Citation: YUAN Hong, ZHANG Jing, WEI Xue-Hong, FANG Hui-Min, YUAN Shi-Fang, WU Li-Xin. Chiral Luminescent Liquid Crystal Material Based on Europium-Substituted Polyoxometalate[J]. Acta Physico-Chimica Sinica, ;2017, 33(2): 407-412. doi: 10.3866/PKU.WHXB201611032 shu

Chiral Luminescent Liquid Crystal Material Based on Europium-Substituted Polyoxometalate

1.
Institute of Applied Chemistry, Shanxi University, Taiyuan 030006, P. R. China;
2.
State Key Laboratory of Supramolecular Structure and Materials, Jilin University, Changchun 130012, P. R. China;
3.
College of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, P. R. China

Received Date: 23 September 2016
Revised Date: 2 November 2016

Fund Project: The project was supported by the National Key Basic Research Program of China (973) (2013CB834503), National Natural Science Foundation of China (21502107, 21574057, 21101101), Natural Science Foundation of Shanxi Province, China (2014021019-5), Scientific Research Start-up Funds of Shanxi University, China (020451801001), Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi Province, China (2016118), and National Training Programs of Innovation and Entrepreneurship for Undergraduates, China (201610108010) and Scientific Instrument Center of Shanxi University, China.

The incorporation of europium-substituted polyoxometalate (PM) into chiral amphiphiles is attractive for the fabrication of multifunctional chiral luminescent liquid crystalline materials. Chiral amphiphiles acted as good promoters to trigger the achiral PM to show induced supramolecular chirality through electrostatic interactions, as illustrated by circular dichroism (CD) spectra. Differential scanning calorimetry (DSC), polarized optical microscopy (POM), and temperature-dependent X-ray diffraction (XRD) analysis confirmed that the organic/inorganic hybrid polyoxometalate complex exhibited thermotropic mesomorphic behaviors. In a cast film, the complex displayed intrinsic luminescence that could be adjusted by accurately controlling the temperature. The electrostatic encapsulation of PM with chiral mesomorphic promoters provides an effective method for constructing PM-based chiral luminescent liquid crystalline materials.
- Polyoxometalate,
- Optical activity,
- Liquid crystal,
- Luminescence,
- Supramolecular selfassembly,
- Surfactant
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
39. [39]
40. [40]
1. [1]
  Yukai Jiang , Yihan Wang , Yunkai Zhang , Yunping Wei , Ying Ma , Na Du . Characterization and Phase Diagram of Surfactant Lyotropic Liquid Crystal. University Chemistry, 2024, 39(4): 114-118. doi: 10.3866/PKU.DXHX202309033
2. [2]
  Congying Lu , Fei Zhong , Zhenyu Yuan , Shuaibing Li , Jiayao Li , Jiewen Liu , Xianyang Hu , Liqun Sun , Rui Li , Meijuan Hu . Experimental Improvement of Surfactant Interface Chemistry: An Integrated Design for the Fusion of Experiment and Simulation. University Chemistry, 2024, 39(3): 283-293. doi: 10.3866/PKU.DXHX202308097
3. [3]
  Yi DING , Peiyu LIAO , Jianhua JIA , Mingliang TONG . Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393
4. [4]
  Zongfei YANG , Xiaosen ZHAO , Jing LI , Wenchang ZHUANG . Research advances in heteropolyoxoniobates. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306
5. [5]
  Yuan GAO , Yiming LIU , Chunhui WANG , Zhe HAN , Chaoyue FAN , Jie QIU . A hexanuclear cerium oxo cluster stabilized by furoate: Synthesis, structure, and remarkable ability to scavenge hydroxyl radicals. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 491-498. doi: 10.11862/CJIC.20240271
6. [6]
  Yongmin Zhang , Shuang Guo , Mingyue Zhu , Menghui Liu , Sinong Li . Design and Improvement of Physicochemical Experiments Based on Problem-Oriented Learning: a Case Study of Liquid Surface Tension Measurement. University Chemistry, 2024, 39(2): 21-27. doi: 10.3866/PKU.DXHX202307026
7. [7]
  Zhaoxin LI , Ruibo WEI , Min ZHANG , Zefeng WANG , Jing ZHENG , Jianbo LIU . Advancements in the construction of inorganic protocells and their cell mimic and bio-catalytical applications. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2286-2302. doi: 10.11862/CJIC.20240235
8. [8]
  Yi Fan , Zhuoqi Jiang , Zhipeng Li , Xuan Zhou , Jingan Lin , Laiying Zhang , Xu Hou . 偶极诱导液体门控可视化物质检测——化学“101计划”表界面性质应用实验新设计. University Chemistry, 2025, 40(8): 265-271. doi: 10.12461/PKU.DXHX202410061
9. [9]
  Zhiwen HUANG , Qi LIU , Jianping LANG . W/Cu/S cluster-based supramolecular macrocycles and their third-order nonlinear optical responses. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 79-87. doi: 10.11862/CJIC.20240184
10. [10]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
11. [11]
  Wanting CHEN , Chufei MIAO , Yan LIU , Bobi ZHENG , Xiaoyu ZHENG , Han XU , Jumei TIAN . Syntheses, characterization, and luminescence properties of Yb(Ⅲ)-based one-dimensional chain coordination polymer. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1672-1680. doi: 10.11862/CJIC.20250013
12. [12]
  Yajuan Xing , Hui Xue , Jing Sun , Niankun Guo , Tianshan Song , Jiawen Sun , Yi-Ru Hao , Qin Wang . Cu₃P-Induced Charge-Oriented Transfer and Surface Reconstruction of Ni₂P to Achieve Efficient Oxygen Evolution Activity. Acta Physico-Chimica Sinica, 2024, 40(3): 2304046-0. doi: 10.3866/PKU.WHXB202304046
13. [13]
  Xiaxue Chen , Yuxuan Yang , Ruolin Yang , Yizhu Wang , Hongyun Liu . Adjustable Polychromatic Fluorescence: Investigating the Photoluminescent Properties of Copper Nanoclusters. University Chemistry, 2024, 39(9): 328-337. doi: 10.3866/PKU.DXHX202308019
14. [14]
  Yanting HUANG , Hua XIANG , Mei PAN . Construction and application of multi-component systems based on luminous copper nanoclusters. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2075-2090. doi: 10.11862/CJIC.20240196
15. [15]
  Hongxia Yan , Rui Wu , Weixu Feng , Yan Zhao , Yi Yan . Innovation Inspired by Classical Chemistry: Luminescent Hyperbranched Polysiloxanes. University Chemistry, 2025, 40(4): 154-159. doi: 10.12461/PKU.DXHX202409010
16. [16]
  Yang YANG , Pengcheng LI , Zhan SHU , Nengrong TU , Zonghua WANG . Plasmon-enhanced upconversion luminescence and application of molecular detection. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 877-884. doi: 10.11862/CJIC.20230440
17. [17]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
18. [18]
  Wentao Xu , Xuyan Mo , Yang Zhou , Zuxian Weng , Kunling Mo , Yanhua Wu , Xinlin Jiang , Dan Li , Tangqi Lan , Huan Wen , Fuqin Zheng , Youjun Fan , Wei Chen . Bimetal Leaching Induced Reconstruction of Water Oxidation Electrocatalyst for Enhanced Activity and Stability. Acta Physico-Chimica Sinica, 2024, 40(8): 2308003-0. doi: 10.3866/PKU.WHXB202308003
19. [19]
  Ruiqin Feng , Ye Fan , Yun Fang , Yongmei Xia . Strategy for Regulating Surface Protrusion of Gold Nanoflowers and Their Surface-Enhanced Raman Scattering. Acta Physico-Chimica Sinica, 2024, 40(4): 2304020-0. doi: 10.3866/PKU.WHXB202304020
20. [20]
  Renjie Xue , Chao Ma , Jing He , Xuechao Li , Yanning Tang , Lifeng Chi , Haiming Zhang . Catassembly in the Host-Guest Recognition of 2D Metastable Self-Assembled Networks. Acta Physico-Chimica Sinica, 2024, 40(9): 2309011-0. doi: 10.3866/PKU.WHXB202309011

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(558)
HTML views(64)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142