Citation: YANG Zu-Guang, ZHANG Jun, CHEN Jiu-Hua, HE Feng-Rong, ZHONG Ben-He, GUO Xiao-Dong. Enhanced Electrochemical Performance of LiNi_0.5Co_0.2Mn_0.3O₂ Cathode Materials at Elevated Temperature by Zr Doping[J]. Acta Physico-Chimica Sinica, ;2016, 32(5): 1056-1061. doi: 10.3866/PKU.WHXB201603092 shu

Enhanced Electrochemical Performance of LiNi_0.5Co_0.2Mn_0.3O₂ Cathode Materials at Elevated Temperature by Zr Doping

YANG Zu-Guang ^1,2 ,
¹ ,
ZHANG Jun ² ,
CHEN Jiu-Hua ² ,
HE Feng-Rong ² ,
ZHONG Ben-He ¹ ,
GUO Xiao-Dong ^1,3,,

1.
1 School of Chemical Engineering, Sichuan University, Chengdu 610065, P. R. China;
2.
2 Dongguan Hec Technology Research Corporation, Dongguan 523871, Guangdong Province, P. R. China;
3.
3 Institute for Superconducting and Electronic Materials, University of Wollongong, Wollongong NSW 2522, Australia

Corresponding author: GUO Xiao-Dong,
Received Date: 28 December 2015
Available Online: 9 March 2016
Fund Project: 国家自然科学基金(21506133) (21506133)四川省科技支撑计划(2014GZ0077)资助项目 (2014GZ0077)

In order to ameliorate the severe capacity fading of LiNi_0.5Co_0.2Mn_0.3O₂ cathode materials at elevated temperatures, a Zr-doping strategy was performed via a solid-state method, and the influence of the doping content on the structural and electrochemical properties of LiNi_0.5Co_0.2Mn_0.3O₂ was studied. The results indicate that the Li⁺/Ni²⁺ cation mixing can be reduced and the electrochemical performance, especially the hightemperature cycling performance, can be improved when the doping content of zirconium is 0.01. After 95 cycles, the capacity retention of Li(Ni_0.5Co_0.2Mn_0.3)_0.99Zr_0.01O₂ is 92.13% at 1C between 3.0 and 4.3 V, which is higher than that of the LiNi_0.5Co_0.2Mn_0.3O₂ (87.61%). When cycling at 55 ℃, Li(Ni_0.5Co_0.2Mn_0.3)_0.99Zr_0.01O₂ exhibits a capacity retention of 82.96% after 115 cycles at 1C, while that of the bare sample remains at only 67.63%. Therefore, a small amount of zirconium doping is notably beneficial to the electrochemical performance of LiNi_0.5Co_0.2Mn_0.3O₂ at elevated temperatures.
- Lithium-ion battery,
- Cathode material,
- LiNi_0.5Co_0.2Mn_0.3O₂,
- Zr-doping,
- High-temperature cycle performance
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Enhanced Electrochemical Performance of LiNi0.5Co0.2Mn0.3O2 Cathode Materials at Elevated Temperature by Zr Doping

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Enhanced Electrochemical Performance of LiNi_0.5Co_0.2Mn_0.3O₂ Cathode Materials at Elevated Temperature by Zr Doping