Citation: SONG Wei-Xin, HOU Hong-Shuai, JI Xiao-Bo. Progress in the Investigation and Application of Na₃V₂(PO₄)₃ for Electrochemical Energy Storage[J]. Acta Physico-Chimica Sinica, ;2017, 33(1): 103-129. doi: 10.3866/PKU.WHXB201608303 shu

Progress in the Investigation and Application of Na₃V₂(PO₄)₃ for Electrochemical Energy Storage

1.
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China;
2.
Department of Materials, Imperial College London, London SW72AZ, UK

Received Date: 23 June 2016
Revised Date: 26 August 2016

Fund Project: The project was supported by the National Natural Science Foundation of China (21473258, 21673298, 51622406).

Lithium ion batteries (LiBs) have been widely utilized, but the limited lithium resource restricts development and application of LiBs in large-scale energy storage. Sodium has similar physicochemical characteristics to that of lithium and is suitable to transfer between two electrodes as a cation in the "rocking chair" mechanism of LiBs. Na-containing compounds have been proposed as the electrodes to store sodium ions and provide channels for diffusion. Polyanion Na₃V₂(PO₄)₃ is a Na-super-ionic conductor (NASICON) with specific Na sites in its crystal structure and three-dimensional open channels. Recently, Na₃V₂(PO₄)₃ has been demonstrated as potential electrode material with promising properties for energy storage. In this review we systematically summarize the structure of Na₃V₂(PO₄)₃, the application and mechanism in a specific energy system, and the recent development of Na₃V₂(PO₄)₃ structure for use as electrodes. The potential problems and trends of Na₃V₂(PO₄)₃ are also discussed.
- Na₃V₂(PO₄)₃,
- Na-super-ionic conductor,
- Electrochemistry,
- Energy storage,
- Material structure
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Progress in the Investigation and Application of Na₃V₂(PO₄)₃ for Electrochemical Energy Storage