Citation: ZHANG Xiao-Ru, XU Yue-Feng, SHEN Shou-Yu, CHEN Yuan, HUANG Ling, LI Jun-Tao, SUN Shi-Gang. Reduced Graphene Oxide-LaFeO₃ Composite Nanomaterials as Bifunctional Catalyst for Rechargeable Lithium-Oxygen Batteries[J]. Acta Physico-Chimica Sinica, ;2017, 33(11): 2237-2244. doi: 10.3866/PKU.WHXB201705231 shu

Reduced Graphene Oxide-LaFeO₃ Composite Nanomaterials as Bifunctional Catalyst for Rechargeable Lithium-Oxygen Batteries

1.
State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China;
2.
College of Energy, Xiamen University, Xiamen 361005, Fujian Province, P. R. China

Received Date: 17 February 2017
Revised Date: 15 May 2017

Fund Project: The project was supported by the National Natural Science Foundation of China (21621091) and the National Key Research and Development Program of China (2016YFB0100202).

Development of electrocatalysts is one of the challenges in the development of the lithium-oxygen battery, especially the synthesis of catalysts with special pore structures and excellent bifunctional catalytic performance for both the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER). In this article, a reduced graphene oxide-LaFeO₃ (RGO-LaFeO₃) nanocomposite electrocatalyst was synthesized by combining sol-gel and hydrothermal methods and using graphene oxide, lanthanum nitrate, ferric nitrate, and citric acid as raw materials. The prepared samples were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, Raman spectroscopy, and scanning electron microscopy. The results confirmed that the RGO-LaFeO₃ was composed of pure phase LaFeO₃ with a perovskite structure and RGO and that the LaFeO₃ nanoparticles were loaded uniformly on the RGO layer surface. In comparison with a LaFeO₃ nanoparticle (NP-LaFeO₃) catalyst, RGO-LaFeO₃ exhibited superior activity for both the ORR and the OER when it served as the cathode of a lithium-oxygen battery. The higher catalytic activity of the RGO-LaFeO₃ is attributed to the synergistic effect of the special three-dimensional electronic conductive structure of RGO and the intrinsic catalytic property of LaFeO₃. It was shown that the lithium-oxygen battery with the RGO-LaFeO₃ cathode can be cycled stably up to 36 reversible cycles under conditions of a limit discharge depth of 1000 mAh·g^-1 and a 100 mA·g^-1 current density for charge-discharge. The study illustrates that the RGO-LaFeO₃ bifunctional electrocatalyst is a promising candidate for the cathode in lithium-oxygen batteries.
- RGO-LaFeO₃,
- Bifunctional catalyst,
- ORR,
- OER,
- Li-O₂ battery,
- Sol-gel,
- Hydrothermal
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
1. [1]
  Yuchen Guo , Xiangyu Zou , Xueling Wei , Weiwei Bao , Junjun Zhang , Jie Han , Feihong Jia . Fe regulating Ni3S2/ZrCoFe-LDH@NF heterojunction catalysts for overall water splitting. Chinese Journal of Structural Chemistry, 2024, 43(2): 100206-100206. doi: 10.1016/j.cjsc.2023.100206
2. [2]
  Hao GUO , Tong WEI , Qingqing SHEN , Anqi HONG , Zeting DENG , Zheng FANG , Jichao SHI , Renhong LI . Electrocatalytic decoupling of urea solution for hydrogen production by nickel foam-supported Co₉S₈/Ni₃S₂ heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2141-2154. doi: 10.11862/CJIC.20240085
3. [3]
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4. [4]
  Zhenchun Yang , Bixiao Guo , Zhenyu Hu , Kun Wang , Jiahao Cui , Lina Li , Chun Hu , Yubao Zhao . Molecular engineering towards dual surface local polarization sites on poly(heptazine imide) framework for boosting H₂O₂ photo-production. Chinese Chemical Letters, 2024, 35(8): 109251-. doi: 10.1016/j.cclet.2023.109251
5. [5]
  Yi Zhou , Yanzhen Liu , Yani Yan , Zonglin Yi , Yongfeng Li , Cheng-Meng Chen . Enhanced oxygen reduction reaction on La-Fe bimetal in porous N-doped carbon dodecahedra with CNTs wrapping. Chinese Chemical Letters, 2025, 36(1): 109569-. doi: 10.1016/j.cclet.2024.109569
6. [6]
  Zhihao Gu , Jiabo Le , Hehe Wei , Zehui Sun , Mahmoud Elsayed Hafez , Wei Ma . Unveiling the intrinsic properties of single NiZnFeO_x entity for promoting electrocatalytic oxygen evolution. Chinese Chemical Letters, 2024, 35(4): 108849-. doi: 10.1016/j.cclet.2023.108849
7. [7]
  Lu Dai , Yuxin Ren , Shuang Li , Meidi Wang , Chentao Hu , Ya-Pan Wu , Guangtong Hai , Dong-Sheng Li . Room-temperature synthesis of Co(OH)₂/Mo₂TiC₂T_x hetero-nanosheets with interfacial coupling for enhanced oxygen evolution reaction. Chinese Chemical Letters, 2025, 36(4): 109774-. doi: 10.1016/j.cclet.2024.109774
8. [8]
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9. [9]
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10. [10]
  Haoying ZHAI , Lanzong WEN , Wenjie LIAO , Qin LI , Wenjun ZHOU , Kun CAO . Metal-organic framework-derived sulfur-doped iron-cobalt tannate nanorods for efficient oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 1037-1048. doi: 10.11862/CJIC.20240320
11. [11]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
12. [12]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
13. [13]
  Jinli Chen , Shouquan Feng , Tianqi Yu , Yongjin Zou , Huan Wen , Shibin Yin . Modulating Metal-Support Interaction Between Pt3Ni and Unsaturated WOx to Selectively Regulate the ORR Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100168-100168. doi: 10.1016/j.cjsc.2023.100168
14. [14]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
15. [15]
  Yuena Yang , Xufang Hu , Yushan Liu , Yaya Kuang , Jian Ling , Qiue Cao , Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125
16. [16]
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17. [17]
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18. [18]
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19. [19]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al₂O₃ for promoting plasma-catalyzed CO₂ hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-. doi: 10.1016/j.actphy.2025.100054
20. [20]
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沈阳化工大学材料科学与工程学院沈阳 110142

Reduced Graphene Oxide-LaFeO3 Composite Nanomaterials as Bifunctional Catalyst for Rechargeable Lithium-Oxygen Batteries

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通讯作者: 陈斌, bchen63@163.com

Reduced Graphene Oxide-LaFeO₃ Composite Nanomaterials as Bifunctional Catalyst for Rechargeable Lithium-Oxygen Batteries