Citation: LI Zhan-Guo, ZHANG Yu-Ting, XIE Qiang, LI Heng-Li, SUN Li-Jing, SONG Xiao-Feng, WANG Li-Juan. NO₂ Sensors Based on p-6P Heterogametic Induction Growth of Copper Phthalocyanine Thin Films[J]. Acta Physico-Chimica Sinica, ;2016, 32(4): 1005-1011. doi: 10.3866/PKU.WHXB201601111 shu

NO₂ Sensors Based on p-6P Heterogametic Induction Growth of Copper Phthalocyanine Thin Films

1.
1. School of Chemical Engineering, Changchun University of Technology, Changchun 130012, P. R. China;
2.
2. State Key Laboratory on High Power Semiconductor Lasers, Changchun University of Science and Technology, Changchun 130022, P. R. China;
3.
3. School of Basic Sciences, Changchun University of Technology, Changchun 130012, P. R. China

Corresponding author: WANG Li-Juan,
Received Date: 6 October 2015
Available Online: 8 January 2016
Fund Project: 国家自然科学基金(21403016) (21403016) 吉林省科技发展计划(20130102065JC, 20140520139JH) (20130102065JC, 20140520139JH)吉林省教育厅项目(2015103)资助 (2015103)

To realize low concentration NO₂ detection at room temperature, copper phthalocyanine (CuPc) organic thin filmsensors are fabricated by using a para-hexaphenyl (p-6P) filmas the inducing layer. The growing characteristics of the p-6P film at different deposition rates are investigated by atomic force microscopy (AFM). At a low deposition rate, the p-6P film exhibited a horizontal growth mode. The large and thin domains were obtained owing to the sufficient diffusion time to the island. A CuPc thin film grown on p-6P film showed high order alignments, as observed by the AFM morphology. The CuPc films grew on the optimizing p-6P film by the weak epitaxial technique. The induction effect of the p-6P film to CuPc films was clearly observed by X-ray diffraction (XRD). By comparing the gas response effects of different deposition rates of the p-6P film, a high response intensity and recovery time were achieved at a low deposition rate. Thus, the performances of the CuPc film sensor were significantly improved by the inducing growth of p-6P thin films. The response intensity was twice that of CuPc thin films on silicon dioxide. The recovery time was 3.2 min and the detection concentration for NO₂ gas was 1.0 × 10^-5.
- Para-hexaphenyl,
- Copper phthalocyanine,
- Thin film sensor,
- Heterogenetic induction
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NO₂ Sensors Based on p-6P Heterogametic Induction Growth of Copper Phthalocyanine Thin Films