass fraction) into Si anodes effectively suppresses the detrimental effects of volume expansion and SEI growth, preserving the structural integrity of the electrode during cycling and achieving enhanced Coulombic efficiency, capacity retention, and cycling stability for Li-ion storage. Thus, the developed method can also be applied to other battery materials with high energy density exhibiting substantial volume changes.
- Phosphorene,
- Li ion battery,
- Anode materials,
- Silicon
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
1. [1]
  Jingshuo Zhang , Yue Zhai , Ziyun Zhao , Jiaxing He , Wei Wei , Jing Xiao , Shichao Wu , Quan-Hong Yang . Research Progress of Functional Binders in Silicon-Based Anodes for Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(6): 2306006-0. doi: 10.3866/PKU.WHXB202306006
2. [2]
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3. [3]
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4. [4]
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5. [5]
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7. [7]
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11. [11]
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14. [14]
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16. [16]
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沈阳化工大学材料科学与工程学院沈阳 110142