Citation: ZHANG Yan-Tao, LIU Zhen-Jie, WANG Jia-Wei, WANG Liang, PENG Zhang-Quan. Recent Advances in Li Anode for Aprotic Li-O₂ Batteries[J]. Acta Physico-Chimica Sinica, ;2017, 33(3): 486-499. doi: 10.3866/PKU.WHXB201611181 shu

Recent Advances in Li Anode for Aprotic Li-O₂ Batteries

1.
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China;
2.
University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Received Date: 29 September 2016
Revised Date: 18 November 2016

Fund Project: The project was supported by the National Natural Science Foundation of China (21605136,91545129,21575135)

The aprotic Li-O₂ battery has attracted considerable interest in recent years because of its high theoretical specific energy that is far greater than that achievable with state-of-the-art Li-ion technologies. To date, most Li-O₂ studies, based on a cell configuration with a Li metal anode, aprotic Li⁺ electrolyte and porous O₂ cathode, have focused on O₂ reactions at the cathode. However, these reactions might be complicated by the use of Li metal anode. This is because both the electrolyte and O₂ (from cathode) can react with the Li metal and some parasitic products could cross over to the cathode and interfere with the O₂ reactions occurring therein. In addition, the possibility of dendrite formation on the Li anode, during its multiple plating/stripping cycles, raises serious safety concerns that impede the realization of practical Li-O₂ cells. Therefore, solutions to these issues are urgently needed to achieve a reversible and safety Li anode. This review summarizes recent advances in this field and strategies for achieving high performance Li anode for use in aprotic Li-O₂ batteries. Topics include alternative counter/reference electrodes, electrolytes and additives, composite protection layers and separators, and advanced experimental techniques for studying the Li anode|electrolyte interface. Future developments in relation to Li anode for aprotic Li-O₂ batteries are also discussed.
- Lithium-oxygen battery,
- Lithium metal anode,
- Li anode stability,
- Solid electrolyte interphase layer
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Recent Advances in Li Anode for Aprotic Li-O2 Batteries

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通讯作者: 陈斌, bchen63@163.com

Recent Advances in Li Anode for Aprotic Li-O₂ Batteries