Citation: LIU Dan, HU Yan-Yan, ZENG Chao, QU De-Yu. Soft-Templated Ordered Mesoporous Carbon Materials: Synthesis, Structural Modification and Functionalization[J]. Acta Physico-Chimica Sinica, ;2016, 32(12): 2826-2840. doi: 10.3866/PKU.WHXB201609141 shu

Soft-Templated Ordered Mesoporous Carbon Materials: Synthesis, Structural Modification and Functionalization

Department of Chemistry, School of Chemistry, Chemical Engineering and Life Sciences, Wuhan University of Technology, Wuhan 430070, P. R. China

Received Date: 24 June 2016
Revised Date: 14 September 2016

Fund Project: The project was supported by the National Natural Science Foundation of China (21401145, 11474226).

Ordered mesoporous carbon materials (OMCs) have potentially broad applications in many fields, such as adsorption, separation, catalysis, and energy storage/conversion. Compared with the elaborate hardtemplate strategy, the soft-template approach, which is based on the self-assembly between amphiphilic block copolymers and polymerizable precursors (e.g., phenolic resins), is a more effective and efficient method for the synthesis of OMCs. In this review, the mechanism and characteristics for three main soft-template methods, i.e., solvent evaporation-induced self-assembly synthesis, aqueous cooperative self-assembly synthesis and solvent-free synthesis, are discussed and compared. In addition, a few highlights of recent progress, including application of novel carbon precursors, structural modification and functionalization of OMCs, are outlined. Finally, we summarize the crucial issues to be addressed in developing the synthesis methodology of OMCs.
- Ordered mesoporous material,
- Porous carbon,
- Block copolymer,
- Soft template,
- Self-assembly
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Soft-Templated Ordered Mesoporous Carbon Materials: Synthesis, Structural Modification and Functionalization

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com