Citation: YANG Yi, LUO Lai-Ming, DU Juan-Juan, ZHANG Rong-Hua, DAI Zhong-Xu, ZHOU Xin-Wen. Hollow Pt-Based Nanocatalysts Synthesized through Galvanic Replacement Reaction for Application in Proton Exchange Membrane Fuel Cells[J]. Acta Physico-Chimica Sinica, ;2016, 32(4): 834-847. doi: 10.3866/PKU.WHXB201601211 shu

Hollow Pt-Based Nanocatalysts Synthesized through Galvanic Replacement Reaction for Application in Proton Exchange Membrane Fuel Cells

1.
1. College of Biological and Pharmaceutical Science, China Three Gorges University, Yichang 443002, Hubei Province, P. R. China;
2.
2. College of Materials and Chemical Engineering, China Three Gorges University, Yichang 443002, Hubei Province, P. R. China

Corresponding author: DAI Zhong-Xu, ZHOU Xin-Wen,
Received Date: 3 December 2015
Available Online: 18 January 2016
Fund Project: 国家自然科学基金(21403126, 21503120)资助项目 (21403126, 21503120)

Pt-based nanocatalysts are irreplaceable for proton exchange membrane fuel cells (PEMFCs), while the low reserves and high cost of Pt severely impede their commercialization. Tremendous efforts have been devoted to reduce the amount of precious metals and improve their electrocatalytic performance at the same time. Nanocatalysts with a hollow interior possess a large active area, high catalytic activity, good stability, and significantly reduce the amount of noble metal. The synthesis methods for their preparation are various, wherein the galvanic replacement reaction without additional procedure to remove the core, without the functionalization to the template surface and with ease of control, is the main method to prepare hollow structural nanocatalysts. We review the recent developments of hollow Pt-based nanocatalysts synthesized by the galvanic replacement reaction. The further challenges and developments of hollow Pt-based nanocatalysts are also discussed.
- Pt-based nanocatalyst,
- Hollow structure,
- Galvanic replacement reaction,
- Proton exchange membrane fuel cell
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沈阳化工大学材料科学与工程学院沈阳 110142